缩酮

The synthesis of alkylcyclohexylbenzoic acid: take the synthesis of ethylcyclohexylbenzoic acid as a typical example. With the AlCl3 as the catalyst, cis+trans acetylcyclohexylbenzene is synthesized from the reaction of acetyl chloride, cyclohexene and benzene.

烷基环己基苯甲酸的合成研究：主要研究了乙基环己基苯甲酸的合成，以乙酰氯、环己烯、苯为原料，三氯化铝为催化剂，合成乙酰基环己基苯，用水合肼、氢氧化钾、一缩二乙二醇经过高温加热还原羰基(Wolff-黄鸣龙还原)，将所得到的乙基环己基苯用乙酰氯进行傅克酰基化得到乙基环己基苯乙酮，所得中间体经过处理之后直接得到反式产物，将反式异构体的乙酰基氧化得到反式烷基环己基苯甲酸。

Aluminum ; Acetone ; 2; 15-Hexadecanedion ; Computer simulation ; Aldol condensation

氧化铝；丙酮； 2； 15－十六烷二酮；计算机模拟；醛醇缩合

In order to study the aldol condensation of 2,15-hexadecanedione on the surface of aluminium, the intermolecular condensationmechanism of acetone occurring on aluminum was simulated by usingsemi-empirical AM1 method embodied in MOPAC 6.0 program package.

为了研究2，15-十六烷二酮在氧化铝表面的环合机理，选择小分子丙酮为模型化合物，用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理。

Aldol condensation of aldehydes with α-H in the base-catalyzed formation of carbon ions, and carbon ions as nucleophiles on aldehydes and ketones to increase the pro-nuclear ...

羟醛 缩合具有α-H的醛，在碱催化下生成碳负离子，然后碳负离子作为亲核试剂对醛酮进行亲核加。。。

Dihydropyrimidin-2 (1H)-ones were synthesized by condensation of aromatic or aliphatic aldehydes, urea and ethyl acetoacetate or acetylacetone one-pot three-component Biginelli condensation in the presence of room temperature ionic liquids as catalysts under solvent-free conditions.

5利用室温离子液体作催化剂，芳香或脂肪醛、尿素和乙酰乙酸乙酯或乙酰丙酮三组分缩合制备3，4-二氢嘧啶-2-酮衍生物。

An organic compound usually formed as an intermediate product in the preparat of acetals from aldehydes or ketones.

一种有机化合物，通常是用乙醛或酮配制乙缩醛时的中间产物。

In comparison with the pure standards and the retention indices RI(subscript s reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.

实验先采用液－液萃取方法提取张裕XO级白兰地的挥发性成分，然后将酸性成分与碱性和中性成分分离，再采用柱色谱分离手段将其分离为若干个级分并浓缩，采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定，在白兰地中共鉴定出302种挥发性成分，包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。

The neutral/basic fraction was furthermore separated into 4 fractions using silica gel normal phase chromatography, and each fraction was then concentrated and analyzed using gas chromatography-mass spectrometry. In comparison with the pure standards and the retention indices reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.

实验先采用液-液萃取方法提取张裕XO级白兰地的挥发性成分，然后将酸性成分与碱性和中性成分分离，再采用柱色谱分离手段将其分离为若干个级分并浓缩，采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定，在白兰地中共鉴定出302种挥发性成分，包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。

It had already been used in preparing the immobilized catalyst for heterogeneous hydrogenation of olefins,[17] in desulfurization of simulated flue gas,[18] and particularly in the reactions between aldehydes or acetones and the compounds with active hydrogen, such as Henry reaction[19] and direct aldol reaction.

16它已被用于制备烯烃非均相加氢反应的固定相催化剂，[17]烟气脱硫，[18]并且特别地被用于醛或酮和含活泼氢的化合物之间的反应，例如Henry反应[19]和直接羟醛缩合。

ALA belongs to the class of a-amino ketones. It dimerizes spontaneously to 2,5-dicarboxyethyl-3,6-dihydropyrazine at alkaline condition in vitro.

ALA属于a-氨基酮酸类化合物，体外无酶催化时，它在碱性溶液中能可逆二聚化缩合成2，5-二羟吡嗪。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。