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羧基

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The three isomers structures of 3 were discussed in detail based on the calculation results. Among the six bonds in 3, the P_O bond between the phosphorus and carboxyl oxygen O3 was the weakest one, and could be easily broken to form a new penta-coordinate intermediate 4 which could yield the phosphoryl N → O migration product 5 by breaking the weaker P_N bond.

在六配位磷中间体3的6根键中,丝氨酸的羧基氧O3与磷之间的键最弱,最易断裂生成新的五配位磷中间体4, 4的P_N键断裂得到磷酰基的N→O转位反应产物5。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明,磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应,可以在颗粒表面引入少量羧基;磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应,可以在颗粒表面接枝不同分子链长度的末端羟基;磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基;磁性聚丙烯酸甲酯颗粒通过乙二胺或1,6己二胺的胺解反应可以得到表面氨基,继而与一氯乙酸反应可以引入亚胺二乙酸基团。

Synthesis of pyruvic acid from lactic acid by catalytic oxidation with oxygen was studied. The effect of catalyst composition, amount of catalyst and oxygen, reaction temperature and time on product yield was investigated and the optimum conditions were found.

由于丙酮酸的分子中同时具有羰基和羧基两个官能团,因而反应中心多而显出比一般化合物更为重要和特殊的化学性质,已引起越来越多的化学工作者的重视。

Objective In search for less toxic and more effective radiosensitizer.The effects of CGEONA (carboxy-β-phenyl-vinyl-germanium sesquioxide sodium salt) on radiosensitivity in tumor-bearing mice and normal mice were investigated.

目的 为了寻找低毒有效的放射增敏剂,观察CGEONA(羧基-苯乙烯基锗倍半氧化物钠盐)对荷瘤小鼠和正常小鼠放射敏感性的影响。

The research results indicated that the first cross-linking between the HPAM and Cr3+ in ground condition was propitious to reduce leaking of blocking agent in oil layer, and the second crosslink action between acylamino of HPAM and organic phenolic aldehyde can form the high intensity gel and it can endure high temperature.

研究结果表明,HPAM羧基与Cr~(3+)离子在地面条件下的一次交联作用有利于减少堵剂在油层的漏失量,HPAM酰胺基与有机酚醛在地层条件下的二次交联作用,能够形成耐温高强度凝胶。

The carboxyl groups of HPAM replace the H〓O ligands of AlCA, which results in the formation of HPAM-AlCA gel.

首次用实验证明了:HPAM大分子中与AlCA反应的基团为羧基,酰胺基不参与交联反应。

Amino-2-methylpropanol was used as the chemical modifying reagent of fatty acids to modify the carboxyl group into nitrogen-containing heterocycle which would effectively prevent the migration of carbon double bonds of the alkenyl in the electron impact source.

以2-氨基-2-甲基-丙醇为脂肪酸的化学修饰试剂,气相色谱-电子轰击质谱分析葵子油脂肪酸。2-氨基-2-甲基-丙醇将脂肪酸羧基修改为含氮杂环,使在EI源中避免了链烯基中碳碳双键的移动。

In this paper, the effect of modifying procedure of the GC electrode on the electrode reaction kinetics of benzoquinone and the modified mechanism of enzyme electrode havebeen studied.

玻碳电极经电化学氧化处理,可提高苯醒电子中继物电极反应的可逆性,其原因在于电极表面氧化生成的羧基与醌基之间形成氢键,提高了电极表面电子冲继物的浓度,降低了异相电荷传递的活化

At the same time, the data of tatal acidic group, phenolic hydroxyl group and carboxy were obtained.

给出了各种原料煤腐植酸中总酸性基、羧基、酚羟基的分析数据。

The results of the analysis of the pectin extracted show ed that the degree of free and Salted forms, the degree of amide substitution,and the degree of esterification of carboxy groups were 85.1%, 1.1%, and 13.8%,...

我们对蚕粪果胶的分析表明,其羧基的游离及成盐程度、酰胺化程度、酯化程度分别为85.1%、1.1%和13.8%,甲氧基含量、半乳糖醛酸含量分别为1.79%和81.5%;特性粘度为267。

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