羟基酸

At first,the intermediate of sodium 3-chloro-2-hydroxy propanesulfate was synthesized from epichlorohydrin and sodium bisulfite;And then,using NaOH as a catalyst,the title compound has been synthesized from intermediate and allyl alcohol to reach the yield of about 70%.

先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠，然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。

two kinds of ash-less and phosphorous-free compounds, referred to as boma and loma, as lubricating oil additives, were synthesized to replace or partially replace zddp. they were characterized by means of infrared spectroscopy, mass spectroscopy and element analysis.

合成了两种无灰无磷抗磨添加剂：不含三嗪环的含羟基羧酸酯衍生物boma；含羟基的三嗪羧酸酯衍生物loma，分别用元素分析和红外光谱对分子结构进行表征。

Water,butylene glycol,cyclomethicone,VP/VA copolymer,glyceryl stearate,glycerin,ppg-15 stearyl ether,titanium dioxide,propylene glycol,cetyl alcohol,citrus aurantium dulcisfruit extract,saccharide isomerate,biosaccharide gum-1,ethoxydiglycol,peg-40 stearate,glycyrrhiza glabraroot extract,morus bombycis root extract,potassium cetyl phosphate,phenoxyethanol,c12-20 acid peg-8 ester,triethanolamine,prunus amygdalus dulcis oil,carbomer,caprylyl glycol,caffeine,disodium edta,methylparaben,chondrus crispus,butylparaben,iris germanica root extract,pentadecalactone,sodium polyacrylate,ethylparaben,sodium hyaluronate,peg-8,propylparaben,citric acid,chlorhexidine digluconate,tocopherol,ascorbyl palmitate,ascorbic acid

水，丁烯二醇，环甲硅脂，VP/VA共聚物，甘油基硬脂酸，甘油，ppg-15 stearyl ether，二氧化钛，丙二醇，十六烷基醇，橙子萃取物，天然异构寡糖， biosaccharde gum-1，乙基氧基乙二醇，聚乙二醇- 40硬脂酸，甘草根提取物，桑白皮根萃取，钾十六烷基磷酸盐，苯氧乙醇，c12-20 acid peg-8 ester，三乙醇胺，甜杏仁油，高分子胶，辛乙二醇，咖啡因，乙二胺四乙酸二钠，对羟基苯甲酸甲酯，卡拉胶，对羟基苯甲酸丁酯，鸢尾花根萃取， pentadecalactone ，聚丙烯酸钠，羟苯乙酯，透明质酸钠，聚乙二醇- 8，羟苯丙酯，柠檬酸，洗必泰葡萄糖酸盐，维生素E，维生素C棕榈酸酯，抗坏血酸

A polyurethane which is obtained from ingredients comprising a high-molecular polyol, an organic polyisocyanate, and a chain extender comprising a specific trifunctional isocyanurate compound having an aromatic hydroxyl group and/or a benzylic hydroxyl group, and which has a crosslinked structure due to the isocyanurate compound.

从包含高分子量多元醇、有机聚异氰酸酯和扩链剂的成分得到的聚氨酯，所述扩链剂包括含芳羟基和/或苄羟基的特定三官能团异氰脲酸酯化合物，并且其由于异氰脲酸酯化合物而具有交联结构。

Ingredients:water,glycerin,caprylic/capric triglyceride, cetyl alcohol ,propylene glycol,glyceryl stearate,panthenol,betaine dimethicone,simmondsia chinensis, rosa rugosa flower extract,allantoin,carbomer,parfum,triethanolamine,tocopheryl acetate,methyl paraben,propyl paraben,creatine,tetrasodium edta,phenoxyethanol,caprylyl glycol,sorbic.

成分：去离子水，甘油，辛酸/葵酸三甘油酯，鲸蜡醇，丙二醇，硬脂酸甘油酯，泛醇，甜菜碱，聚二甲基硅氧烷，霍霍巴油，玫瑰花提取液，尿囊素，卡波姆，香精，三乙醇胺，生育酚乙酸酯，对羟基苯甲酸甲酯，对羟基苯甲酸丙酯，肌酸，乙二胺四乙酸四钠，苯氧乙醇，辛二醇，山梨酸。

In this work , 1,8-octodiol, the starting material, reacted with 40% hydrobromic acid to produce 8-bromooctan-1-ol, with the catalytic action of PPTs, its hydroxyl group was protected by 2,3-dihydropyran. Then it coupled with 1-heptaalkyne, by means of P-2 nickel as catalyst, stereoselectivity catalysis hydrogenated, with the catalytic action of acid to take off extremital 2, 3-dihydropyran which protected hydroxy group, then used PCC to oxidize alcohol into corresponding aldehyde.

以1，8-辛二醇为原料，与40%氢溴酸进行单溴代反应，得到8-溴-1-辛醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应，保护分子中的羟基，再与1-庚炔进行偶联，以P-2镍为催化剂立体选择性催化加氢，酸性条件下脱末端的2，3-二氢吡喃对羟基的保护，使用氯铬酸吡啶盐将醇氧化成醛。

ConclusionThe main components of essential oils are 2,4-bis(1,1-dimethylethyl) phenol (4.4%), tetradecanoic acid (6.96%), n-hexadecanoic acid (7.69%), 9,12-cctadecadienoic acid (6.37%), hexadecanoic acid-2-hydroxy-1- ethyl ester (4.79%) and octadecanoic acid-2-hydroxy-1- ethyl ester (4.77%), respectively.

结论阿给炭挥发油的主要成分为2，4-二树丁基苯酚（4.4％）、十四酸（6.96％）、n-十六酸（7.69％）、-9，12-十八碳二烯酸（6.37％）、软脂酸-2-羟基-1-羟甲基乙酯（4.79％）、硬脂酸-2-羟基-1-羟甲基乙酯（4.77％）。

And the ability of antioxidant of polyhydroxy benzamides don't have too many differences with Trolox (IC50 =13.90 μg/ml), the substition of hydroxy group at amino benzene ring doesn't affect the whole ability of antioxidant apparently, but while the single hydroxy group at carboxylic acid benzene ring, they are apparently decrease to scavenge the ability of free radical, as a result, the hydroxy at amino benzene ring substitutes its function, without the hydroxy group, the ability of antioxidant is worst, but it upgrades its function while the hydroxy and amino are in the ortho-position or para-position.

而当多酚醯胺化合物其抗氧化能力与Trolox差不多时(IC50 =13.90 μg/ml)，胺基苯环上之羟基取代对整体抗氧化能力影响不明显，但在羧酸苯环上具单羟基时，其清除自由基能力明显下降，使得胺基苯环上羟基取代发挥了影响力，无羟基取代时，抗氧化能力最差，而羟基与胺基互为邻位或是对位时较间位有提升效果。

They were two new compounds, [cyclo(Pro-Val-Phe-Phe-Pro-Val-Phe-Ser-Leu),7],[2-N-(1-methoxycarbonylethyl)guanosine, 10], and eight known compounds,(p-hydroxybenzoic acid, 1),(methyl succinate, 2),(russulaceramide, 3),(phenylalanine, 4),(guanine, 5),(β-carboline, 6),(uridine, 8), and (adenosine, 9). All the compounds were isolated from Amanita exitialis for the first time.

分别为：对羟基苯甲酸(p-hydroxybenzoic acid，1)、丁二酸二甲酯(methyl succinate，2)、神经酰胺(russulaceramide，3)、苯丙氨酸（phenylalanine，4）、鸟嘌呤核苷(guanine，5)、β-咔啉(β-carboline，6)、环（脯氨酸-缬氨酸-苯丙氨酸-苯丙氨酸-脯氨酸-缬氨酸-苯丙氨酸-丝氨酸-亮氨酸） [cyclo(Pro-Val-Phe-Phe-Pro-Val-Phe-Ser-Leu)，7]、尿嘧啶核苷(uridine，8)、腺嘌呤核苷(adenosine，9)、2-N-(1-甲氧羰基乙基)鸟苷[2-N-(1-Methoxycarbonylethyl)guanosine， 10]。10个化合物均为首次从致命鹅膏中分离得到，其中化合物7和10为新化合物。

The main intermediates were detected during decomposition,such as acetic acid,oxalic acid,malonic acid,phenol,3-hydroxyhypnone,naphthalene,benzene sulfonic acid,phthalic acid,β-naphthalene etc . by ultraviolet-visiblespectroscopy,ion chromatographand gas chromatograph coupled with mass spectrophotometertechniques.The possible degradation pathway of Acid Orange Ⅱ was also speculated,that was,hydroxyl radical reacted with the azo linkage-bearing carbon of naphthol-ring,and the C—N cleaved,the azo-dye decolored and mineralized.

运用紫外光谱、离子色谱、色谱-质谱联用等方法，测定出酸性橙Ⅱ的主要降解产物有乙酸、乙二酸、丙二酸、苯酚、3-羟基苯乙酮、萘、苯磺酸、邻苯二甲酸、β-萘酚等，并依此推测酸性橙Ⅱ的降解机理，即羟基自由基攻击酸性橙Ⅱ分子上与萘环相连的C—N键，导致C—N键的断裂，进而染料脱色矿化。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。