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In chapter 3, Fe-EDTA chelate-induced aromatic hydroxylation of terephthalate as a new method for the evaluation of hydroxyl radical-scavenging ability was studied.

第三章利用Fe-EDTA引发对苯二甲酸芳环羟基化反应建立了一种评价抗氧化剂清除·OH能力的新型荧光分析法。

The state of Cu species determine the catalytic performance in hydroxylation of benzene.

从XRD、UV-vis和H_2-TPR表征结果可见,催化剂制备中的焙烧温度、Cu的负载量和ZSM-5的硅铝比可以改变Cu物种与载体的相互作用强弱及Cu物种的分散状态,是影响催化剂苯羟基化反应性能的重要因素。

In the frist part, it was simply summarized that the application of microbial transformation and the two important reactions:side chain cleavage and hydroxylation of steroid respectively.

第一部分,首先对微生物转化技术的应用和两个重要的甾体转化反应-甾体边链降解反应和甾体羟基化反应进行了简要综述。

In this dissertation, we studied the catalysts, reaction conditions and mechanism of one-step hydroxylation of benzene to phenol oxidized by molecular oxygen, which is the cleanest and the most economical process.

所以近年来作为一条比较经济的路线,以苯为原料经过一步氧化,直接羟基化生产苯酚的反应吸引了各国研究者的广泛关注,这也是催化化学中最为艰难、最具有挑战性的研究课题之一。

The oxides with spinel and peroskite structure are the key active components for phenol hydroxylation, and higher contents of them have the higher reaction activity.

形成的尖晶石或钙钛矿结构为苯酚羟基化反应的活性相,具有良好晶态的复合氧化物催化剂的反应活性较高。

Meanwhile, when the supported ionic liquid is used in asymmetric dihydroxylation reaction, there was no catalystic activity of osmium catalyst.

离子液体固载于改性后BMMs在不对称双羟基化反应中由于分子筛改性引入的氨基与锇催化剂的配位作用使其失去活性。

The AM1 method was used for a quantum chemistry study of the phenol hydroxylation reaction mechanism. The possible reaction path of the phenol and oxyhydrogen free radical was optimized, and the structures of stable intermediates in the reaction mechanism were also obtained.

本文还首次采用AM1方法对苯酚羟基化反应机理进行了量子化学研究,将苯酚与氢氧自由基的反应沿可能的反应路径进行几何优化,得到反应历程上相关驻点稳定构型的三维结构。

6β-santonin could be selectively reduced and hydroxylated by the cell suspension cultures of P.acinosa, which would provide valuable intermediates for its further structural modification.

结论利用商陆培养细胞可对6β-santonin进行选择性还原及羟基化反应,可为其进一步化学结构改造提供有价值的中间体。

The experiments also show that adding NaHSO3 into the reaction liquid of hydroxylation reaction can inhibit the catalytic effect of benzoquinone and residual catalyst on the phenolic tars formation caused by oxo-condensation of the diphenols and therefore reduce the tars formation of the diphenols in the reaction solution.

羟基化反应液中加入亚硫酸氢钠可以抑制对苯醌和残留催化剂对苯二酚氧化缩合生成焦油的催化作用,从而减少了反应液中苯二酚的生焦反应。

A method of capillary electrophoresis with tris (2,2′-bipyridyl) ruthenium electrochemiluminescence detection has been applied to the simultaneous determination of proline and hydroxyproline in human urine.

1引言胶原蛋白中常含有丰富的脯氨酸和羟脯氨酸,其中Hyp几乎为胶原蛋白所特有。在胶原蛋白代谢中,Pro通过羟基化形成Hyp,胶原蛋白降解释放的Hyp从尿中排泄[1]。

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