羟基乙酸

MIPC was photocatalytically transformed to 3,4-dihydroxyl hypnone, 2-iso-butyl phenol and acetic acid, and mineralized ultimately in oxygenated TiO2 slurries. The photocatalytic degradation processed according to first order kinetics with the apparent rate constant depending on initial concentration, light intensity and the amount of catalyst. The amount of catalyst had an optimum value (0.5g/L). The apparent rate was inversely proportional to square root of the initial concentration approximately.

MIPC能被光催化转化成3，4-二羟基苯乙酮、2-异丁基苯酚和乙酸等产物并最终被矿化，MIPC的光催化反应过程符合一级动力学规律，其表观速率常数与MIPC的起始浓度、TiO2量和光强等因素有关，MIPC降解的反应速率与入射光强成正比，与MIPC初始浓度的平方根成反比。

D limonene was distributed among the culture flasks (200 mg/L). The flasks were incubated at 28oC on a rotary shaker (r/min=120) for 5 days. On completion, the culture broth were successively extracted with EtOAc. The extract was quantitatively measured by gas chromatography mass spectrometry analysis, The results showed that biocatalytic reactions were comprised of oxidation, including hydroxylation and ketonization which occurred at different positions of the D limonene, as well as hydrogenation, hydrolyzation, esterification and cyclic cleavage. These bacteria strains possess the distinctive biocatalytic capacities towards the D limonene. A series of terpenoids, including sesqui , di and tri terpernoids were also observed,which was accounted for D limonene had influence on the metabolites of marine bacteria.

以2216E为培养基，添加200mg/L的柠檬烯，在28℃，以120 r/min摇瓶培养5 d，用乙酸乙酯提取培养液，经GC MS分析其转化产物，结果显示，这些细菌能在柠檬烯的不同位置进行羟基化、羰基化等，并伴随有还原、水解、酯化、开环等反应，但转化能力和转化程度不同；在产物中，还检测到系列结构不同的其它萜类：包括倍半萜、二萜以及三萜等，这些萜类化合物的产生跟柠檬烯的加入有关，说明柠檬烯能影响细菌代谢产物的产生。

Schiff base derived from p-hydroxybenzaldehyde and p-aminobenzoic acid was prepared by solid-state reaction at supersonic speed airflow and low-heating. Lophophora shape Cu complexes was prepared from the Schiff base and copper acetate and through adding sodium dodecyl sulfate. The structural composition of complexes was confirmed by FTIR and elemental analysis.

利用超音速气流低热固相法合成了对羟基苯甲醛缩对氨基苯甲酸Schiff碱配体，再以该配体和乙酸铜为原料，通过添加十二烷基硫酸钠的方式制备出了晶形规整的仙人球型配合物，利用元素分析和红外等现代测试手段确定了配合物的结构组成。

This thesis is constituted by four parts: In the first part a summarization is given on the main total synthetic methods of isoflavones, for example, deoxybenzoin method which generally involves two steps wherein a phenol is reacted in the presence of a Lewis acid with phenylacetic acid to generate an intermediate deoxybenzoin which is then cyclized with a one carbon electrophile.

本论文主要工作包括四部分：第一章综述了近年来全合成异黄酮的主要方法：脱氧安息香法，是以多羟基苯酚与苯乙酸或苯乙腈在Lewis酸存在下，反应生成中间体脱氧安息香，然后再与亲电碳试剂进行关环反应生成异黄酮。

A series of novel amphipathic macrocyclic polyamine ligands derived from iminodiacetic acid and diethylene triamine have been synthesized and characterized by MS, 1H NMR, IR spectra and elemental analysis.

以亚胺基二乙酸和二乙撑三胺为原料，通过关环等反应合成了一类侧链含有羟基的新型两亲性大环多胺。

A simple method was developed for the analysis of 6-hydroxy-1-methyl-1,2,3,4-tetrahydro-β-carboline (6-OH-MTHβC), 5-hydroxytryptamine (5-HT) and 5-hydroxyindole acetic acid (5-HIAA) in rat brain by high performance liquid chromatography with electrochemical detection.

建立了大鼠脑组织中6-羟基－1-甲基－1，2，3，4-四氢－β-咔啉(6-OH-MTHβC)、5-羟色胺(5-HT)和5-羟吲哚乙酸(5-HIAA)含量的高效液相色谱-库仑阵列电化学检测方法。

The optimum technical parameters were obtained as follows:bromating temperature is 15℃,solvent is methyl arcohol, bromating agent is BrCl,the molar ratio of 4-hydroxy-benzaldehyde to BrCl is 1:1.15,reaction time is 2.5 hours.

其工艺参数优化如下：溴化时反应温度选择15℃，溶剂选择甲醇+乙酸甲酯，溴化剂选择氯化溴，对羟基苯甲醛与氯化溴之比为1∶1.15，反应时间选择2.5个小时，滴溴时间约半个小时。

Optically active ethyl-3-hydroxybutyrate,a useful chiral synthon,was prepared by stereoselective reduction of ethyl acetoacetate of the bread yeast in organic solvent.

利用面包酵母在非水相中不对称还原乙酰乙酸乙酯，制备了光学活性的手性化合物S-3-羟基丁酸乙酯。

7-Hydroxy-4-methylcoumarin was synthesized from ethyl acetoacetate and m-dihydroxybenzene by the Pechmann condensation using phenyl sulfonic acid as catalyst under solvent-free conditions.

摘 要：以苯磺酸作催化剂，乙酰乙酸乙酯和间苯二酚为原料，通过Pechmann缩合反应合成7-羟基-4-甲基香豆素。

Synthesis 3,5-dihydroxytoluene by ethyl acetoacetate and diketene as material(yield 6%),by 3-methyl-4-chlorophenol and KOH as material(yield 30-40%)respectively,It was solved for product separation and purify.

分别以乙酰乙酸乙酯与双乙烯酮为原料(收率6%)、3-甲基-4-氯苯酚与氢氧化钾为原料(收率30-40%)合成了3，5-二羟基甲苯，解决了产品分离纯化问题。3-甲基-4-氯苯酚路线进行了中试，中试收率为20%。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。