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Therefore, we started hydroxy benzene acetic acid and acetic acid coordination unit for the nodes of copper, cobalt, cadmium, manganese, zinc coordination polymers of structural chemistry studies.

因此,我们开展了苯羟基乙酸和苯氧乙酸配位单元为节点的铜、钴、镉、锰、锌配位聚合物的结构化学的研究。

This article through the belt hydroxyl aldehyde class material and the chloroacetic acid response, the synthesis intermediate, then with the neighbouring phenylene diamine responded again synthesized 6 kind of benziminazole class compound, including 4 kinds not to report.

本文通过带羟基的醛类物质和氯乙酸的反应,合成中间体,然后再与邻苯二胺反应合成了6种苯并咪唑类化合物,其中有4种还未被报道。

Benzyl bromide was synthesized from potassium bromide ,a by-product from synthesis of 2-hydroxy-4-n-octyloxybenzophenone(UV-531),and benzoic alcohol in the presence of concentrated sulfuric acid.

溴化钾作为工业生产2-羟基-4-正辛氧基二苯甲酮的副产品,在浓硫酸存在的条件下,与苯甲醇进行反应合成苄基溴。

In ethylene glycol solution, 1 was converted into 1-oxo-13c-(2-hydroxyethoxy)-1, 13c-dihydro-dibenzo -xanthene (23) and ketal compound 7a, 13bethylenedioxy-1-hydroxy-7a, 13b-dihydro-dibenzo -xanthene (24), the structure of which was confirmed by X-ray single crystal diffraction.

在乙二醇中反应时,1被氧化为二苯并咕吨型的23和缩酮型的7a,13b-亚乙二氧-1-羟基-7a,13b-二氢-二苯并-咕吨(24)。24的结构得到X-ray单晶衍射的证实。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(α,ω-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4 '-alkoxyl azobenzene as the monomers.

摘 要 以4,4′-二苯甲氯和2,4-二羟基-4′-烷氧基偶氮苯为单体,通过溶液聚合,合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(,-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4'-alkoxyl azobenzene as the monomers.

以4,4′-二苯甲酰氯和2,4-二羟基-4′-烷氧基偶氮苯为单体,通过溶液聚合,合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

The four reaction channels including hydroxyl-type benzaldoxime are endothermic reaction, thermodynamically non-spontaneous process, but the other four reaction channels including ion-type benzaldoxime participation are exothermic reaction and thermodynamically spontaneous process. The latter four reaction channels, which have lower reaction barriers, faster reaction velocities and bigger equilibrium constants than those of the former fours, are the chief reaction channels.

苯甲醛肟以羟基型参与反应的4个反应通道均为吸热反应和热力学非自发过程,它们均具有较高的反应势垒、较慢的反应速率和较小的平衡常数;而以离子型参与反应的四个反应通道均为放热反应和热力学自发过程,它们的反应势垒较低,反应速度较快,平衡常数也较大,故苯甲醛肟应主要以离子型参与反应。

Quinone methides, generated in situ from the reaction of 4-hydroxycoumarin with benzaldehyde, formaldehyde and pentanal, underwent the Diels-Alder reaction with silyl enol ethers to give a series of 3,4-dihydro-2H,5H-pyrano[3,2-c][1]benzopyran derivatives in high yields.

通过4-羟基香豆素与苯甲醛、甲醛和戊醛缩合产生的quinone methide与烯醇硅醚的Diels-Alder反应,以较高产率合成了一系列含有硅氧基的3,4-二氢-2H,5H-吡喃并[3,2-c][1]苯并吡喃-5-酮衍生物。

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是,超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解,这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

Fourteen new pyrethroids containing isoxazole were designed and synthesized from 4-isopropyl-3-substituted phenyl-5-hydroxyl isoxazoles as major material, whose structures were also characterized by IR, 1H NMR and elemental analysis.

以4-异丙基-3-取代苯基-5-羟基异噁唑和3-苯氧基苄基溴为原料,三乙胺为缚酸剂,设计并合成了14个未见报道的4-异丙基-3-取代苯基-5-异噁唑基-(3'-苯氧基)苄基醚。通过红外光谱、核磁共振、元素分析等手段,确证了它们的化学结构。

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