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The recent development in the toughening and plasticization of poly or poly(hydroxybutyrate-co-hydroxybutyvalerate) was reviewed.

总结了近年来国内外关于聚羟基丁酸酯和聚羟基丁酸酯-co-羟基戊酸酯共聚物在增韧和增塑改性方面的研究进展。

The smooth surface of nano-HA prothesis fails to take advantage of the benefit of nano-HA.

光滑表面的纳米羟基磷灰石假体未能发挥纳米级羟基磷灰石的优势;在影响骨整合方面就羟基磷灰石涂层来说,涂层表面改性可能比单纯涂层材料纳米化更重要。

Based on different thickness hydroxylation content in quartz sample, the changes of Hydroxyl peak 3675cm^(-1 intensity is obvious of different thickness in quartz sample, and withe increase of Quartz plate thickness, the hydroxyl peak transmittance increases.

通过对石英样品中不同厚度羟基含量分析得出,对于不同厚度的石英样品,羟基峰(3675cm^(-1)左右)的强度变化十分明显,石英片厚度的增加,羟基峰的透射率增大。

In the aluminum solution ,the trivalence aluminum ion combi...

另一方面,在这种铝盐溶液中,三价铝离子是以铝水配合物的形态存在,配位水发生水解生成羟基配离子,其通过羟基桥联结,放出水分子,并逐级由单体配合成双核、三核以致形成多核羟基配合物。

In the aluminum solution ,the trivalence aluminum ion combines with water to form the coordination compound and then the coordination waters hydrolyze into hydroxide ions. The hydroxide ions can join up each other by the hydroxide ion bridges so that the double cores, three cores and multiple cores coordination compounds are formed.

另一方面,在这种铝盐溶液中,三价铝离子是以铝水配合物的形态存在,配位水发生水解生成羟基配离子,其通过羟基桥联结,放出水分子,并逐级由单体配合成双核、三核以致形成多核羟基配合物。

Alcaligenes eutrophus WSH3 was selected as the strain for the production of polyβ-hydroxybutyrate and copolymer of 3-hydroxybutyrate and 3hydroxyvalerate . This study is aimed at finding an operative way leading to high PHB and PHBV productivity, high yield coefficient and high content of PHB and PHBV. The main research results are as follows

本文以真养产碱杆菌(A.eutrophus)WSH3为聚-β-羟基丁酸和3-羟基丁酸与3-羟基戊酸的共聚物的生产菌株,以实现PHB和PHBV发酵过程的高的生产强度、高的产物对基质的产率系数和高的聚合物含量为目标,进行了PHB及PHBV发酵条件的研究,主要研究内容和结果如下

Glucose an aldohexose, exists as D and L forms. The furthest asymmetric carbon from the aldehyde group is C-5. D-glucose is called D because the configuration of the atoms bonded to C-5 is the same as for D-gly- ceraldehyde. Similarly D-fructose﹙a ketohexose﹚ is designated D because the configuration

环状结构:醛基或酮基跟一个羟基反应共价闭合,形式上一个糖的醛基和羟基反应生成了一个半缩醛,而一个酮基与一个羟基反应生成一个半缩酮,在同一分子内这个反应能进行,单糖的开链式形成了糖环,葡萄糖环形成一个六碳环。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物,利用理化性质和波谱技术(UV、IR、EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构,分别为9种蒽醌类化合物:大黄酚,大黄素甲醚,大黄素,芦荟大黄素,大黄酸,番泻苷A或B,ω-羟基大黄素(ω-hydroxylemodin),大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside),芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside);3种菲醌类化合物:丹参酮ⅡA(tanshinoneⅡA),隐丹参酮,丹参酮Ⅰ(tanshinone Ⅰ);1种异黄酮:7,3'-二羟基-5'-甲氧基异黄酮(7,3'-dihydroxy-5' methoxyisofla-vone)以及原儿茶醛,原儿茶酸,黄芪甲苷(astragaloside Ⅳ),苦杏仁苷,2,3,5,4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷(2,3,5,4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside),Z—儿茶素,桂皮酸。

Their chemical structures were characterizd on the basis of spectral and chemical evidences to be: Sarracenin (1), 2-methyl-5-hydroxy-7-O-ethyl caffeate chromome (2), Naringenin(3), 2-methyl-5, 7-dihydroxychromome (4), 2-methyl-6-hydroxyl-cinnamic acid methyl ester (5), eriodictyol (6), quercetin (7), Naringenin-7-O-β-D-glucoside( 8 ), eriodictyol-7-O-α-D-glucoside (9), quercetin-3-O-β-D-glucoside(10). In addition, one compound was abtained from the n-butanol frationk, which was finally identified as Morrosiside(11) by spectral and chemical evidences.

以波谱数据及其理化性质鉴定为:Sarracenin(1),2-甲基-5-羟基-7-O-咖啡酸乙酯色原酮(2),柚皮素(3),2-甲基-5,7-二羟基色原酮(4),2-甲基-6-羟基苯丙烯酸甲酯(5),圣草酚(6),槲皮素(7),柚皮素-7-O-β-D-葡萄糖苷(Naringenin-7-O-β-D-glucoside)(8),圣草酚-7-O-α-D-葡萄糖苷(eriodictyol-7-O-α-D-glucoside)(9),槲皮素-3-O-β-D-葡萄糖苷(quercetin--3-O-β-D-glucoside)(10);另外从正丁醇萃取部位分离得到1个化合物,以波谱数据和文献对照鉴定为:Morroniside(11)。

Their structures were identified by physicochemical constant and spectral analysis (IR, UV, EI-MS, 1H-NMR, 13C-NMR, and HMBC). Results The compounds were identified from their ethanol extracts as: 6, 8-dihydroxy-2-[2-(3'-methoxy-4'-hydroxyl phenylethyl)] chromone and 6-methoxy-2-[2-(3'-methoxy-4'-hydroxyl phenylethyl)] chromone.

结果 从沉香乙醇提取物中分得2个色酮类成分,分别鉴定为6,8-二羟基-2-[2-(3'-甲氧基-4'-羟基苯乙基)]色原酮{6,8-dihydroxy-2-[2-(3'-methoxy-4'-hydroxyl phenylethyl)]chromone,Ⅰ}和6-甲氧基-2-[2-(3'-甲氧基-4'-羟基苯乙基)]色原酮{6-methoxy-2-[2-(3'-methoxy-4'-hydroxyl phenylethyl)]-chromone,Ⅱ}。

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