羧基

The structure of products was characterized by means of infrared spectra, wide-angle X-ray diffraction and differential scanning caloriimetry and the effect of deacetylation in course of konjac glucomannan carboxy methylation was analyzed.

运用红外光谱、广角X-射线衍射和示差扫描量热法表征产物结构并探讨脱乙酰基对KGM羧甲基改性的影响。

Analyse and compare what adopt a variety of pair of methods, the Michael addition reaction of ester of acerbity second of second of hydroxyl of protection of benzyl of the response of close nucleus addition that uses second nitrile and ester of formic acid second certainly, chloridize, cyanogen, reaction that take off carboxyl generates 3- benzyl oxygen radical the fifth of the ten Heavenly Stem the method of 2 nitrile, detailed discussion the action that wait and the by-product that arise possibly reach the reactant in each pace reaction, activator, dissolvent avoid a method.

通过对多种方法的分析和比较，确定采用乙腈和甲酸乙酯的亲核加成反应、氯化苄保护羟基、氰乙酸乙酯的Michael加成反应、脱羧反应生成3-苄氧基戊二腈的方法，并具体的讨论了每一步反应中反应物、催化剂、溶剂等的功能和可能产生的副产物及避免方法。

The results of magnesium and calcium ions tolerance test indicated that the modified SPS, synthesized from the above two methods,has good chelation with magnesium and calcium ions for the crablike carboxyl and ester group and increase the reaction weight with magnesium and calcium ions for addition of hydrophilic group.Both of the two modified petroleum sulfonates could produce ultra-low interfacial tension at calcium and magnesium ions concentration lower than 600 mg/L,whereas the general petroleum sulfonates could only produce ultra-low value below 300 mg/L.

耐钙镁离子能力测试结果，以大庆炼化公司两种渣油为原料，采用上述两种合成方法制备的改性石油磺酸钠，由于产物中引入蟹爪状羧酯基，对钙镁离子有较强的螯合作用，同时增加了亲水基，增大了表面活性剂分子与钙镁离子的反应量，因而在600mg/L的钙镁离子溶液中获得10-3级的超低界面张力；而普通石油磺酸钠仅能在300mg/L的钙镁离子溶液中获得超低界面张力。

A Michael addition of dimethyl malonate and 2-pentyl-cyclopentenone could conduct a precursor which used for preparing aim compound by a selective decarboxylation.

中间体化合物2-戊基环戊烯酮在一定条件下经Michael加成和选择性脱羧反应合成目标化合物。

In the thesis, a series of novel single and multi-armed oxadiazole bridging ligands and pyridyl-4, 5-imidazole dicarboxylic acid ligands have been synthesized. The coordination chemistry of these novel ligands with transition metal ions was investigated. In addition, two 1, 3, 4-oxadiazole bridging ligands end-capped by chelating Schiff-base coordination sites have been designed and synthesized. The coordination chemistry based on one of the two ligands with metal ions was primarily investigated.

本文报道了一系列新颖的含1， 3， 4-Oxadiazole杂环的单臂及多臂有机配体，研究了它们与过渡金属离子的配位反应化学；合成了吡啶基-4，5-咪唑二羧酸有机配体，研究了它们在水热条件下与过渡金属离子的配位反应化学；另外，还合成了1， 3， 4-Oxadiazloe杂环桥联的双Schiff-base有机配体，初步探讨了其与过渡金属离子的配位反应化学。

The combination of chemicals includes a catalyst, such as, dibutyl tin dilaurate; carboxylic or sulfonic acid; and an extender compound, such as 2,4 pentanedione.

该化学试剂混合物包括催化剂，如二月桂酸二丁基锡；羧酸或磺酸；和增量化合物，如2，4－戊二酮。

A new method for the synthesis of 1 methyl 3 propyl pyrazol e 5 carboxlic acid from 2 pentanone and diethyl oxalate is reported.

以 2 -戊酮和草酸二乙酯为起始原料，经缩合、与甲基肼环合、水解等三个步骤合成了 1 -甲基-3-丙基吡唑-5 -羧酸。

In addition, some aryl-substituted propenoic acids were prepared via Perkin reaction.

此外，通过Perkin反应合成了4种芳基取代丙烯酸，研究了其关环和脱羧反应。

It is found that the initial pH,ρ(H_2O_2) and ρFe~(3+ of the solution have significant effects in this photooxidative process. The removal percentage of COD_ is higher under solar irradiation than under UV irradiation. Under the selected conditions, using solar/H_2O_2/ferric oxalate complexes to treat the landfill leach has good efficiency. landfill leach ; ferric oxalate ; photocatalysis

已有的研究表明，Fe3+羧酸盐络合物具有光催化降解有机物的性能[1-3]；当草酸铁络合物体系中存在一定量的H2O2时，在太阳光或紫外光照射下，可发生类Fenton反应产生羟基自由基[4]，而草酸铁络合物可在一定程度上循环利用，使Fe3+和C2O2-4可以重新形成草酸铁络合物：2[Fe(C2O4)n](3-2n)hν2Fe2++(2n-1)C2O42-+2CO2(1)Fe2++H2O2

In this mechanism, a phosphine ligand in the Ru hydride complexes is replaced by protonic solvent ROH to generate the chain carrier.

三、反应机理论文提出，在固载Ru基催化剂上的scCO〓加H〓生成HCOOH的反应中，CO〓的活化在Ru配合物的作用下，以反插入Ru-H键，生成金属-羧酸配合物的形式进行。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。