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羟基酸

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During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时,先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外,又研究了影响该反应的几个重要因素:亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4:1;稳定剂2-甲基-2-丁烯的用量至少大于2:1,通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出,获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

With regard to the biological activities of paeonol and sodium paeonol sulfonate, we studied their inhibitory effects on phytopathogen and their activities of scavenging O2-and OH.

实验结果显示,丹皮酚磺酸钠的纯度为99.4804%,化学结构为2-甲氧基-4羟基-5-乙酰基苯磺酸钠。

Ten kinds of metal and three kinds of organic templates, including ethylenediamine, 1,4-butylenediamine and pyrazine were used in the synthesis of metal phosphonate coordination polymers.

在所合成的16种金属有机膦酸盐配位聚合物中,有机配体为2-羟基乙酰基膦酸,用于配位的金属离子共10种,模板剂3种分别为乙二胺(en,1,4-丁二胺,哌嗪。

Connecting with the character of ESR spectra at 77K andcalculated LUMOs, HOMOs the linear relationship between spin transfer efficiencyand molar ratios of nucleotide in DNA to sinapic acid or sinapine provides quantitativeevidence of long range electron transfer within mixed aggregates.

将低温获取的电子自旋共振波谱与DNA组分及羟基肉桂酸衍生物的前线轨道能量相关联,依据自旋自DNA向芥子酸及其衍生物的转移效率与核苷酸和后者摩尔比的线性关系揭示混合堆集物中电荷长程传递的证据。

RESULTS: Four constituents were elucidated as β-sitosterol, eriantic acid B, 2α, 3α, 24-trihydroxyurs-12-en-28-oic acid and daucosterol.

结果:分得4个化合物,分别鉴定为β-谷甾醇,毛花猕猴桃酸B,2α,3α,24-三羟基-12-烯-28-乌苏酸和胡萝卜苷。

Various chrome complex dyes(1:1 ratio) of mordant black 1,mordant black 7,mordant black 9 and mordant black 11 have been synthesized and sodium dichromate is been used as mordant agents instead of Cr3+ to oxidate dyes sufficiently.

还设计合成了媒介黑1、媒介黑7、媒介黑9和媒介黑11的高水溶性1∶1络合染料,重铬酸钠作为铬化试剂,染料得到了充分的氧化,无色配体多羟基羧基酸的引入使染料有很好的水溶性,该实验路线未见报道。

The properties of zinc stannate and zinc hydroxystannate as flame retardant and smoke suppression agents are briefly introduced.

简要介绍了阻燃抑烟剂锡酸锌和羟基锡酸锌的性质,综述了它们的制备方法、应用范围及阻燃和抑烟机理的研究进展。

Rare earth luminescence materials of alkaline earth stannates have also been prepared via thermal decomposition of hydroxo stannate precursors.

利用某些新型带羟基的碱土锡酸盐作为前驱体,固相反应合成掺稀土的锡酸盐发光材料。

Using 1-amino-2-phenoxy-4-hydroxyanthraquinone, chlorosulfonic acid ,thionyl chloride,and 3-ethoxypropylamine as raw materials and sodium carbonate as acid-binding agent,C.

以1-氨基-2-苯氧基-4-羟基蒽醌、氯磺酸、氯化亚砜、3-乙氧基丙胺为原料及Na2CO3为缚酸剂合成了C.I。分散红92。

It demonstrated that the hydroxy organic acids substituted with-OH,-SH at α—C such as lactic acid, Hydroxy-acetic acid, mercapto-acetic acid, glyconic acid have good selectivity for separation of hematite and aegirine pka values of organic acids fall down because of the-I inductive effect of-OH or-SH, and lie at the pH range between two minerals point-zero-charge. As a result, the depression ability of them was enhanced, and a cyclo-pentyl chelate was formed when this organic acids acted with Fe〓 on the minerals surface.

发现在α位具有-OH、-SH等取代基的短链一元羧酸(乳酸、羟基乙酸、巯基乙酸,葡萄糖酸)对赤铁矿与钠辉石的浮选分离具有优良的选择性抑制作用,-OH、-SH的-I诱导效应导致有机酸的pKa值下降并落在两种矿物零电点之间,使其抑制性能增强,并与矿物表面的Fe〓形成稳定的五元螯合环。

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