羟基化

We found that the iodohydroxylation of 1-2-allenyl selenides with I〓 and water can smoothly proceed in aqueous MeCN at 0℃.

我们发现在乙腈水溶液中，1，2-联烯基硒醚可以和碘发生羟碘化作用，碘和羟基高度区域和立体选择性加成到1，2-联烯基硒醚的β，γ-位。

Firstly, Vinyl ethers were prepared in a one-pot, two-step transformation by O-alkylation reaction of 2-hydroxyalkyl phenyl selenides with primary or secondary organic halides followed by oxidation-elimination with 30 % hydrogen peroxide.

1.2-羟基烷基苯基硒醚和伯、仲卤代烃通过O-烷基化反应，然后用30％的双氧水进行氧化消除反应，提供了&两步、一锅法&合成烯基醚的新方法，该方法反应条件温和，操作简便，产物收率中等到良好(70-85％)。

METHOD:Venlafaxine was synthesized by steps of etherification,acid chloridization,amidation,Grignard reaction,reduction,salifying from 4-hydrophenylacetic acid.

该化合物以对羟基苯乙酸为原料，经醚华、酰氯华、酰胺化格氏反应、还原、成盐等步骤制备而成。

A series of sulfonated poly(phthalazinone ether phosphine oxide)s were prepared via polycondensation of 4-(4-hydroxyphenyl) phthalazinone with sBFPPO and BFPPO.

通过将4-(4-羟基苯基)-2，3-二氮杂萘酮与二(4-氟苯)苯基氧膦和磺化二(4-氟苯)苯基氧膦单体共聚，制备了一系列磺化聚二氮杂萘酮醚三苯基氧膦。

Treatment of pterin (2-amino-4-hydroxy-pteridine) derivatives with N,N-dimethylformamide dimethylacetal [1,(CH 3) 2NCH(OCH 3) 2] usually gave corresponding N 2-(N,N-dimethylaminomethylene)- pterin derivatives in polar solvents.

用N ，N 二甲基甲酰胺缩二甲醇 [(CH3 ) 2 NCH(OCH3 ) 2 ，1]和蝶呤(2 氨基 4 羟基蝶啶)衍生物在极性有机溶剂中反应一般得到脒化产物：N2 (N ，N 二甲基氨基亚甲基)-蝶呤衍生物。

The result shows that the elimination reaction and ring closing reaction are synergistic, and the hydrogen in the elimination reaction derives from hydroxyl. In addition, the activation energy of the reaction is 139.2kJ/mol.

计算结果表明，该反应中的消除反应和成环反应是协同进行的，溴化氢消除反应中的氢来自与O(22)相连的羟基氢，反应的活化势垒为139.2kJ/mol，反应放热25.1kJ/mol。

In this report, half-esterification between these pendent hydroxyl groups of hydroxyl-PU and maleic anhydride could lead to new pendent groups, carboxylic groups. These highly polar carboxylic groups in the side chain of PU could play the role of internal emulsifier. They had self-dissociation ability in the water or were neutralized first by appropriate amount of base. Then, PU bearing carboxylic group could dispersed steadily in the water, named aqueous-based polyurethane dispersion.

在本论文中，利用原来亲油性Hydroxyl PU主链段上悬挂的羟基经由与琥珀酸酐的半酯化(Half-esterification Reaction)反应后，使PU在侧链上悬挂具有强极性的羧酸基，其可作为聚胺酯分子中的内乳化剂，羧酸基能在水相中自身解离产生离子或加入适量碱使之中合，使聚氨酯高分子能够稳定分散於水中，即所谓水性PU分散液(Aqueous-based Polyurethane Dispersion)。

The invention is characterized in that the carrier is produced through the reaction between halogen acetylized crosslinked polystyrene resin and hydroxybenzyl alcohol.

本发明的特征是：该载体由卤乙酰化聚苯乙烯树脂与对羟基苯甲醇反应制得。

The invention adopts halogen acetylized crosslinked polystyrene resin and hydroxybenzyl alcohol as the raw material, and the solid phase synthesis carrier with hydroxymethyl as the active group is synthesized through the joint catalysis of N, N-dimethyl formamide used as the reaction solvent, inorganic base and phase-transfer catalyst.

本发明采用卤乙酰化交联聚苯乙烯树脂和对羟基苯甲醇为原料，在以N，N-二甲基甲酰胺为反应溶剂、无机碱及相转移催化剂的共同催化下合成了一种以羟甲基为活性基团的固相合成载体。

In the case of BDD the mineralisation of the sodium dodecyl benzene sulfonate was achieved in all experimental conditions due to reaction with hydroxyl radicals electrogenerated on the diamond surface during electrolysis.

在这个案例的矿化的钠1 十二烷基苯酯所有实验条件下反应而羟基自由基在金刚石表面溶在意外发生。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。