羟基

The 1,5-Bis(4-aminophenylazo) anthraquinone, 1,5-bis(4-hydroxyphenyl azo) anthraquinone and 1,5-bis(3-methyl-4-hydroxyphe nylazo) anthraquinone were synthesized by diazotizing 1,5-biaminoanthraquinone with nitrosyl sulfuric acid and coupling with aniline, phenol and o-cresol.

合成以1，5-二氨基蒽醌为原料，经亚硝酰硫酸重氮化，分别和苯胺、苯酚及邻甲酚偶合，得到双（4-氨基苯）－1，5-二偶氮蒽醌，双（4-羟基苯）－1，5-二偶氮蒽醌和双（3-甲基－4-羟基苯）－1，5-二偶氮蒽醌，反应产率达47%~62%。

A brief review of preparation of three 1,1'binaphthyls with nonidentical groups in 2, 2'positions: 2amino2'hydroxy1,1'binaphthyl, 2hydroxy2'mercapto1,1'binaphthyl and 2amino2' mercapto1,1'binaphthyl was prespented, and the progress on their application in the asymmetrical synthesis was outlined.

概述了 2 ，2'位置上带有不同取代基的 1，1'联萘化合物，如 2氨基 2'羟基 1，1'联萘、2羟基 2'巯基 1，1'联萘和 2氨基 2'巯基 1，1'联萘的制备及在不对称合成中的应用研究进展。

The space oriented blocks of modifiers favor the formation of small-sized rutile TiO2 nano-rods, at the same time, the coordination between carboxyl or hydroxyl group of modifiers and TiO2 nanoparticles also inhibit the TiO2 crystal growth, resulting in small-sized rutile nanoparticles.

结果表明：含羧基或羟基的有机化合物在修饰剂条件下都制得了纳米金红石型二氧化钛，且修饰剂的加入抑制了棒状纳米二氧化钛的颗粒大小，其中修饰剂的空间位阻效应在控制合成小尺寸二氧化钛纳米棒中起主要作用，且修饰剂的羟基和羧基的络合作用对颗粒的生长也起到抑制作用。

The constituents were extracted by some solvents. 18 constituents were isolated from Chloroform fraction by different chromatography. 15 constituents were identified by IR ,MS and NMR as follows: 3-sitosterol, P-sitosterylpalm itate,succinate acids, 1, 4-benzenediol, 1, 2-benzenediol, p-hydroxybenzaldehyde, syringaresinol, oleanolic acid, usolic acid, ethyl caffeate , Rosmarinic acid ethylster and etc. In such constituents ,nine compounds were isolated for first time from Origanum vulgare L..

牛至药材经水煮醇沉法所得浸膏，利用溶剂法和色谱法从中分离得到18个单体成分，通过IR、MS、NMR等波谱技术鉴定了其中的15个化合物，分别为β-谷甾醇(1)、β-胡萝卜苷(2)、琥珀酸(3)、对-二苯酚(4)、邻-二苯酚(5)、对羟基苯甲醛(6)、1.2-二羟基-4-异丙基-5-甲基苯(7)、新木脂素(8)、丁香脂素(9)、齐墩果酸(10)、乌苏酸(11)、4-二十六烯(12)、正二十六醇(13)、咖啡酸乙酯(14)、迷迭香酸乙酯(15)等，其中化合物3、4、5、6、7、8、9、14、15等9种化合物均为首次从该属植物中分离得到。

Given the known reaction mechanism and general chemical considerations, we propose that nicotine, when used as the carbon source by P. putida J5, is catabolized to pyruvic acid via pyrrolidine pathway and then participates in the synthesis of vitamin pantothenate and CoA, which supply the energy for the normal functioning.

通过对突变位点基因的功能分析推测，假单胞杆菌可以将尼古丁代谢为2，5-二羟基吡啶，而2，5-二羟基吡啶可以进一步转化为丁烯二酸和丙酮酸，进而参与了泛酸和 CoA 的合成，为生理代谢提供基质。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

This paper study the adsorption characteristic and application of bentonites on waste water treatment, which is bacesd on previously study on OH-Fe and OH-Fe-Al pillared bentonites.

本文立足于前人的研究，对羟基铁柱撑和羟基铁铝柱撑膨润土的吸附性能及应用进行了实验研究。

In the protein adsorption and osteoblast culture in vitro, more surface hydroxyl groups and higher polar component of surface energy led to more protein and cell adsorbed, and higher cellular activity.

在本论文中，通过金红石二氧化钛膜、锐钛矿二氧化钛膜、含钙的钛表面、含磷的钛表面和Ti-羟基磷灰石涂层的表征，结合羟基磷灰石沉积、蛋白质吸附和细胞体外培养，研究了钛的表面表征与生物活性的关系。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。