羟基化反应

There six chapters in this dissertation: the overview on the study of probing for reactive oxygen species, spin-labelled fluorophore as probe for free radicals, Fe -EDTA chelate-induced aromatic hydroxylation of terephthalate as a new method for the evaluation of hydroxyl radical-scavenging ability, study of fluorimetric method for the determination of peroxynitrite, study of spiro-formed rhodamine B hydrazide as a novel fluorescent probe in analytical chemistry, the conclusion and prospect of the present research work.

本论文分六章，包括生物活性氧表征的研究进展、自旋标记荧光探针表征自由基的研究、利用Fe-EDTA引发对苯二甲酸芳环羟基化反应评价抗氧化剂清除羟基自由基能力的研究、荧光法表征过氧亚硝酸根的研究、螺环型罗丹明B酰肼化合物作为新型荧光探针的性质及应用的研究、结论与展望。

Strong acids, such as sulfuric acid, hampered from the occurrence of the phenol hydroxylation.

过强的酸，如硫酸、硝酸和盐酸，对苯酚羟基化反应造成危害，使羟基化反应不能发生。

Under these conditions, photodegradation of MO mainly involves three intermedial processes: demethylation, methylation and hydroxylation.

其中，最先发生的是脱甲基化反应，而生成产物最多的是羟基化反应。

In the frist part, it was simply summarized that the application of microbial transformation and the two important reactions:side chain cleavage and hydroxylation of steroid respectively.

第一部分，首先对微生物转化技术的应用和两个重要的甾体转化反应-甾体边链降解反应和甾体羟基化反应进行了简要综述。

The oxides with spinel and peroskite structure are the key active components for phenol hydroxylation, and higher contents of them have the higher reaction activity.

形成的尖晶石或钙钛矿结构为苯酚羟基化反应的活性相，具有良好晶态的复合氧化物催化剂的反应活性较高。

The AM1 method was used for a quantum chemistry study of the phenol hydroxylation reaction mechanism. The possible reaction path of the phenol and oxyhydrogen free radical was optimized, and the structures of stable intermediates in the reaction mechanism were also obtained.

本文还首次采用AM1方法对苯酚羟基化反应机理进行了量子化学研究，将苯酚与氢氧自由基的反应沿可能的反应路径进行几何优化，得到反应历程上相关驻点稳定构型的三维结构。

The result indicates thato-PD is converted to one trimer with ca.

羟基自由基抑制剂和氧合血红素物种抑制剂尿酸都不抑制该氧化反应，这些结果表明邻苯二胺的羟基化反应没有包括在其氧化过程中。

The experiments also show that adding NaHSO3 into the reaction liquid of hydroxylation reaction can inhibit the catalytic effect of benzoquinone and residual catalyst on the phenolic tars formation caused by oxo-condensation of the diphenols and therefore reduce the tars formation of the diphenols in the reaction solution.

在羟基化反应液中加入亚硫酸氢钠可以抑制对苯醌和残留催化剂对苯二酚氧化缩合生成焦油的催化作用，从而减少了反应液中苯二酚的生焦反应。

Several types of ligand reactions observed under hydrothermal condition were summed up:(1) hydrolysis of pyridine nitrile, aldehyde and ester in mixed water and alcohol into pyridine-carboxylate;(2) replacement of carboxylate group with sulfonic group;(3) coupling of phenanthroline by dehydrogen;(4) oxidative coupling of methanol into oxalic acid;(5) hydroxylation of isophthalate.

总结了以往在水热条件下观察到的几类配体反应：（1）吡啶腈、醛和酯在醇和水混合溶液中水解成吡啶羧酸；（2）磺基取代羧基反应；（3）邻菲啰啉的脱氢的聚合：（4）甲醇被氧化偶合生成草酸：（5）间苯二甲酸的羟基化反应。

Triphenylmethyl chloride can react selectively with the 30-hydroxil group of glycyrrhetol under the catalyzing effects of three ethyl amine and dimethyl amino-pyridine.This condition of the reaction has an important value for the selective protection of 30-hydroxil group of glycyrrhetol.

三苯氯甲烷在三乙胺和二甲氨基吡啶等碱性催化下与甘草萜醇的C30-位羟基进行选择性缩合反应，此反应产率较与C3-位羟基化反应的要高，此种反应条件在甘草萜醇C30-位羟基的选择性保护中具有重要的价值。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。