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羧基

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The present invention relates to a coating composition comprising; A at least one polyester oligomer prepared from reactants comprising a 20 60 wt.% of at least one polyol, b 5 30 wt.% of at least one polycarboxylic acid selected from the group of cyclic polycarboxylic acids, the esters or the anhydrides thereof, wherein the carboxyl groups are separated by 3 carbon atoms or less, and from the group of alpha , beta -saturated acyclic polycarboxylic acids, the esters or the anhydrides thereof, and c 20 60 wt % of at least one monocarboxylic acid, the sum of the wt.% indicated for the reactants,, and always being 100 wt.%, and the oligomer being a low-viscosity oligomer having a weight average molecular weight Mw of less than 5,000, and a hydroxyl number in the range of about 200 to about 400 mg KOH/g oligomer, and B at least one polyisocyanate.

本发明涉及一种包含如下组分的涂料组合物:A至少一种由包含如下成分的反应物制备的聚酯低聚物:a20-60wt%至少一种多元醇,b5-30wt%至少一种选自其中羧基被3个或更少碳原子隔开的环状多元羧酸、其酯或酸酐以及选自α,β-饱和的无环多元羧酸、其酯或酸酐的多元羧酸,以及c20-60wt%至少一种一元羧酸,其中反应物、和的wt%之和总是为100wt%,所述低聚物是重均分子量Mw低于5000且羟基值为约200-约400mg KOH/g低聚物的低粘度低聚物,以及B至少一种多异氰酸酯。

Ionic liquids of 1-carboxymethyl-3-ethylimidazolium chloride, 1-methoxyethyl- 3-ethylimidazolium chloride ([C2OC1-EIM]Cl) and 1-[2-(2-chloroethoxy)ethyl]-3-ethylimidazolium chloride ([Cl-C2OC2-EIM]Cl) were synthesized, and their chemical structures were confirmed by FT-IR and 1H NMR.

合成了三种含有羧基或醚基的离子液体, 1-羧甲基-3-乙基咪唑氯化物、1-甲氧乙基-3-乙基咪唑氯化物([C2OC1-EIM]Cl)和1-[2-(2-氯乙氧基)乙基]-3-乙基咪唑氯化物([Cl-C2OC2-EIM]Cl),用FT-IR和1H NMR对它们的化学结构进行了表征。

According to the theoretic significance and the applications of the complexes, this paper mainly concluded the following work: The ligand, 2-carboxybenzaldehyde-2,4-dinitrophen hydrazone, was synthesized by 2-carboxybenzaldehyde and 2,4-dinitrophenyl hydrazine in absolute alcohol.

中文摘要本文基于芳香腙类化合物的抑菌活性、稀土元素的生物活性以及二者配位后可能的协同效应,主要进行了以下几个方面的工作:在无水乙醇中,利用2-羧基苯甲醛和2,4-二硝基苯肼缩合反应得到了配体2-羧基苯甲醛-2,4-二硝基苯腙(C14H10N4O6)。

The new compound,2- oxo-propionic acid p-carboxylphenyl hydrazone,was synthesized by the condensation reaction of 2- oxo-propionic acid and p-carboxylphenyl hydrazine which was prepared from p-aminobenzoic acid by diazotization and reduction.

以对氨基苯甲酸为原料,经过重氮化反应和还原反应,合成了对羧基苯肼(2);2与2-羰基丙酸缩合得到新化合物2-羰基丙酸缩对羧基苯腙,其结构经UV,荧光光谱,1H NMR,13C NMR,IR和元素分析表征。

Amino-2-methylpropanol was utilized as a chemical modifying reagent to modify carboxyl groups in unsaturated fatty acids into nitrogen-containing heterocycles, which effectively suppressed the migration of double bonds of the alkenyl within the electron impact source and led to regular informative mass spectra indicative of the position of the olefinic bonds in the chain.

以2-氨基-2-甲基丙醇为脂肪酸的化学修饰试剂,将不饱和脂肪酸羧基化学修饰试剂,将不饱合脂肪酸羧基化学修饰成含氮杂环,从而避免了链烯基中碳碳双键在EI源中的移动,并使质谱呈现显示双键位置的规范信息。

Based on hydrogen peroxide and ammonium persulfate as compounded initiating system,unsaturated vinyl monomers were used to directly copolymerize a new high range polycarboxylate water reducer structurized in carboxyl,esterquat and amido as main chain and in polyethylene glycol ether as side chain.

以过硫酸铵和双氧水为复合引发体系,采用不饱和单体直接共聚,得到一类主链为羧基、酯基、酰胺基,侧链为聚乙二醇醚基的新型聚羧酸高效减水剂,研究了共聚物的结构对分散性能的影响。

DBP and DEHP have the similar photodegradation mechanism. The predominant pathway for DBP and DEHP photodegradation in the Fe -oxalate complexes system is hydroxyl radical extracting H atom in α-position of the aliphatic chain close to the carboxyl group followed by oxidation to produce alcoholized derivatives ROH. ROH then breaks down to phthalic acid and dialcohol that will be further oxidized up to mineralization.

DBP和DEHP的光降解历程相似,主要反应途径是OH自由基提取烷基上与羧基相连的α-H原子,然后被氧化生成醇衍生物,再分解成为酞酸和二醇,酞酸经历开环和进一步脱羧,二醇可以被氧化成为低级烷基羧酸,直至矿化。

Mol/L. 3 A study on the ECL of acridinum esters including 10--acridinium-9-carboxyl-phenyl-ester iodinate and 10-methyl-9-(p-formylphenyl)-acrdiniumfluorosulphonate in neutral solution was carried out. It was found both CACPEI and MFPA give strong ECL in KNO〓 solution when an appropriate voltage was applied on Pt electrode.

本文研究了碘化10-乙羧基吖啶-9-羧酸苯酯和对甲酰基苯基-10-甲基吖啶-9-羧酸酯氟磺酸盐的ECL行为,发现在中性KNO〓介质中,这两种吖啶酯都能在一定的电位下产生很强的ECL信号,考察了各种影响因素,确定了发光的最佳条件,探讨了可能的发光机理。

It is shown that the of the porous carbon towards (I_2) depends on the pore volume of the porous carbon; the adsorption of the porous carbon towards phenolic compounds depends on the density of carboxylic and lactonic groups on the surface of the porous carbon; the adsorption of the porous carbon towards Cr d...

发现多孔炭对酚类化合物及Cr的吸附以化学吸附为主,其中对酚类化合物的吸附由羧基与内酯基的表面密度合量决定,对Cr的吸附由表面官能团中羧基和内脂基含量的合量决定;多孔炭对I2的吸附以物理吸附为主,由孔容决定。

The morphology of dispersive emulsion particle was observed by SEM.The results showed that the moderate amount of surface carboxyl groups and ionization carboxyl were available to the improvement of water resistance of latexes.

SEM结果表明羧酸改性后的乳液微观分散状态良好,适度的表面羧基密度和适量的离子化羧基对提高乳液的湿强度是有效的。

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