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Chemically, fluoroquinlones are an amphoterics molecule processing major ionizable groups, a basic piperazine amine and acidic carboxyl. The form of drugs was greatly affected by the acidity in aqueous solution. Thus the effect of pH values in aqueous solution on the fluorescent properties of fluoroquinolones was studied in details, the spectral properties of each form was characterized. It was found that the fluoroquinolones exhibit weak fluorescence in strong basic solution.

氟喹诺酮类药物分子结构中既有羧基,又有哌嗪氨基,它们所处环境的pH值对其存在型体有很大影响,因此我们详细研究了水溶液的pH值对该类药物光谱特性的影响,并对于各型体光谱特征进行归属,发现强碱性溶液中其发光较弱。

With the varying of potential the adsorption behavior of picolinic acid is invariant,while the adsorption behavior of isonicotinic acid and nicotinic acid may change.

分析表明在电极电位负移过程中皮考酸分子一直采取通过羧基和苯环上的N原子侧立吸附在银电极表面,与之不同的是,异烟酸分子和烟酸分子在表面的吸附状态都随电位改变发生了变化,我们对此进行了分析和解释。

With the varying of potential the adsorption behavior of picolinic acid is invariant, while the adsorption behavior of isonicotinic acid and nicotinic acid may change. The probable reasons are given.

分析表明在电极电位负移过程中皮考酸分子一直采取通过羧基和苯环上的N原子侧立吸附在银电极表面,与之不同的是,异烟酸分子和烟酸分子在表面的吸附状态都随电位改变发生了变化,我们对此进行了分析和解释。

Two coordination polymers composed of in situ synthesized ligand deriving from isophthalic acid through the hydroxylation on the 2-position have been synthesized under hydrothermal conditions.

利用铜离子的氧化还原性质,以铜离子和间苯二甲酸在水热条件下反应使配体发生羟基化衍生成2,6-二羧基苯酚,并组装出2个含衍生配体的配位聚合物。

The corrosion-inhibiting efficiencies of isoquinoline and its hydroxyl and carboxyl derivatives on Fe electrode in HCl solution have been determine with electrochem.

本文在30℃, 1.0mol.dm^-3 HCl溶液中用电化学方法测定了异喹啉及其羟基,羧基衍生物对Fe电极的缓蚀效率。

The corrosion inhibition of isoquinoline and its hyd roxy and carboxylic derivates were determined by electrochemical methods,and qua ntum chemistry calculation were gained through HMO and CNDO.

用电化学方法实测了异喹啉及羟基、羧基两类取代衍生物的缓蚀效率,并用HMO、CNDO方法进行量子化学计算。

The neural network's outputs included the corrosion-inhibition efficiencies of isoquinoline and its hydroxyl and carboxyl derivatives for iron electrode in HCl solution or electrode parameters which were determined with electrochemical methods in 1.0 mol·dm-3 HCl solution at 30℃.

以缓蚀剂分子氮净电荷、自由价、亲核前沿电荷密度等量子化学参数为输入变量,考察了异喹啉及其羟基、羧基衍生物在30℃,1.0mo1·dm~(-3)HCl溶液中对铁的缓蚀效率,建立了相应的预测模型。

Based on our intensive studies on the lactonization of oligo/polysialic acids, we proposed for the first time that the lactone-ring formation of oligo/polysialic acids has three stages. We also provided a novel model to explain the conformational changes of oligo/polysialic acids caused by the repulsing forces among the carboxyl groups of sialic acid residues. Our results should provide novel approaches for further investigation of the structural-functional relationships of oligo/polysialic acids.

在对多/寡聚唾液酸内酯化过程进行深入研究的基础上,于国际上率先提出多/寡聚唾液酸内酯的形成具有三个阶段的观点,并首创性地提出了羧基排斥所致多/寡聚唾液酸分子空间构象改变的模型,为深入研究多/寡聚唾液酸结构与功能的关系提供了新生长点。

The experiment result shows that favorable colour development performance can be achieved for the adhesive with polyvinyl alcohol as major component and the waterproof quality can be improved when the carboxyl tetraphene latices was mixed into the adhesive in a certain proportion.

实验发现,使用聚乙烯醇为主体的胶粘剂可使热敏纸获得良好的发色性能,胶粘剂中混入一定比例的羧基丁苯类胶乳可以使热敏纸的防水性能得到改善。

By chemical treatment of LS, a kind of modified lignosulphonate based plasticizer was obtained. The modification was confirmed to be connected with carboxyl groups through infra-red spectroscopy analysis.

通过化学方法对LS改性,得到了一种接有羧基基团的改性木质素磺酸盐减水剂。

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