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羟基丙酮

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The products are methyl vinyl ether (cis- and trans-), allyl alcohol and propen-2-ol.

计算得到的丙酮分子的5个异构化反应通道分别对应3种异构化产物,乙烯甲基醚、丙烯醇和1-丙烯-2羟基。

Hydroxy-2-methyl-1-phenyl propan-1-one (1173) was a more effective photoinitiator to these monomers than that of benzophenone.

与二苯甲酮相比,2-羟基-2-甲基-1-苯基丙酮(1173)对两种单体具有较好的引发效果。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下,起亲核加成反应,反应中间体5在室温用酸性丙酮水解,得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物,产率56%、通过制备薄层层析分得这四个立体异构体,它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似,推定了它们的绝对构型。

The activity of pyruvate formate-lyase and pyruvate dehydrogenase accounts for the observed production of formate, acetate, ethanol and acetoin. In 1978, Hillman isolated one of the mutants of Streptococcus mutans which lack the enzyme activity of dehydrogenase.

当外源性糖丰富的时候,果糖-1,6-二磷酸增加,使LDH活化,90%以上的葡萄糖被转化为乳酸;外源性糖供应不足时,通过丙酮酸甲酸裂解酶和丙酮酸脱氢酶作用产生甲酸、乙酸、3-羟基丁酮和乙醇。

Given the known reaction mechanism and general chemical considerations, we propose that nicotine, when used as the carbon source by P. putida J5, is catabolized to pyruvic acid via pyrrolidine pathway and then participates in the synthesis of vitamin pantothenate and CoA, which supply the energy for the normal functioning.

通过对突变位点基因的功能分析推测,假单胞杆菌可以将尼古丁代谢为2,5-二羟基吡啶,而2,5-二羟基吡啶可以进一步转化为丁烯二酸和丙酮酸,进而参与了泛酸和 CoA 的合成,为生理代谢提供基质。

Preparation of the lateral chain-4-benzyloxy-3-hydroxy butyronitrile is introduced as the substrate, the REFORMATSKY reaction is performed, then obtains the dicarbonyl ester, in the structure of which containing a chiral hydroxyl group, then performs the chiral reduction, take off the benzyl group after the protection reaction with acetonylidene,then obtains the lateral chain by oxidation.

手性侧链醛的合成:采用-4-苄氧基-3-羟基丁腈作为底物,通过REFORMATSKY反应缩合得到含有手性羟基的二羰物酯,再手性还原,丙酮叉保护后氢解脱苄,最后氧化得到侧链醛。

Result Under the pretreatment conditions, the content of acetone extractives transformed. The hydroxyl and carboxyl, belonging to auxochromic groups, were oxidized into the carbonyl and ester groups. Also, there were plenty of auxochromic groups and chromophoric groups in the acetone extractives of silver chain.

结果]刺槐在预处理条件下,丙酮抽出物成分发生了变化,羟基、羧基等助色基团在预处理条件下氧化成羰基、酯基等发色基团,且丙酮抽出物的主要成分中含有大量发色基团和助色基团。

The paper carries on qualitative analysis to the acetone extractives before and after discoloring, shows the main components of the extractives and then takes comparison. The results shows :①The hydroxyl is oxidized and then shifted to the carbonyl,carboxyl, ester and ketone groups during inducing discoloration under the pretreatment conditions,which makes the wood color deep;② There are plenty of auxochromic groups in the acetone extractives of silver chain, the interaction between the auxochromic groups and the chromophoric groups makes the wood color deep.

摘 要:本文通过对刺槐变色前后丙酮抽出物的定性分析,得出变色前后丙酮抽出物的主要成分,进行对比分析,初步得出抽出物对诱发变色的作用为:①变色前后羟基在预处理条件下氧化成羰基,羧基,酯基和酮基等官能团,使木材颜色加深;②刺槐丙酮抽出物的主要成分中含有大量助色基,这些基团会与木素中的发色基团相互作用,使木材颜色加深。

A new flavanone from Dryopteris sublaeta;2. Isolation and Structure Identification of a New Flavanone from Dryopteris sublaeta;3. RESULTS Five compounds are isolated from the ether fraction of 70% acetone-extracts,and their structures were identified as(2S)5,7-dihydroxy-6,8-dimethyl flavanone desmethoxymatt.

结果浅裂鳞毛蕨地上部分用体积分数为70%丙酮提取液乙醚萃取部位分离得到了5个化合物,分别鉴定为:(2S)5,7-二羟基-6,8-二甲基二氢黄酮,(2S)5,7-二羟基-6,8-二甲基-4′-甲氧基二氢黄酮,(2S)5,7,2′-三羟基-6,8-二甲基-二氢黄酮,(2S)5,7,4′-三羟基-3′-甲氧基-6,8-二甲基二氢黄酮,(2S)5-羟基-4′-甲氧基-6,8-二甲基二氢黄酮-7-O--βD-葡萄糖苷。

Their structures were characterized by IR, 1H NMR, of which 4-chloro- 2-methyl-7-(2-bromoethoxy) isoflavone, 2, 4\'-dimethyl-7-(2-bromo-ethoxy)isoflavone and 2-methyl-7-(2-bromoethoxy) isoflavone are rarely reported so far.4\'-chloro-2-methyl-7-(3-bromopropoxy)isoflavone, 2, 4\'-dimethyl-7-(3-bromo- propoxy) isoflavone, 2-methyl-7-(3-bromopropoxy) isoflavone, 4\'-methoxy-2-methyl-7-(3-bromopropoxy) isoflavone and 4\'-hydroxy-2-methyl-7-(3-bromopropoxy) isoflavone were gained by reacting 7-hydroxy-2-methyl isoflavone derivatives with 1, 3-dibromo- propane, respectively.

第三章(来源:73ABC论文网www.abclunwen.com)在丙酮溶液中以K_2CO_3为碱,使溴乙氧基异黄酮和溴丙氧基异黄酮与咪唑偶合,以较高的产率合成出10种目标化合物:2-甲基-4′-氯-7-2-(1-咪唑基乙氧基异黄酮、2,4′-二甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-甲氧基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-羟基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-氯-7-3-(1-咪唑基丙氧基异黄酮、2,4′-二甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-甲氧基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-羟基-7-3-(1-咪唑基丙氧基异黄酮,经IR、~1H NMR、~(13)C NMR、元素分析等对其结构进行了表征,10种目标产物均未见文(来源:ABC论文cccccc网www.abclunwen.com)献报道。

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