缩醛化

A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: wherein, R1 is selected from H, linear, branched or circular alkyl with 1-20 carton atoms, linear, branched or circular alkyl with 1-20 C atom, which is perfluorinated or semi-perfluorinated; and CN; R2 is alicyclic group with 5 or more carbon atoms; X is selected from methylene, aether, ester, amide and the connecting part of the carbonate; R3 is linear or branched alkylene with one or more carbon atoms or perfluorinated or semi-perfluorinated linear or branched alkylene; R4 is selected from H, CH3, CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated aliphatic group; R5 is selected from the CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated substituted and unsubstituted aliphatic group; n is 1 or higher integer; OR12 is OH or at least an acid unstable group selected from the tert-alkyl carbonate, tert-alkyl ester, tert-alkyl aether, acetal and ketal.

本发明公开了一种包含一种聚合物的光刻胶组合物，该聚合物包括至少一种具有下列结构的单体：其中，R 1 选自氢、具有1～20个碳原子的线形、支化或环状烷基、半氟化或全氟化的具有1～20个碳原子的线形、支化或环状烷基、以及CN；R 2 为具有5个或更多个碳原子的脂环基团；X为选自亚甲基、醚、酯、酰胺和碳酸酯的连接部分；R 3 为具有1个或多个碳原子的线形或支化亚烷基或者半氟化或全氟化的线形或支化亚烷基；R 4 选自氢、甲基(CH 3 )、三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的脂族基团；R 5 选自三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的取代或未取代的脂族基团；n为1或更大的整数；OR 12 为OH或者选自叔烷基碳酸酯、叔烷基酯、叔烷基醚、缩醛和缩酮的至少一种酸不稳定基团。

In addition, when the modified PVA resins fulfilled requirements in the following: 1 the acetalization degree varied from 60 mol% to 80 mol%, 2 the esterification degree varied from 10 mol% to 20 mol%, 3 the amount of hydroxyl group was 5-25 mol%, 4 the range of value of B/P(the mass ratio of the binder to diazo resin) was from 4 to 4.5,5 the range of its molecular weight was from 4×10^5 to 8×10^5, the negative PS plate obtained had excellent sensitivity, hydrophobic property, good developability, good ink receptivity and good scratch resistance.

因此其分子量、酯化度和缩醛度的确定，必须综合考虑各项性能之间的平衡。缩醛度为60-80 mol%，酯化度10-15mol%，羟基5-25 mol%，分子量约为4-8万，B/P为4-4.5时，制得的阴图PS版的感度、显影性、着墨性和耐磨性都较好。

It was found that the catalytic activities of HZSM-5 sample (ZS540.2) steaming at 540℃ latm for 2hr to condensation reaction and etherization of propylene oxide were enhanced.

发现了适度水热处理HZSM-5应用于缩醛和环氧丙烷醚化等-系列反应后得到的催化活性增强现象。

The model for the process of methylal synthesis by fluidized catalytic distillation was established and was used to simulate and design the process. A 1000t/a methylal production unit was built and the test run was conducted with success.

从提出流化催化精馏新型塔结构入手，在本征动力学、宏观动力学、甲缩醛合成流化催化精馏模型与模拟设计和工业性试验等方面，进行了系统的理论和实验研究，取得了一系列研究结果，并获得了1000吨／年甲缩醛合成装置的试车成功。

This mechanism is different from that for the acetalization reaction of polyvinyl alcohol with saturated aldehydes,which has only 1,2-addition.Crosslinking in polyvinyl butenal was mainly resulted from the 1,4-addition.

此机理不同于只有1，2-加成方式的聚乙烯醇缩饱和醛化反应。1，4-加成主要导致聚乙烯醇缩丁烯醛的交联。

According to the results of IR and XRD, two main mechanisms lead to the formation of cross-linked chitosan microspheres: one was the Schiff base reaction and hydrogen bond formation, the other was the acetalization.

结合IR光谱和XRD测试，分析了壳聚糖交联固化成球的机理：壳聚糖和香草醛之间所发生的Schiff碱反应和氢键的形成以及缩醛化反应，以此为基础共同形成交联结构从而使壳聚糖交联固化成球。

The paper introduces the formula, process and tensile strength of the organic-inorganic composite adhesive which is prepared by mixing acetalization of polyvinyl alcohol with silicasol.

叙述了以聚乙烯醇为原料，经缩醛化后和硅溶胶制备有机—无机复合粘合剂。介绍了配方、备程序和拉伸粘结强度的试验结果。

Acetalization of Benzaldehyde with 1,2 Propanediol over Dealuminated USY

脱铝超稳Y沸石催化苯甲醛与1，2-丙二醇的缩醛化反应

Vanillin 58 was used as starting material, which underwent methylation, bromination, acetalization, lithiation followed by nucleophlic addition to aldehyde, Diels-Alder reaction, selective reduction and lactonization to produce diphyllin in an overall yield of 38%(7 steps).

这个方法从香兰素58开始，经过甲基化、溴化、成乙二醇缩醛反应、锂化而后对醛亲核加成、Diels-Alder反应、选择性还原反应和内酯化反应共7步，最后得到diphyllin，总产率38％。

The intermediate 5-amino-1H-pyrazole-4-carboxylic acid ethyl ester prepared in the first part underwent successively hydrazinolysis, condensations with ketene dithioacetals and alkylations to give rise to the dipyrazolyhnethanes.

从第一部分中的中间体5-氨基-1H-吡唑-4-羧酸乙酯开始，经过肼解、与乙烯酮二硫代缩醛的缩合反应和烷基化反应，合成了二吡唑基甲酮类化合物。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。