羟基化反应

Anisaldehyde was synthesized from p-hydroxybenzaldehyde with dimethyl carbonate by microwave irradiation under phase transfer catalyst tetrabutylammonium bromide, The effect of power, time, solvent and catalyst of reaction on yield were researched.

以四丁基溴化铵为相转移催化剂，采用对羟基苯甲醛和碳酸二甲酯为原料，微波辐射下合成大茴香醛。考察了反应溶剂、功率、时间和催化剂对反应产率的影响。

Six novel dihydrobenzofuran and benzofuran neolignans compounds(1～6) were synthesized by knoevenagel reactiton,esterfication, biomimetic oxidative coupling ,DDQ dehydrogenation,reduction and hydrolysis with 4-hydroxybenzaldehyde and malonic acid as starting material.

以对羟基苯甲醛和丙二酸为原料，经Knoevenagel缩合反应，酯化、仿生氧化偶联、DDQ脱氢、还原和水解等反应步骤，合成了6种未见文献报道的苯并二氢呋喃新木脂素和苯并呋喃新木脂素类化合物(1~6)。

2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料，通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3，4-二氢-1-异喹啉酮类化合物。

A series of crosslinked sulfonated polys were synthesized from 4,4'-difluorodiphenyl sulfone, 4,4'-biphenol, 3,3'-disulfonate-4,4'-difluorodiphenyl sulfone and 1,3,5-trihydroxy benzene by nucleophilic substitution polycondensation reactions. The trifunctional crosslinker of THB was in the mass fraction range of 3%-7%.

以4，4'-二氟二苯砜、4，4'-联苯二酚、3，3'-二磺化－4，4'-二氟二苯砜二钠盐和三羟基苯为原料，经高温溶液缩聚反应，制备了一系列不同磺化度的新型交联磺化聚芳醚砜。

First, the preparation of the aminom ethylation of tannin using its electrophilic reaction activity of C-6, C-8 in ring-A; then process the quaternization base on the aminom ethylation; last, progress the sulfonation by use of the activity of phenolic hydroxyl hi ring-B.

首先利用单宁A环的C—6、C—8的亲电反应活性制备单宁胺甲基化产物；然后在胺甲基化的基础上进行季胺盐化；最后利用单宁B环的酚羟基的活性进行磺化。

Thiol groups were good to be used in functionalizing gold nanoparticles, and ester bond formation and breakage played the major role in this research. Thioctic acid and 11-mercapto-1-undecanol were used to functionalize the gold nanoparticles and form ester bond by using the carboxylic acid group on thioctic acid and the hydroxyl group on 11-mercapto-1-undecanol. Concentrated sulfuric acid was used to be the catalyst in this reaction, and sodium hydroxide was added for the proceeding of the reverse reaction.

硫醇官能基在金奈米粒子的修饰有很好的效果，利用带有硫醇官能基之tioctic acid 与11-mercapto-1-undecanol (11-MUDO)分子修饰在金奈米粒子上，并使TA上之羧基和11-MUDO上之羟基脱水生成酯化键，浓硫酸则是反应中的催化剂，而氢氧化钠则可促使系统进行逆反应。

The optimal conditions for the target product were obtained: reaction temperature 110 ℃, reaction time 1.5 h, NaOH dosage 1.2 g,molar ratio 3:1(disproportionated rosin glycide ester: the hydroxyl group per D-glucose unit), microwave power 700 W.

目标产物的最佳合成条件：反应温度110℃，反应时间1.5 h，NaOH用量1.2 g，摩尔比3：1（歧化松香缩水甘油酯：葡萄糖单元中羟基数）及微波功率700 W。

MIPC was photocatalytically transformed to 3,4-dihydroxyl hypnone, 2-iso-butyl phenol and acetic acid, and mineralized ultimately in oxygenated TiO2 slurries. The photocatalytic degradation processed according to first order kinetics with the apparent rate constant depending on initial concentration, light intensity and the amount of catalyst. The amount of catalyst had an optimum value (0.5g/L). The apparent rate was inversely proportional to square root of the initial concentration approximately.

MIPC能被光催化转化成3，4-二羟基苯乙酮、2-异丁基苯酚和乙酸等产物并最终被矿化，MIPC的光催化反应过程符合一级动力学规律，其表观速率常数与MIPC的起始浓度、TiO2量和光强等因素有关，MIPC降解的反应速率与入射光强成正比，与MIPC初始浓度的平方根成反比。

Chloro-5,12-naphthacenequinone was synthesized from 2-(1-hydroxy-2-naphthyl)carbonylbenzoic acid by chlorination reaction using a mixture of phosphorus pentachloride and phosphorus oxychloride as a chlorating agent and then by ring-closing reaction using sulfuric acid as a dehydrating agent.

以2-[(1-羟基-2-萘基)羰基]苯甲酸为原料、五氯化磷/三氯氧磷为氯化剂进行氯化反应，然后用浓硫酸脱水环化，合成了6-氯-5，12-萘并萘醌，优化了反应条件，总收率达68.2%。

Pentanediol reacted with phosphorus tribromide to make it mono-bromination, under the catalytic action of PPTs it reacted with 2,3-dihydropyran to protect another hydroxy group, then to react with triphosphine, produced quarterphossal.

再以1，5-戊二醇为原料，三溴化磷使之单溴代，得到5-溴-1-戊醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应保护其另一端的羟基，与三苯基膦反应生成季磷盐。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。