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The AM1 method was used for a quantum chemistry study of the phenol hydroxylation reaction mechanism. The possible reaction path of the phenol and oxyhydrogen free radical was optimized, and the structures of stable intermediates in the reaction mechanism were also obtained.

本文还首次采用AM1方法对苯酚羟基化反应机理进行了量子化学研究,将苯酚与氢氧自由基的反应沿可能的反应路径进行几何优化,得到反应历程上相关驻点稳定构型的三维结构。

The free hydroxyl radical of greater activity produced in the catalytic ozonization of V is the essence of the catalytic system; and the formed V also contributed greatly to the removal of chemical oxygen demand.

结果表明,催化体系的本质是催化剂中的四价钒催化臭氧分解生成了活性更高的羟基自由基,所生成的五价钒对体系化学耗氧量的去除也有很大的贡献(近10%)。

During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时,先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外,又研究了影响该反应的几个重要因素:亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4:1;稳定剂2-甲基-2-丁烯的用量至少大于2:1,通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出,获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

The process of deprotein was carried out after adding papain.

进行了南瓜多糖清除羟基自由基和抗氧化性的实验。

Hydroxybutyraldehyde, which is main material of synthesizing 3-hydroxybutyric acid was prepared through the aldol condensation of acetaldehyde in this paper. The properly reaction conditions of acetaldehyde condensation and paraldehyde depolymerization was studied and obtained.

本文自行制备了氧化反应的主要原料3-羟基丁醛,并对乙醛羟醛缩合反应及三聚乙醛的解聚反应进行了初步研究,确定了反应的最佳条件。

The nylon was used as the matrix of radiochromic film dosimeters, while hexahydroxyethyl pararosaniline cyanide was used as the dyes of radiochromic film dosimeters, and the radiochromic film dosimeter was developed.

以尼龙为基材、六羟基乙基副品红氰化物(hexahydroxyethyl pararosaniline cyanide, HPR-CN)为染料研制辐射变色薄膜剂量计。

The present paper take the purine synonym kui zuo lin as a parent nucleus, separately in its 4 and 7 introduction structure diverse substituted benzene amino and the flexible side chain, designed a series of 4- substitution anilino-- 6- methoxy - 7-(2- hydroxyl to substitute for third oxygen radical) kui zuo lin a kind of compound.

本论文以嘌呤类似物喹唑啉为母核,分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链,设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。

Methods: In this paper, a quinazoline purine analogues for the parent nucleus, respectively, and four of its seven introduced to replace the structure of diverse and flexible side-chain amino-benzene, design a series of 4 - to replace the aniline-based -6 - methoxy --7 -(2 - hydroxy replace C oxy) quinazoline compounds.

目的:通过各种化学合成方法完成目标化合物4--6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉的合成并对目标化合物进行结构修饰,以期获得高活性的表皮生长因子受体酪氨酸激酶抑制剂。

Objective To explore the role of 6-hydroxydopamine in the pathogenesis of Parkinson′s disease.

目的:探讨神经毒素6-羟基多巴(6-OHDA)在帕金森病发病机制中的作用。

The main contribution of this paper is summarized as follow:1 Copolymer acrylate resin including hydroxyl, carboxylic and amina(-NH_2) is a new type of antifogging system and ahydrophi- lic antifogging constituents which is not found before.2 Water-soluble acrylate resin hydrophilic antifogging coating material is a new-type environmental protection material which takes ethanol as solvent and whose pastiness is adjusted by deionized water.3 The quality rate of accessory soft monomer ethyl acrylate and accessory hard monomer butyl methacrylate is 6 to 4, the quality rate of functional monomers in all monomers is 20 percent, the quality rate of MAA in the functional monomers is 22 percent, the quality rate of β-hydroxyl ethyl acrylate in the functional monomers is 8 to 10 percent and the remainder of functional monomer is acrylic acid.4 Cross-linking agent methylol acrylamide belongs to self-cross-linking system.

本文的主要贡献概述如下: 1 含有亲水羧基、羟基和氨基(-NH_2)丙烯酸共聚树脂是一种新型高效的防雾体系,用的亲水防雾组分是前所未有的。 2 以乙醇为溶剂制得水溶性丙烯酸树脂具有很好的水溶性能和防雾性能,只需加入去离子水就可以调节它的粘度,是一种新型的环保型防雾材料。 3 辅助软单体丙烯酸乙酯和辅助硬单体甲基丙烯酸甲酯最佳配比为质量比6∶4;官能单体占单体总量的20%,甲基丙烯酸占官能单体总量10~15%,甲基丙烯酸β-羟乙酯占官能单体总量的8~10%,剩下的为丙烯酸。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。