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羟基

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It consists of many glucose units, in each of which one of the hydroxyl groups has been replaced by an acetylamine group (CH3CONH).

包括许多的葡萄糖单元,每个单元的羟基都被乙酰基取代。

Result: Eight compounds were isolated from ethanolic extract of the brown alga D.divaricata and their structures were identified as-torreyol,4β,5α-dihydroxycubenol,3-farnesyl-p-hydroxybenzioc acid,chromazonarol,fucosterol,phenyl acetylamine,4-hydroxybenzoic acid and n-hexadecanoic acid.

结果:从叉开网翼藻中分离得到8个化合物,分别鉴定为-torreyol,4β,5-αdihydroxycubenol,3-farnesyl--phydroxybenzioc acid,chromazonarol,岩藻甾醇,苯乙酰胺,4-羟基苯甲酸和正十六酸。

The E-TOF will also be feasible and practical to assist chemists in screening the optimal reaction condition or evaluating the overall efficiency of different catalytic systems for a specific asymmetric reaction.4.For the first time,we explored chiralγ-hydroxy-α,β-acetylenic esters,which were prepared via asymmetric alkynylation,as key intermediates to the synthesis of chiralγ-butyrolactones. This convergent and enantioselective approach to chiralγ-butyrolactones is practical and easily handled with protecting group free.

这一概念包括反应产率、对映选择性、配体用量以及反应时间四个重要反应参数,不仅适用同一反应不同催化体系的横向综合性评价,而且适用于某一特定反应催化体系的优化过程,有助于研究人员选择最佳的反应条件。4、我们发展了以手性γ-羟基-α,β-炔酸酯为关键中间体完成了手性γ-丁内酯类天然产物的对映立体选择性全合成,该关键中间体能够以我们的催化体系方便的对映选择性合成,之后的官能团转换方法成熟,易于操作,无需进行繁琐的官能团保护和脱保护过程,绿色经济。

With 1,2-dimethoxyethaneas an additive,the reaction proceeded under mild condition to gave the highly functionalizedγ-hydroxy-α,β-acetylenic esters,and highly toxic reagent was avoided.

以DME为添加剂使不对称合成手性γ-羟基-α,β-炔酸酯的反应条件更加温和、易于操作,避免了剧毒物质的使用。

In this study, six patients with piebaldism had removal of achromic epidermis via appropriately set erbium:YAG laser followed by application of autologous cultured epidermal grafts on the recipient bed. The 3,4-dihydroxyphenylalanine reaction was used to determine melanocyte content, and a semiautomatic image analysis system calculated the percentage of repigmentation.

在这项研究中,六名通过适当能量设定之铒-雅克雷射,移除色素缺乏表皮的白斑病患,在受体皮肤上以自体培养表皮移植的应用加以追踪。3.4-羟基苯丙胺酸反应用以测定黑色素细胞内容,并以半自动影像分析系统计算再色素沉淀的百分比。

The result showed that: a good photo of chromosome can be obtained by using 8-hydroxyquiline to pre-treat Achyranthes bidentata BI combined with low osmosis treatment.

结果表明:采用8-羟基喹啉对牛膝进行前处理结合低渗处理可以获得良好的染色体图像。

LacZ gene was fused with the promoter of the acoR gene and bkdR gene, and two recombined genes were expressed in sigL mutant strain and HD-73 wild strain sequentially.

分别将调控aco操纵子(编码3-羟基丁酮脱氢酶系统)的转录调节基因acoR和调控bkd操纵子(编码催化支链脂肪酸合成的酶系统)的转录调节基因bkdR的启动子与lacZ基因融合,并转入出发菌株和sigL突变体中,测定b-半乳糖苷酶的活性。

Results Six compounds were isolated from the ethanol extracts of Acrostichum aureurm,and their structures were elucidated as ponasterone A(1),pterosterone(2),kaempferol(3),quercetin(4),4-(3,4-dihydroxyphenyl)-2-butanone(5),and daucosterol(6),respectively.

结果从卤蕨乙醇提取物中分离得到6个化合物,分别鉴定为ponasterone A(1)、pterosterone(2)、山奈酚(3)、槲皮素(4)、4-(3,4-二羟基苯基)-2-丁酮(5)、胡萝卜苷(6)。结论6个化合物均为首次从该植物中分离得到。

ABSTRACT To study the antibacterial constituents from the fermentation broth of endophytic fungus Penicillium sp. 0935030 from mangrove plant Acrostichum aureurm. The separation procedure was guided by antibacterial bioassay. Seven compounds were isolated and purified by column chromatography, and their structures were identified as cyclo (1), cyclo (2), 1(2Furanyl)1,2ethanediol (3),(3β,4β,22β)olean12ene3,22,23triol (4), mannitol (5), uridine (6), and liquiritigenin (7) by physicochemical and spectral data.

为研究红树林植物卤蕨内生真菌Penicillium sp.0935030发酵物中的抗菌活性成分,采用活性追踪的方法,用多种色谱技术对化合物进行分离纯化,通过理化性质和光谱数据鉴定出7个化合物,分别为:环(1),环(2),1呋喃基1,2乙二醇(3),(3β,4β,22β)12烯3,22,23三羟基齐墩果烷(4),甘露醇(5),尿苷(6)和甘草素(7)。

In the cyclization process,α-acylamino radicals preferred to attack acylsilanes from the face opposite to the β-substituent, and the stereoselectivity of the bridgehead is excellent. The orientation of the hydroxy group formed in the cyclization process was mainly exo.

生物碱架桥上立体化学的建立,可透过环上取代基立体障碍的影响,使得环化过程只会从立障较小的一面进行,因此可得到单一立体化学的结果,而环化所形成的羟基则是以exo的产物为主。

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