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Crystal structural analysis reveals that, because water molecules bond to Cu atoms, the dhbd ligand can only adopt a hydroxyl oxygen atom to bridge two reversed U-shaped subunits into a novel centrosymmetric dual-U-shaped tetranuclear Cu structure. Each U-shaped frame consists of two crystallographically distinct Cu atoms, two dpphen ligands and one coordinated water molecule.

晶体结构分析表明,由于水的配位阻断, 2,3-二羟基丁二酸根仅通过单羟基氧桥联两个U形双核亚单元形成具有一个对称中心的双U形四核结构,其中U型亚单元包含晶体学上不对称的2个Cu原子、1个2,3-二羟基丁二酸根、2个4,7-二苯基-1,10-邻菲咯啉和1个配位H2O分子。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法,其反应混合物包括:一种含至少85重量%的4,4′-二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分,一种多元醇组合物,其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量%之间的聚氧亚烷基多元醇,水,一种平均羟基当量为15至250之增链剂,以及视需要使用的交联剂,该硬性嵌段-含量(hardblock-content)大于45重量%。

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5:1)中和-2,6-二羟基甲苯环合得1,3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

Hydroxyacetic acid was synthesized by glycolonitrile in the presence of H2SO4 , and it was separated by applying extraction based on chemical complexation and solvent method.

羟基乙腈为原料,在酸性条件下水解合成羟基乙酸,并采用络合萃取法和溶剂溶解法分离羟基乙酸。

The review highlights the technical developments in the identification,quantification and separation of α-hydroxyacetic acid,especially solvent extraction and synergistic extraction.

文章比较了各种羟基乙酸定性及定量分析方法,综述了羟基乙酸分离方法,特别是溶剂萃取和协同萃取效应。最后,分析了羟基乙酸的开发前景。

The advantages of α-hydroxyacetic acid biosynthesis over traditional chemical conversion are wide range of reaction condition,high conversion ratio and green process.

化学法生产羟基乙酸存在原料消耗大、产品收率低、环境污染严重等缺点;生物法合成羟基乙酸条件温和、底物转化率高,为绿色合成羟基乙酸提供强有力的技术支持。

This indicates that the interpolymer complexation resulting from thestrong specific interactions has overcome the surface segregation effect caused by thedifferences in the surface free energies.

羟基和吡啶基之间的氢键概率随着羟基含量的增加而迅速增加,在高羟基含量(49 mol%)的情况下,几乎达到1.0,这也从另一个方面说明了在络合物中,链段配对的趋势很强。

The SERS spectra of isoquinoline and its six derivates 3 -isoquinolinecarboxylic hydrate (Ⅱ, 1-isoquinolinecarboxylic acid, methyl 3-isoquinolinecarboxylate, isocarbostyril, 5-hydroxy-isoquinoline and 1, 5-isoquinolinediol were obtained by mixing the chemicals with silver colloid.

应用SERS技术,我们获得了异喹啉及其六种衍生物3-羧基异喹啉(Ⅱ,1-基异喹啉,甲基-3-羧基异喹啉酸酯,1-羟基异喹啉,5-羟基异喹啉和1,5-二羟基异喹啉的喇曼光谱。

Prophenoloxidase is a key enzyme for mediating melanotic encapsulation of oocysts,which may be transformed into active phenoloxidase by limiting proteolysis.

而前酚氧化酶(Prophenoloxidase,PPO)是介导卵囊黑化包被反应的一种关键酶,活化后可催化酪氨酸羟基化为二羟基苯基丙氨酸,二羟基苯基丙氨酸和多巴胺可进一步氧化为具有活性的苯醌活性,苯醌即可介导蛋白交联并聚合成黑色素层固定、隔离或杀死入侵的病原体。

Then, we studied the pathway of bacterial metabolism of Bpa and identified three kinds of metabolon of p-Hydroxy benzoic acid , p-Hydroxy benzaldehyde and p-Hydroxy acetophenone.

其次,利用现代分析化学技术研究Pseudonomas sp.W2对Bpa的代谢途径,发现对羟基苯甲酸、对羟基苯甲醛、对羟基苯乙酮为三种中间代谢产物。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

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