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The feasibility of electrocarboxylation of benzyl chloride has been investigated at silver cathode in CO2-saturated room-temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4) solution for the first time.

在饱和了CO2的室温离子液体中,首次在银电极上研究了苄基氯电羧化的可行性。

As superplasticizer , a series of comb-shaped copolymers of polycarboxylic acid were synthesized by polyoxyethylene allyl methyl diether, maleic anhydride, and styrene with different initiators,and esterified with PEO-n.

以聚氧乙烯甲基烯丙基二醚、顺丁烯二酸酐、苯乙烯等为共聚单体,采用不同引发剂,合成了一系列聚羧酸型梳状共聚物超分散剂,并以PEO n单酯化得酯化产物,研究了共聚物的结构、组成、添加量等对水泥粒子分散性能的影响。

It was found that introducing electron-donating groups, such as alkyls, weaken the electron-accepting ability of C60 and make its first reduction wave shifted to more negative position.

结果发现,引入推电子基团,如烷基,会使C60得电子能力降低,第一个还原电位有较大的负移;引入具有拉电子性质的基团,如羧酸酯基,则会部分抵消由於C60共扼结构被破坏而引起的电位负移,结果使得电位负移值减少。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用,烯烃的硼氢化物在PTC条件下,插入∶CCl2 ,可得饱和羧酸;炔烃则难以与之硼氢化。

By utilizing three benezenemulticarboxylate derivatives (H2chdc, H2aip, NaH2sip), we obtain 12 coordination polymers. Especially, compelexes 1 and 2 are based on one-dimensional ···OHInOHIn···chains as building units, while complex 3 is based on double four-ring [In8(μ2-O)4(μ2-H2O)8]16+, complex 4 is based on trinuclear In3(μ3-O)(CO2)6, complexes 11 and 12 are both based on nested bistranded helices.

选择了三类取代苯羧酸配体: 2,5-二羟基-1,4-对苯二甲酸(2,5-H2chdc); 5-氨基间苯二甲酸(5-H2aip); 5-磺酸基间苯二甲酸钠盐(5-NaH2sip)和InCl3反应合成了十二个配位化合物:其中1、2以···OHInOHIn···链为构筑单元, 3以双四元环[In8(μ2-O)4(μ2-H2O)8]16+为构筑单元,4以棱柱状三核铟In3(μ3-O)(CO2)6为构筑单元,而11、12以嵌套的双股螺旋链为构筑单元。

The limited of quantification of this method in various matrixes is 2 μg/kg.

三氟羧草醚在各种基质中的测定低限均为2 μg/kg。

According to the experience of the research of the indoles alkaloid, we designed a series of novel compounds which contained indoles heterocyclic as the flat aromatic group, benzyloxy substituent at indoles 6 site as the nonhydrophilic group tail, carboxylic derivatives and TZDs bioisosterism substituent at indoles 2 site or 3 site as the hydrophilic group head.

于是根据我们课题组多年来对吲哚生物碱研究的经验,我们设计了以吲哚作为中间平面芳环体系,6位连接苄氧基作为疏水尾部,2位或3位连接羧酸及其衍生物、噻唑烷二酮及其电子等排体的一系列化合物。

A brief review is given for the chlorization of organic compound with SOCl 2,especially, the chlorization of carboxylic acid,substitution of hydoxyl group,carbonyl group,methlyene group and C,N,S,P,Si atoms.

综述了氯化亚砜在有机合成中的氯化应用,重点介绍了使羧酸氯化、去羟基氯化、加成羰基氯化、使活性亚甲基氯化及取代C ,N ,S ,P ,Si等原子上基团氯化的反应原

In the following experiments, we used solution blending method to mix ZnO nanoparticles and ABM copolymers together. In XRD and FTIR analysis, we found that the carboxylic acid groups of ABM copolymer could dissolve ZnO crystalline and adsorbed onto the surface of ZnO nanoparticles. In the sedimentation test, we observed that ABM copolymers enhanced the stability of dispersion of ZnO nanoparticles in the hydrophobic organic solvent.

将ZnO粒子与ABM共聚物以溶液掺混方式混合后,经XRD与FTIR等分析可得知ABM共聚物中的羧酸官能基会溶解ZnO的晶格结构并吸附於ZnO粒子表面上;由沉降实验可观察得知,ABM共聚物可提升ZnO粒子在亲油性有机溶剂中的分散稳定性。

The intermediate 5-amino-1H-pyrazole-4-carboxylic acid ethyl ester prepared in the first part underwent successively hydrazinolysis, condensations with ketene dithioacetals and alkylations to give rise to the dipyrazolyhnethanes.

从第一部分中的中间体5-氨基-1H-吡唑-4-羧酸乙酯开始,经过肼解、与乙烯酮二硫代缩醛的缩合反应和烷基化反应,合成了二吡唑基甲酮类化合物。

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