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A novel family of ester acetal molecular glass materials has been created by the reaction between monocarboxylic acid and divinyl ether s.

通过一元羧酸和二乙烯基醚的反应,我们得到了一种新颖的酯缩醛结构分子玻璃。

The results of clinical assessment showed that levosimendan was safe and effective which could improve the prognosis of the patients and kept normal blood kinetics. By improving the reported synthetic route, levosimendan was synthesized from acetanilide via eight steps of reaction.

本论文探索了左西孟旦的合成路线,对文献报道的合成工艺进行了合理有效的改进,以乙酰苯胺为原料,最终经Friedel-Crafts反应,羰基α-位溴代,丙二酸二乙酯缩合,水解,脱羧,环合,拆分及重氮化加成等八步反应合成了左西孟旦。

The hydroxyl amino acid has been replaced, the resulting compounds can also be regarded as ammonia hydrogen has been replaced by acyl derivatives.

羧酸中的羟基被氨基取代后,生成的化合物,也可看作是氨的氢被酰基取代的衍生物。

The phase transition behavior of 2,3-O-MC inaqueous solution was studied in terms of DS value, concentration and molecularweight.

甲基纤维素和羧甲基纤维素在水中的溶解与取代基在纤维素链和葡萄糖残基上的分布有关。

Moreover, Oxygen-containing groups such as methoxyl, carbohydrates, carboxylic/carbonyl, were also very different among four HAs

另外不同腐殖酸之间,含氧结构单元如甲氧基、碳水化合物结构、羧酸/羰基官能团等的含量也明显不同。

Secondly,UV spectrophotometry was adopted to research the combination action on SM_2 and SIZ with MAA and 4-Vp.The combination action of functional monomer with template molecules were produced in the results. Then,the prediction imprinting principle of SM_2 and SIZ were given. The diagrams of infrared spectrum were analysed in MAA and 4-Vp and IMPs of SM_2. It was discoved that the absorbability peak of C=C function group in the IMPs were turn to be very low ,but the function group of carboxylic acid and pyridyl in the IMPs were no evidence change, and the condition was created in the molecular recognition of MIPs. Thermal Analysis was adopted to research IMPs ,in which ,a better thermal stability and its decompose temperature were showed in the results.

其次,本文利用紫外分光光度法研究磺胺二甲嘧啶和磺胺异噁唑与甲基丙烯酸或4-乙烯基吡啶的结合作用,结果表明,溶液中的功能单体与模板分子之间产生了结合作用,并预测磺胺二甲嘧啶和磺胺异噁唑印迹机理;分别分析了功能单体甲基丙烯酸、4-乙烯基吡啶、磺胺二甲嘧啶和磺胺异噁唑分子印迹聚合物的红外谱图,经过对比发现制得的印迹聚合物中C=C双键峰很小,并且功能键羧酸键和吡啶氮没有明显变化,这为聚合物特异识别特性创造了条件;利用综合热分析仪,对分子印迹聚合物进行综合热分析,结果表明分子印迹聚合物具有较好的热稳定性,分解温度也较高。

Comb-shaped polycarboxylic -type superplasticizers were synthesized with acrylic acid,mathacrylic acid,sodium allylsulphonateand methoxypolymethacrylatethrough aqueous copolymerization initiated by ammonium persulfate.

将甲氧基聚氧乙烯醚单甲基丙烯酸酯、丙烯酸、甲基丙烯酸和烯丙基磺酸钠进行水溶液共聚,合成了具有梳型结构的聚羧酸系高效减水剂。

In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...

中文摘要:本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用,具体研究内容和结果如下:一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下,苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应,无需分离和纯化反应中间体,直接使用30 %的双氧水进行氧化-消除反应,提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法,该方法反应条件温和,操作简便,产物收率良好(76-82 %)。

Experimental results showed that aerosol created by 1,3,5-trimethylbenzene photooxidation can be classify with five distinct chemical particle classes, the predominant components of these five particles are aromatic aldehyde, phenol, nitrophenol and carboxylic acid compounds.

利用该算法对OH自由基启动1,3,5-三甲苯光氧化形成的二次有机气溶胶单粒子质谱数据进行了聚类分析,在得到的五个聚类中包含了芳香醛、酚类化合物、硝基酚和羧酸等重要的光氧化产物,为研究苯系物光氧化机理提供了新的信息。

As support, Agarose can benot only used in normal condition, but also in denaturalization (for example, 6 mol/Lhydrochloric acid carbamidine or 8 mol/L urea). Herein, the preparation of IMACmatrixes were conducted using agarose as support, carboxymethylated aspartate as chelating ligand and Co~(2+) and Ni~(2+) as chelating center ions.

本实验用琼脂糖作为基质,选用四配位,与金属离子有较强作用力的羧甲基天冬氨酸为配基,以Co~(2+)、Ni~(2+)作为螯合金属离子,合成了一系列金属螯合亲和色谱填料,并对其蛋白质分离性能进行了研究。

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第三章汉藏语&的&字结构的类型划分。