羟基化

Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水，甘油，氢化聚异丁烯，液体石蜡/矿油，丁二醇，环己硅氧烷，鲸蜡醇，甘油硬脂酸酯，棕榈油，玉米胚芽油，PEG-100硬脂酸酯，白蜂蜡/蜂蜡，肉豆蔻醇肉豆蔻酸酯，石蜡，香精，腺苷，苧烯，山梨醇，CI 14700，CI 19140，稻糠油，杏仁油，EDTA二钠，羟丙基四氢吡喃三醇，苯氧乙醇，聚乙二醇-14M，异十六烷，氢氧化钠，辛基十二醇，季戊四醇四（双-t-丁基羟基氢化肉桂酸）酯，山梨坦三硬脂酸酯，水解大豆蛋白，卡波姆，鸡蛋果籽油，苹果果实提取物，欧洲栗籽提取物，异山梨醇酐二甲醚，聚山梨醇酯-80，辛酰水杨酸，2-油酰胺基-1，3-十八烷二醇，氯苯甘醚，麦芽糖醇，香豆素，黄原胶，微晶蜡，丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物，丙二醇，芳樟醇，香茅醇，玉米油，羟苯丙酯，羟苯甲酯

In addition, when the modified PVA resins fulfilled requirements in the following: 1 the acetalization degree varied from 60 mol% to 80 mol%, 2 the esterification degree varied from 10 mol% to 20 mol%, 3 the amount of hydroxyl group was 5-25 mol%, 4 the range of value of B/P(the mass ratio of the binder to diazo resin) was from 4 to 4.5,5 the range of its molecular weight was from 4×10^5 to 8×10^5, the negative PS plate obtained had excellent sensitivity, hydrophobic property, good developability, good ink receptivity and good scratch resistance.

因此其分子量、酯化度和缩醛度的确定，必须综合考虑各项性能之间的平衡。缩醛度为60-80 mol%，酯化度10-15mol%，羟基5-25 mol%，分子量约为4-8万，B/P为4-4.5时，制得的阴图PS版的感度、显影性、着墨性和耐磨性都较好。

The resultant was hydrogenised to remove protective group of amino group, then the product was reacted with NaNO2 to give diazonium salt, which was conjugated with salicylic acid, hydroxybenzene, N-salicyloyl glycine acid to get azo derivatives of 4-ASA.

本文首先对4-ASA的氨基和羟基进行了选择性保护，通过氢化还原法选择性脱除氨基的保护基，然后将氢化产物制成重氮盐，通过与水杨酸、苯酚和水杨酰甘氨酸发生反应生成4-ASA的偶氮衍生物，最后在碱性条件下水解得到最终产物。

With trimethyl,4-dodecylbenezyl ammonium chloride and 18-crown-6 as pase-transfer catalysts, the azidation of polyepichlorohydrin in poly and H2O were studied. The reaction discipline and mechanism were discussed. The results show that the system with trimethyl, 4-dodecylbenezyl ammonium chloride as phase transfer catalyst and PEG as medium is a safe and effective approach to glycidyl azide polymer preparation, and azidational ratio of PECH can reach 97% above within 15 h.

研究了氯化十二烷基苄基三甲基铵和18-冠－6为相转移催化剂时端羟基聚环氧氯丙烷在聚环氧乙烷和水为介质中的叠氮化反应，探讨了反应规律和反应机理，结果表明：以PECH为介质，十二烷基苄基三甲基氯化铵(TMDA-1)为相转移催化剂的反应体系，可在15h内使PECH叠氮化转化率达到97%以上，无主链断裂等副反应，是一条较为安全快速的制备叠氮粘合剂的方法。

ABSTRACT Immobilized penicillin acylase (from E.coli) was used to catalyze 7 phenylacetamido 3 E propenyl cephalosporanic acid hydrolyzation into 7 amino 3 E propenyl cephalosporanic acid. Then, trans APRA was acylated with hydroxyethyl ester of 4 hydroxy D phenylglycine to obtain trans cefprozil.

以7 苯乙酰氨基 3 E 丙烯基 3 头孢菌素 4 羧酸为原料，在青霉素酰化酶作用下，首先酶法水解得到3 E 丙烯基 3 头孢菌素 4 羧酸，过滤固相酶，滤液调pH分离得到反式APRA固体；在青霉素酰化酶作用下，反式APRA再与对羟基苯甘氨酸乙二醇酯缩合，得到反式头孢丙烯；酶法合成所得的产品与进口反式头孢丙烯对照品一致。

Results showed that the hybrid monomer could photopolymerize effectively and both free radical and cationic polymerization processes were improved. When 2-Hydroxy-2-methyl-1-phenyl-1-propanone (1173) was introduced into hybrid system containing UVI-6976, the final conversion of propenyl ether double bond and polymerization rate increased obviously. The comparison of photopolymerization kinetics between hybrid and blend system was investigated as well.

结果表明，以硫鎓盐为光引发剂时，这三种杂化单体均可以有效进行杂化光聚合反应，丙烯基醚和丙烯酸酯双键都显示出较快的反应速度和较高的最终转化率，同时在简单结构的硫鎓盐（UVI-6976）引发体系中加入自由基引发剂2-羟基-2-甲基-1-苯基-1-丙酮（1173）后，丙烯基醚双键的阳离子聚合速率和最终转化率都有了很大提高。

The excited-state intramolecular proton transfer tautomerism reaction of 6-methyl-4-hydroxy pyri-midine monomers and dimmers was investigated by the ab initio method with the self-consistent reaction field with Tomas's polarized continuum mode and CIS theories at HF level on the basis of 6-311+G* and 6-31G basis set. By studying the potential energy surface, it was found that the monomer's ground-state proton transfer process together with the excited-state proton transfer process is a molecular system of four energy level, but dimmers were not, which can be used to explain the fact that UV-visible absorption and fluorescence spectra of monomer and dimers all corresponded to quinoid.

采用 ab initio HF理论的组态相关CIS方法和连续溶剂模型PCM，分别在6-311+G*和6-31G水平上研究了6-甲基-4-羟基嘧啶单体及二聚体激发态质子转移的异构化反应；对其反应势能面的研究发现，单体基态和激发态的异构化反应一起可以形成四能级的分子电子体系，而二聚体的却不能，由此解释了单体和二聚体的紫外吸收光谱和荧光发射光谱均对应于酮式构型的原因。

The results show that: the functional groups in coal are the function of coal rank , and the yields of CO 2, H 2O and CO are related to the content of carboxyl, hydroxyl and other oxygen containing groups such as ether groups in coal, and Tar and CH 4 are related to the aliphatic CH, the char yields to the aromatic CH.

借助化学分析和FTIR光谱分析对我国煤化程度不同的18 种煤中官能团的研究表明：煤中官能团含量与煤化程度有关；煤中羧基、羟基及醚键等其他含氧官能团的含量与热解生成物CO2、H2O 和CO 的产率有关，脂肪—CH 的含量与甲烷和焦油的产率相关联，芳香—CH 的含量与热解半焦产率有关。

In the cyclization process,α-acylamino radicals preferred to attack acylsilanes from the face opposite to the β-substituent, and the stereoselectivity of the bridgehead is excellent. The orientation of the hydroxy group formed in the cyclization process was mainly exo.

生物碱架桥上立体化学的建立，可透过环上取代基立体障碍的影响，使得环化过程只会从立障较小的一面进行，因此可得到单一立体化学的结果，而环化所形成的羟基则是以exo的产物为主。

The terminal allylation reaction was studied which was influenced by reaction time, reaction temperature, category and dosage of allylation reagent and molecular weight of polyether.

其次对双羟基聚醚的端烯丙基化反应进行研究，讨论了反应时间、反应温度、聚醚分子量、烯丙基化试剂的种类和用量对反应的影响。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。