羟基化

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

The mineralization of gold and silver is zoned and closely related to silicification of carbonate and clastic rocks, so siliceous ore dominates in the deposit.

矿化温度主要在300～170 C之间，成矿流体的主要成分为K~-、Na~-、Ca~(2+)、Mg~(2+)、Cl~。金属配合物的分配计算显示，金在成矿热液中主要以疏氢配合物迁移，而银、铁、铅、锌则以氯配合物为主，铁、铅、锌在成矿后期的中性-弱碱性环境下可转变为羟基和硫氢配合物。

Various chrome complex dyes(1:1 ratio) of mordant black 1,mordant black 7,mordant black 9 and mordant black 11 have been synthesized and sodium dichromate is been used as mordant agents instead of Cr3+ to oxidate dyes sufficiently.

还设计合成了媒介黑1、媒介黑7、媒介黑9和媒介黑11的高水溶性1∶1络合染料，重铬酸钠作为铬化试剂，染料得到了充分的氧化，无色配体多羟基羧基酸的引入使染料有很好的水溶性，该实验路线未见报道。

A computer-aided local transient flow property measuring system was developed using a high speed CCD camera coupled with optical fibers in order to study the Gas-liquid-solid three-phase jet loop reactors. SnO2 crystal films were orientally deposited on the alkoxysilane molecule-coated hydroxyl glass substrates so as to prepare surface-marked particles as the tracers. An image analysis system was established to identify different phases. Stroboscopic photography was utilized to extend the measure range. The developed measuring and analysis system was capable of determining accurately the local transient flow property in a G-L-S jet loop reactor. Based on the above system, local transient flow properties of gas, liquid, and solid phase were measured and studied the influences of fluid property, operation and configuration parameters on the reactor.

以气液固三相喷射环流反应器为研究对象，将高速CCD和光纤束耦合制成局部瞬态流动特性微机数据采集及图象处理系统，利用MPS硅烷分子在带有羟基的玻璃基底上的自组装引导SnO2晶态膜层在功能化表面上进行沉积，以获得表面标记的示踪粒子，解决图象处理技术与相的识别的问题，利用频闪技术拓展了测量上限，得到可以准确测定气液固三相喷射环流反应器中局部瞬态流动特性的测试系统；采用上述测试技术进行喷射环流反应器中局部气相、液相与固相瞬态流动特性的实验研究，并考察物性参数、操作参数与结构参数的影响规律。

OBJECTIVE: To investigate the feasibility of ultrasonic contrast to evaluate the vascularization of HA orbital implants, and to compare with enhanced MRI.

目的：探讨超声造影评价多孔羟基磷灰石血管化程度的可行性，并与增强MRI对照。

XPS and FTIR spectroscopy analysis indicated that chemical bonds were formed between maleic rosin and wood flour through the esterification reaction of anhydride groups and hydroxyl groups on wood surface.

FTIR与XPS分析表明，马来松香分子中的酸酐基团与木粉表面的羟基发生了酯化反应，并且马来松香是以单酯的形式接枝到木粉表面，同时产生－游离羧基。

It was found that ARA was composed of esterification products of (2-HEA)-ester with pimaric acid, dehydroabietic acid, abietic acid and two isomers of acrylpimaric acid. ARA is a good crosslinking agent which can copolymerize with most vinyl monomers. The properties of solvent-resistance and heat resistance of the copolymer were improved considerably by the use of ARA.

实验结果表明：ARA主要由海松酸、脱氢枞酸、枞酸和丙烯海松酸的二种异构体的丙烯酸－2-羟基乙基酯的酯化产物组成，ARA是一种良好的交联剂，可与大多数乙烯基单体共聚合，其与MMA的共聚物的耐溶剂性和耐热性均得到了较大幅度的提高。

In this paper, the synthesis ways and applications of 4,5-dimethyl-l,3-dioxolen -2-one were introduced. An appropriate way synthesizing DMDO from acetoin via acylation, cyclization and dehydrochlorination was selected. The influences of various process conditions on the reaction were studied in detail, and the optimum process conditions were obtained by single factor experiments.

本文介绍了医药中间体4，5-二甲基-1，3-二氧杂环戊烯-2-酮的应用情况和合成路线，选择了适于工业化生产的工艺路线，即采用羟基丁酮为原料，经酰化、环合和脱氯化氢等步骤合成DMDO，并采用单因素试验法详细研究了各项工艺条件对反应结果的影响规律，确定了优化工艺条件。

Emphasis: Aminolysis method of hydroxyl on alcohol, addition amination of epoxy alkyl, aminolysis of aliphatics haloid.

重点：醇羟基的氨解、环氧烷类的加成胺化、脂族卤素衍生物的氨解。

As to the curing reaction of the modified phenolic epoxy resins, there is the etherification reaction between phenolic hydroxyl groups and epoxy groups. When the secondly modified epoxy resins are cured at higher temperatures respectively, the absorbance increasing at 1670Cm〓 and 1640Cm〓 are indicative of aminolysis reaction.

对于改性酚醛环氧树脂的固化反应，有酚羟基和环氧基间的醚化反应，二次改性环氧树脂在较高的温度固化时，1670Cm〓和1640Cm〓吸收峰的增加说明有氨解反应。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。