羟基化

From the transform infrared spectroscopy and X-ray photoelectron spectroscopy spectra, the hydroxyl and ethoxyl groups of the silica sol drawn from partially hydrolysis and polycondensation between TEOS and MTES can react with PA6 precursor.

红外图谱和X射线光电子能谱分析结果显示，硅溶胶的羟基和未完全水解的烷氧基能够与PA6的前驱体发生杂化反应。X射线衍射结果显示，采用本实验方法制备出的PA6和疏水型PA6/SiO2有机无机杂化材均为α晶型，而DSC结果表明，PA6/SiO2有机无机杂化材料的熔点略高于PA6。

The blue crosslinking polymeric dyes were synthesized with use of leucoquinizarin and polyvinylamine prepared from the Hofmann degradation of polyacrylamide. The maximum wave length was 597nm. The effects of temperature, the concentration of amino group, the pH value and the mole ratio of leucoquinizarin to amino group on the yield of red crosslinking polymeric dye were discussed.

以具有不同聚合度和不同胺化度的聚乙烯胺为骨架，以1，4—二羟基蒽醌隐色体为原料合成了蓝色可交联高分子染料，该染料的最大吸收波长为597nm，研究了反应温度、氨基浓度、pH值以及1，4—二羟基蒽醌隐色体与聚乙烯胺中氨基的摩尔比对反应的影响。

The relative stabilities and probable proton transfer in isolated and monohydrated 2-hydroxyimidazole molecules have been studied in gas phase using ab initio (MP2/6-31＋G *) method.

采用从头算方法在MP2/6-31＋G*水平上研究了2-羟基咪唑分子在孤立分子和一水合物的异构体的相对稳定性和可能的质子迁移反应，分析了一个水分子的参与对2-羟基咪唑分子异构体的相对稳定性和质子迁移速率的影响，采用Monte Carlo模拟方法研究了反应体系在水溶液中反应的溶剂化效应。

The pyridinium salts was transformed by the base to 1-hydroxy or 3-hydroxy-quinolizinylides, which undergo 1,3-dipolar cycloadditionreaction with alkenes,and then aromatizated to cycl[3,3,2]azinone in thepresence of oxidant.

实验证明，这是一个连续进行的多步反应：2-羰基吡啶鎓盐在反应中先生成1-羟基或3-羟基喹嗪叶立德，然后与烯烃起1，3—偶极加成反应，最后在氧化剂作用下脱氢芳构化而生成Cycl[3，3，2]azinone。

The main intermediates were detected during decomposition,such as acetic acid,oxalic acid,malonic acid,phenol,3-hydroxyhypnone,naphthalene,benzene sulfonic acid,phthalic acid,β-naphthalene etc . by ultraviolet-visiblespectroscopy,ion chromatographand gas chromatograph coupled with mass spectrophotometertechniques.The possible degradation pathway of Acid Orange Ⅱ was also speculated,that was,hydroxyl radical reacted with the azo linkage-bearing carbon of naphthol-ring,and the C—N cleaved,the azo-dye decolored and mineralized.

运用紫外光谱、离子色谱、色谱-质谱联用等方法，测定出酸性橙Ⅱ的主要降解产物有乙酸、乙二酸、丙二酸、苯酚、3-羟基苯乙酮、萘、苯磺酸、邻苯二甲酸、β-萘酚等，并依此推测酸性橙Ⅱ的降解机理，即羟基自由基攻击酸性橙Ⅱ分子上与萘环相连的C—N键，导致C—N键的断裂，进而染料脱色矿化。

A novel type of photoalignment material based on the esterification reaction of 3,5-dihydroxyl benzyl alcohol and cinnamoyl chloride was firstly reported in this paper. The distinct property of this material is the nonlinear branch conformation and its polarity end with hydroxyl group.

通过在3，5-二羟基苯甲醇分子中的双酚基基团上引入双肉桂酰酯光敏基团的酯化反应，合成了一类新型的分子顶部为羟基极性基团，整个分子构型类似于树枝状的光敏小分子化合物。

To evaluate the allelopathy effects of benzoic acid and ρ-hydroxybenzoic acid on watermelon, this paper studied the effects of benzoic acid and ρ-hydroxybenzoic acid on watermelon seed germination and seedling growth by seed soaking, seed-bud soaking and seedling irrigation.

为探明苯甲酸、对-羟基苯甲酸对西瓜的化感作用，采用浸种、浸芽和浇灌幼苗的方法分别研究了苯甲酸、对-羟基苯甲酸对西瓜种子发芽和幼苗生长的影响。

Feeding for 24h by third instar larvae of the maize stalk borer induced farnesyl pyrophosphate synthase gene expressing, but had no effect on expression of AOC, BX9, PAL and PR2a genes and DIMBOA content.

3玉米螟3龄幼虫处理24h能诱导玉米根中法呢烯基焦磷酸合成酶基因表达，但不能诱导丙二烯氧化物环化酶、β－1，3葡聚糖酶基因（PR2a）、糖基转移酶（BX9）、苯丙氨酸转氨酶基因表达，同时对第二叶和根中丁布含量无显著影响，使第二叶对羟基苯甲酸及第三叶丁布、对羟基苯甲酸、香草酸含量显著降低。

In these components, 2-methyl-1-propanol, ethyl acetate, 3-methyl-1- propanol, 2,3-butanediol, phenylethyl alcohol, butanedioic acid diethyl ester, ethyl hydrogen succinate, 2-hydroxy-ethyl propanoic acid and 4-hydroxy-benzeneethanol were main aroma components, these volatile componds provided the typical sensory style of wine.

其中，2-甲基-1-丙醇、乙酸乙酯、3-甲基-1-丙醇、2，3-丁二醇、2-羟基丙酸乙酯、苯乙醇、丁二酸二乙酯、乙基-氢化琥珀酸和4-羟基苯甲醇等成分构成了葡萄酒的主体香气，这些主体香气与其他风味成分一起构成葡萄酒的典型风味特征。

This research utilized the method of organic synthesis, researching different amounts and positions of hydroxy-substituted benzoic acid and serotonin into amide reaction, so as to produce a series of polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10). Accordingly, this study conducts the following four tests. I. The activity of antioxidant and the experiment of ability to scavenge DPPH free radical, II. The ability of overall antioxidant—the activity of TEAC, III. The activity test of inhibit Tyrosinase, and IV. The study of absorbing UV / VIS Spectrophotometers. This study use trolox, arbutin, and octyl salicylate as the control groups, and to test the ability of anti-oxidation, the activity of inhibit Tyrosinase, and the ability of absorbing UV. This research ultimately intends to investigate the applied value of those compounds into cosmetics.

本研究主要利用有机合成的方法，将不同数量及不同位置的羟基取代苯甲酸化合物与色洛冬宁进行醯胺化反应后，得到一系列的多羟基取代之N-色洛冬宁苯甲醯胺衍生物（化合物1 ~ 10），进行四种不同活性测试方法：一、清除DPPH自由基能力抗氧化活性测试；二、总抗氧化能力活性测试；三、抑制酪胺酸酶活性美白测试；四、紫外线／可见光光谱仪吸收测试，并以水溶性维生素E、熊果素、水杨酸辛酯当作对照组，探讨其抗氧化能力、抑制酪胺酸酶的活性能力与吸收紫外线能力，再进一步探讨其应用於化妆品上的价值。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。