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羟基乙酸

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The productions of glycin oxidation are complicated and the cost is high. The cyanogenesis is poisonous and unsafe.

国内外合成羟基乙酸的方法主要有甘氨酸氧化法、氰化法、醛类羧化法、甲醛和甲酸甲酯偶联法、草酸电解法、氯乙酸水解法等。

The beheviour of four low-molecule weight organic acid lactic acid,hydroxy-acetic acid,mercapto-acetic acid,glyconic acid as iron-containing silicate-aegirines depressants on the hematite direct flotation is investigated in this paper.The results of flota

本文研究了四种小分子有机酸抑制剂乳酸、羟基乙酸、巯基乙酸、葡糖酸在赤铁矿正浮选中对含铁硅酸盐脉石霓石的抑制行为,纯矿物、人工混合矿与实际矿石浮选实验均证明了它们具有良好的选择性抑制作用,可以成功地实现赤铁矿与霓石的浮选分离。

Glyceraldehyde, glycoladehyde, glycolic acid, and formaldehyde were identified as the intermediate products.

甘油光催化降解最终产物是H_2O和CO_2,检测到了甘油醛、羟基乙醛、羟基乙酸、甲醛等中间产物。

Hydroxy benzene acetic acid and acetic acid have biological activity, such as anti-bacterial and other aspects, a wide range of applications.

羟基乙酸和苯氧乙酸都具有生物活性,在诸如抗菌等方面具有广泛的应用。

Therefore, we started hydroxy benzene acetic acid and acetic acid coordination unit for the nodes of copper, cobalt, cadmium, manganese, zinc coordination polymers of structural chemistry studies.

因此,我们开展了苯羟基乙酸和苯氧乙酸配位单元为节点的铜、钴、镉、锰、锌配位聚合物的结构化学的研究。

It demonstrated that the hydroxy organic acids substituted with-OH,-SH at α—C such as lactic acid, Hydroxy-acetic acid, mercapto-acetic acid, glyconic acid have good selectivity for separation of hematite and aegirine pka values of organic acids fall down because of the-I inductive effect of-OH or-SH, and lie at the pH range between two minerals point-zero-charge. As a result, the depression ability of them was enhanced, and a cyclo-pentyl chelate was formed when this organic acids acted with Fe〓 on the minerals surface.

发现在α位具有-OH、-SH等取代基的短链一元羧酸(乳酸、羟基乙酸、巯基乙酸,葡萄糖酸)对赤铁矿与钠辉石的浮选分离具有优良的选择性抑制作用,-OH、-SH的-I诱导效应导致有机酸的pKa值下降并落在两种矿物零电点之间,使其抑制性能增强,并与矿物表面的Fe〓形成稳定的五元螯合环。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法,合成了4种苯并咪唑-2-羧酸衍生物并进行了表征;培养了2个化合物d、e的晶体并测定和讨论了晶体结构;制备了3种未见报道的苯并咪唑金属配合物,对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

The difficulty of route is the refinement of products. There is a lot of sodium chloride in solution. In order to refine the glycolic acid, the methods of vacuum distillation and organic solvent extraction are adopted.

水解合成后得到的是羟基乙酸的水溶液,其中含有大量的氯化钠和少量未水解的氯乙酸及其它杂质,采用减压蒸馏及有机溶剂萃取方法进行精制是比较适宜。

A brief account of technique conditions of several main technique routes for synthesizing glycollic acid and existing main problems in it are given.

概述了羟基乙酸几种主要工业合成方法的工艺条件及存在的主要问题,即氯乙酸水解法、氰化法、甲醛羰基化法和一氯乙酸钾水解法。

The effect factors on glycolic acid ratio were studied(reaction temperature,reaction time,and the ratio of catalyst to choloroacetic acid).

以氯乙酸和氢氧化钠为主要原料,碘化钠为催化剂碱性水解法合成羟基乙酸,并采用单因素法对影响因素进行了研究,得到最优化条件:反应温度90℃,反应时间8 h,催化剂NaI用量为氯乙酸质量的0.8%。

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