缩酮

Sulfonated poly are prepared by direct polymerization of biphenol A, disodium 4, 4"-difluoro-3, 3"-disulfonate-1, 1-diphenylketone and 2, 6-difluorobezonitrile. The polymers are characterized with ~1H-NMR, FT-IR.

以双酚A，2，6-二氟苯腈和4，4′-二氟-3，3′-二磺酸钠-1，1′-二苯酮采用直接缩合法合成了不同磺化度的磺酸型聚芳醚腈酮，通过FT-IR和~1H-NMR对聚合物进行了表征，证明其结构正确。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料，经过高锰酸钾的碱性氧化，甲醇酯化，再与甲氧基胺盐酸盐肟化后，用N-溴丁二酰亚胺溴化，最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

It could be synthesized by a key intermediate 2-pentylidene cyclopentanone formed a condensation starting from cyclopentanone and n-valeraldehyde, followed by isomerization, Michael addition and a selective decarboxylation.

本文研究了以正戊醛和环戊酮为基本原料，经缩合反应、异构化反应、Michael加成反应和脱羧反应等制备二氢茉莉酮酸甲酯的化学合成方法和工艺。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1，2-氧硼杂环戊烷与〓反应，再经PCC氧化，分子内缩合得到二氢茉莉酮。1，2-氧硼杂环戊烷的C-B键除氧化断裂之外，也能够在〓或KF作用下卤化断裂成碳卤键。

1Five novel E-(4-β-D-allopyranosyloxyphenyl)-1-(4-substituted phenyl) propenone derivatives were designed and synthesized by the Claisen-Schimidt reaction with 4-substituted hypnone.

1与4-取代苯乙酮进行Claisen-Schimidt缩合，合成了五个未见文献报道的E-4-β-D-吡喃阿洛糖苷-苯乙烯基-4-取代苯酮衍生物。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1，2，4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体，然后与罂粟碱反应合成开链片螺素，最后经乙酰化、去保护、成内酯环得到片螺素；第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯，然后由该中间体与罂粟碱反应，在完成关环的同时也引入酯基，最后去保护、成内酯环得到片螺素；第三条路线是由香豆素或茚二酮出发，经溴代后的中间体与罂粟碱反应，得到片螺素的基本框架。

Five chalcones were synthesized via the aldol condensation reaction of acetophenone or parasubstituted acetophenones with 1-phenyl-3-methyl-5-phenoxyl-pyrazol-4-aldehyde, which reacted with two kinds of hydrazine in glacial acetic acid under refluxing to give a series of bipyrazoline derivatives. In this synthetic course, glacial acetic acid is not only a solvent, but also a catalyzer.

以1-苯基－3-甲基－5-苯氧基－吡唑-4-甲醛为原料，与苯乙酮发生羟醛缩合，生成相应的查尔酮，再在冰醋酸中与不同的肼反应，高产率的合成出10种新的5位含1-苯基－3-甲基－5-苯氧基－吡唑基的吡唑啉类衍生物。

Efficient conversion of pentaerythrite with carbonyl compounds,aldehyde or ketone,to the corresponding pentaerythritol dialdehyde or diketone compounds in the presence of ammonium hydrogen sulfate under microwave irradiation without solvent was described.

无溶剂微波照射下，通过硫酸氢铵催化季戊四醇和醛、酮反应合成了季戊四醇双缩醛、酮化合物。通过IR和1HNMR对产物结构进行了表征，研究了反应条件对产率的影响，最佳反应条件为微波照射功率750 W，照射时间1.5 min

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。