羧基
- 与 羧基 相关的网络例句 [注:此内容来源于网络,仅供参考]
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The absorbability and retentivity of crosslinked polyacrylamide and its modified products to water and fertilizer were investigated.
由于羧基、羟基和胺基的协同作用,对水和肥的保持、吸收能力大大增强。水解4h的产物PAM-4中羧基、羟基和胺基的协同作用最好,对水和肥的保持、吸收能力最强。
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WithinPMAO LB films,because the distance between the metal ions is no morethan 0.3nm,the carboxylate groups of a molecule form a nanoparticle(the size is less than 0.2nm)by the hydrogen bond or metal ion asthe bridges.
实验表明,在这种高羧基密度的聚合物中,由于羧基距离较近(<0.3nm),羧基通过氢键或金属离了为桥在分子内聚集成纳米团簇(<2nm)。
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Spiral Spirobifluorene acetylated is oxidated by m-chloroperoxybenzoic acid and hydrolyzed by sodium hydroxide ,obtaining 2,2 '- dihydroxy -9,9'- spiral Spirobifluorene .Through nitrification,Reduced by hydrazine hydrate, we may get the 2,2 '- diamino -9,9'- spiral Spirobifluorene which are characterizated by IR, 1H-NMR !
L-酒石酸和乙醇酯化得到酒石酸二乙酯,将保护羧基保护起来,然后用碘甲烷在2,3-位上两个甲基,得到2,3-二甲氧基-酒石酸二乙酯,再用氢氧化钠将其水解,得到2,3-二甲氧基-酒石酸,用五氯化磷将羧基酰化,得到2,3-二甲氧基- 1,4-丁二酰氯,经过与二环己胺反应,得到拆分配体2,3-二甲氧基–N,N,N',N'-四环己丁二酰胺。
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In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions(0-D chain); complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.
合成了8个结构新颖的配合物,并用X-射线单晶结构分析方法确定了晶体结构,分别为: [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构;配合物2借助水分子形成一维链状结构;配合物3、4、5、6是以H4btc为第一配体、phen为第二配体,通过水热法合成的配合物,其中,Co2+、Ni2+、Cu2+为中心离子;配合物3中的二价钴离子具有相同的配位环境,不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境,在配合物4中,一维链通过H4btc上的羧基形成一个二维层结构;配合物5、6是借助H4btc上的羧基形成的一维链状结构;配合物7、8属于异质同晶结构,它们的分子通过分子间氢键形成三维网状结构,H4btc上的羧基失去2个质子,作为一个二价负离子起到电荷平衡作用。
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By way of orthogonal testing analysis,study was carried out on effects of molar ratio of unsaturated monomers with carboxylic groups,sulphonic groups,polyoxyethylene side chain groups and mean degree of polymerization of polyoxyethylene side chain groups on performance of polycarboxylic series of water reducer.
采用正交试验分析法,研究了带活性基团羧基、磺酸基、聚氧化乙烯链基等不饱和单体的摩尔比及聚氧化乙烯链的聚合度等对聚羧酸系减水剂性能的影响,提出一种合成聚羧酸系高性能减水剂的最佳配方。
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The particular preparation procedure is as follows: preparing a carbon nanotube with carboxyl by acidulating the carbon nanotube; Preparing the carboxylic carbon nanotube/nylon 66 composite material by polymerizing the carboxylic carbon nanotube and the raw material (such as polybasic acid and polybasic amine) which is used for preparing the nylon 66 through in situ polymerization.
具体步骤为:通过对碳纳米管进行酸化,制备携带羧基的碳纳米管。通过原位聚合法将羧基化碳纳米管与制备尼龙66的原料进行聚合,制备羧基化碳纳米管/尼龙66复合材料。
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A novel method combining a conventional free-radical solution polymerization with a chemical saponification was used to synthesize a, cu-dicarboxyl terminated oligo s with molecular weight below 1500. Here, cn-carboxyl terminated oligo s were firstly synthesized by the free-radical polymerization in THF, where 4,4'-azobis(4-cyanovaleric acid) was used as initiator, thioglycolic acid as chain transfer agent, then CTBMA were transformed into di-CTBMA via saponifying CTBMA in dioxane/H_2O/KOH solution.
利用传统自由基聚合法,在四氢呋喃溶液中自由基引发聚合甲基丙烯酸丁酯单体而得到w-羧基-甲基丙烯酸丁酯低聚物(分子量在1500左右);利用CTBMA 末端酯基的反应特性,在二氧六环/水/KOH混合溶液中皂化CTBMA,使之转化为a ,w-羧基甲基丙烯酸丁酯低聚物;研究了溶剂的类别、反应时间等反应条件对皂化产物结构的影响;利用MALDI-TOF-MS及LSIMS对皂化各阶段产物进行了分析监测。
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The main factors that can affect the strength of base PAN fiber and how its hydrolysis reaction happened in alkaline conditions were discussed.
应用红外光谱仪、元素分析仪、比表面分析仪等对基体聚丙烯腈纤维及其部分水解PAN-COOH型离子交换纤维进行了表征,讨论了影响基体PAN纤维强度的主要因素和碱性条件下的水解反应获得了干态水解PAN纤维的性能指标:强度8.3 cN/dtex,交换容量0.26 mmol/g , BET比表面积为0.58平方公尺/g的PAN-COOH型离子交换纤维,并较为详细地讨论了该纤维氰基转化成羧基的比率,羧基在纤维表面的排列及最大水解量。
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In this paper,the method for determining the COOH in PET has been introduced by three electrode potential titration .
采用三电极电位法,对以苯酚-四氯乙烷为溶剂测定聚酯中端羧基进行了实验和探讨,并建立了端羧基测定的新方法,此方法的相对标准偏差为 2 78%,可用于聚酯中端羧基测
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By synthesizing the hapten LBc starting from the metabolite of bifenthrin (2-methyl-3-phenylbenzyl alcohol), LBs (2-methyl[1,1-biphenyl]-3-ylmethyl 3-carboxyl-2,2-dimethylcyclopropane carboxylate and Lby (2-methyl[1,1-biphenyl]-3-ylcarboxylic acid , Three haptens were praparaed which were used in next step.
利用联苯菊酯的代谢物联苯醇合成了联苯菊酯的半抗原LBc(2-甲基-3-苯基苄基氧基羰基丙酸)、LBs(2-甲基-3-苯基苄基-3-羧基一2,2-二甲基环丙烷羧酸)和LBy(2-甲基-3-苯基苯甲酸)。
- 推荐网络例句
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Do you know, i need you to come back
你知道吗,我需要你回来
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Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.
1〕 杨银书,王祥生,李德昌。安徽省首次发现嗜群血蜱。
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Chapter Three: Type classification of DE structure in Sino-Tibetan languages.
第三章汉藏语&的&字结构的类型划分。