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羟基酮

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The oxidationresistant experiments were studied by refined flavones, such as reducing power, antioxidation actions to axunge, scavenging action to superoxide anion, scavenging action to hydroxyl free radical.

利用精制后的沙棘总黄酮进行了还原能力的测定、抗猪油氧化、清除超氧阴离子自由基和清除羟基自由基实验,实验结果表明沙棘黄酮有良好的抗氧化能力。

The oxidationresistant experiments were studied by refined flavones, such as reducing power, antioxidation actions to axunge, scavenging action to superoxide anion, scavenging action to hydroxyl free radical. And the results showed total flavones of Hippophae had well oxidationresistant ability.

利用精制后的沙棘总黄酮进行了还原能力的测定、抗猪油氧化、清除超氧阴离子自由基和清除羟基自由基实验,实验结果表明沙棘黄酮有良好的抗氧化能力。

Based on the molecular structures, sugar alcohols can be classified into Mono sugar alcohol (such as erythritol, xylitol, sorbitol and mannitol ) and Disaccharide alcohol (such as maltitol,lactitol and isomaltitol).

糖醇是醛糖或酮糖的羰基经氢化还原成羟基的多元醇;按其结构可分为单糖醇(如四元赤藓糖醇、五元木糖醇、六元山梨糖醇和甘露糖醇),双糖醇(如麦芽糖醇、乳糖醇、异麦芽酮糖醇)。

Efficacious drugs were made of these species for treatment of cough, phlegm, breathe heavily, especially, to cure lung disease. We have investigated on the Chemical constituents of Adenophora stenanthina subspecies xifengsis collected from Gansu Qingyang, and twenty four compounds were isolated from ethanol extraction by chromatography technigues. Twenty compounds were identified by means of chemical and spectra methods(IR, FAB-MS, EI-MS,〓,〓, DEPT , among which three compounds were new as 3βvanilloyloxy-stigmast-5-ene-7β-one; 3β-Vanilloyloxy-stigmast-5-en-7 β-ol; 3β-vanilloyloxy-stigmast-5-en-7β, 15 〓-diol.

我们对采自甘肃庆阳的西峰沙参Adenophorastenanthina subsp.xifengensis)进行了化学成分的研究,利用现代层析手段从该植物的乙醇浸膏中分离出二十四个化合物,经化学方法和波谱技术(红外,质谱,核磁共振谱)鉴定了二十个化合物的结构,其中三个为新的化合物,它们分别是:豆甾-5-烯-7-酮-3β-香草酸酯;7β-羟基-豆甾-5-烯-3β-香草酸酯;7β,15ξ-二羟基-豆甾-5-烯-3β-香草酸酯。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水,c12-20 acid peg-8 ester,辛基十二烷醇,鲸蜡硬脂醇异壬酸酯,丁烯二醇,多醣物质,PEG-40氢化蓖麻油,4-甲氧基肉桂酸-2-乙基己基酯,苯氧乙醇,十六烷基磷酸钾,澳洲胡桃子油,地美司康,卡波姆,丙烯乙二醇,甘油硬脂酸,椰油脂酸甘油酯类,牛油果,c12-13烷醇乳酸酯,对羟基苯甲酸甲酯,二苯甲酮-3 ,环十五内酯,山梨酸,甜橙油,氢氧化钠,维生素E醋酸酯,乙二胺四乙酸二钠,鸢尾花萃取,维他命A酯,问荆萃取,对羟基苯甲酸丁酯,聚乙二醇- 8,羟苯丙酯,羟苯乙酯,透明质酸钠,洗必泰葡萄糖酸盐,苦橙油,维生素E ,维生素C棕榈酸酯,柠檬酸,抗坏血酸,柠檬精油,沉香醇水:几乎所有护肤品成分第一位都是水。辛基十二烷醇:界面活性剂、乳化剂、稠化剂,有一定刺激性

Sixteen compounds were separated from 80% ethanol extract of Plant A, they were:-lariciresinol,-isolariciresinol,-isolariciresinol 9-O-β-D-glucopyranoside, tanegoside B, apiginin, apigenin 7-O-β-D-glucoside, apigenin 7-O-β-neospheroside, quercetin 3-O-β-D-glucopyranoside, 1, 7-dihydroxy-3, 4-dimethoxyxanthone, 3-O- [α-L-rhamnopyranosyl (1-4 ] -β-D-glucopyranoside-(25S)-5β-spirostan-3β-ol , 3β-O-D-glucopyranoside quinovic acid, mangiferin , 3'-p-hydroxybenzoyl-mangiferin, physcion, benzenyl methanol β-D-glucopyranoside and Vanillic acid.

结果: 1。从植物A的80%乙醇提取物中共分离得到16个化合物,分别为:-落叶松脂醇、-异落叶松脂醇、异落叶松脂醇9-O-β-D-吡喃葡萄糖苷、tanegoside B、芹菜素、芹菜素7-O-β-葡萄糖苷、芹菜素7-O-β-新橙皮糖苷、槲皮素3-O-β-D-吡喃葡萄糖苷、1,7-二羟基-3,4-二甲氧基-口山酮、菝葜皂苷元-3-O-[α-L-吡喃鼠李糖基(1-4)]-β-D-吡喃葡萄糖苷、喹诺酸3β-O-D-葡萄糖苷、知母宁、3′-对羟基苯甲酸-知母宁、大黄素甲醚、苯甲醇-β-D-吡喃葡萄糖苷、香草酸。

The free radical scavenging properties of six Aloe species are to be investigated in some modified chemical system. The antioxidant was purified by silica column and thin layer chromatography and analyzed by HPLC. A fraction was purified from A. brevifolia Mill showed the most effective scavenging activities on 〓 and ·OH (66. 01% and 38. 98% respectively). With the analysis of IR spectrum, UV spectrum and mass spectrum, the structure of FA was identifed as 8-C-D-glucopyranosyl-2- [2-hydroxy] propyl-5-methyl-7-hydroxychromone. Its scavenging activity on free radicals is higher than that of aloe-emodin. Its antioxidant activity may be due to the phenoxyl on glucosyl chromone which can be react with free radicals and form relatively stable free radicals.

本研究利用分别产生超氧阴离子自由基和羟自由基的化学模型体系研究比较了不同品种芦荟提取物的清除活性氧自由基的抗氧化作用,进一步利用硅胶柱结合薄层层析法和反相高压液相色谱法,从短叶芦荟叶子中首次分离了具有较强自由基清除能力(超氧阴离子自由基和羟自由基清除率分别为66.01%和38.98%)的成分FA,利用红外光谱、紫外光谱和质谱等仪器分析结果推断出该活性成分的分子结构为8-C-吡喃葡萄糖-2-[2-羟基]-丙基-5-甲基-7-羟基对氧萘酮,它的自由基清除能力高于芦荟大黄素,是一种天然抗氧化剂。

In the second part of the thesis, we discussed a L-proline-catalyzed direct Aldol reaction between L-amino acid-derived N,N-dibenzyl -amino aldehydes 15 and acetone, cyclopentanone or hydroxyacetone, which afforded (-amino--hydroxy- or (-amino-,(-dihydroxy-ketones in good to excellent yields (up to 94%) and diastereoseletivities (up to 94.9%).

发现许多情况下,反应的产率和de值超过90%。接着,在碱性条件下,我们将L-亮氨酸衍生的N,N-二苄基--氨基醛15g与羟基丙酮反应得到的主要产物(,-二羟基-γ-氨基酮171d与次溴酸钠反应,得到了具有抗肿瘤活性的天然产物PM-94128的氨基酸片断184。

Evaluation of some Mannich bases of conjugated styryl ketones and related compounds versus the WiDr colon cancer in vitro.

朱志宏,徐秀娟。2,4-二羟基-3-芳氨基甲基苯乙酮和8-乙酰基-3-芳基-3,4-二氢-5-羟基-2H-1,3-苯并噁嗪的合成及其相互转化。

The main intermediates were detected during decomposition,such as acetic acid,oxalic acid,malonic acid,phenol,3-hydroxyhypnone,naphthalene,benzene sulfonic acid,phthalic acid,β-naphthalene etc . by ultraviolet-visiblespectroscopy,ion chromatographand gas chromatograph coupled with mass spectrophotometertechniques.The possible degradation pathway of Acid Orange Ⅱ was also speculated,that was,hydroxyl radical reacted with the azo linkage-bearing carbon of naphthol-ring,and the C—N cleaved,the azo-dye decolored and mineralized.

运用紫外光谱、离子色谱、色谱-质谱联用等方法,测定出酸性橙Ⅱ的主要降解产物有乙酸、乙二酸、丙二酸、苯酚、3-羟基苯乙酮、萘、苯磺酸、邻苯二甲酸、β-萘酚等,并依此推测酸性橙Ⅱ的降解机理,即羟基自由基攻击酸性橙Ⅱ分子上与萘环相连的C—N键,导致C—N键的断裂,进而染料脱色矿化。

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