缩聚物

Optimization of polyester condensation process and reactor design;2. The Structure Characters of the Sulfonated Condensation Polymer Series High Performance;3. The pH value of the solution was adjusted,and the co- condensation reaction was taken place between the hydroxy groups forming transparent organic-inorganic hybrid films on polycarbonate.

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质，引入正硅酸乙酯水解产物硅溶胶作为无机增强物，调节两种混合溶液pH值，利用两者羟基之间的共缩聚反应在聚碳酸酯板表面制备有机/无机复合透明耐磨薄膜；采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。

According to the regular condensation polymerization principle, a certain amount of amino terminated polyether D230 and a certain amount of divinyl three amine are mixed uniformly by water, and then a certain amount of hexanedioic acid is added in and stirred for dissolving.

本发明属于工业水处理技术领域，具体涉及一种抑制水中二氧化硅/硅酸盐垢沉积的非离子型聚合物及其制备方法，该聚合物是一种含具有醚键、仲胺键、肽键结构的非离子型共聚物，具体为己二酸/端氨基聚醚/二乙烯三胺共聚物，按照常规的缩聚反应原理，首先用水将一定量的端氨基聚醚D230和一定量的二乙烯三胺混合均匀，然后加入一定量的己二酸并搅拌使其溶解。

This invention carrying through alcoholysis of common gloss polyester chip, getting low-molecular polymer of polytetramethylene terephthalate, using this low-molecular polymer as pregnant liquor, doing esterification reaction and polycondensation reaction of PTA and hybrid diatomic alcohol in normal pressure, getting the modified copolyester product which has inherent viscosity of 0. 65-0. 85dl/g, fine pellucidity and is suitable in the application of engineering plastics.

本发明是通过对普通大有光聚酯切片进行醇解，得到对苯二甲酸乙二酯低聚物，以此低聚物为母液，在常压下使PTA与混合二元醇进行酯化反应和缩聚反应，制备得到了特性粘数在0.65-0.85dl/g且具有良好透明性的适用于工程塑料领域应用的改性共聚酯产品。

Large single crystals were also obtained by using pyrocatechol as additive. It was shown by 〓Si-NMR and IR that Sipyrocatechol complex was formed in the reaction system.

在F〓体系中，F〓对铝源和硅源起络合和矿化作用，形成可溶性氟硅酸盐AlF〓〓、SiF〓〓络合物，然后缓慢水解成含氧氟硅酸盐络合物，它们再发生定向缩聚，提供了分子筛晶体生长所需的可溶性结构单元。

The catalysts such as tetraphenyl tin,aluminium isopropoxide and boron trifluoride etherate complex were used to catalyze the copolymerization.In addition,the copolyester can be given by copolycondensation after monomers were hydrolyzed by phosphoric acid.Boron trifluoride etherate complex was chosen as the catalyst because the catalytic activity was the best among the catalysts.

由于γ-戊内酯为五元环结构，难以进行开环聚合，因此分别考察了四苯基锡、异丙醇铝、三氟化硼乙醚络合物等催化剂，以及以磷酸为催化剂的水解缩聚反应，结果发现三氟化硼乙醚络合物的催化活性最高，因此选择三氟化硼乙醚为本体开环聚合的催化剂。

A series of sulfonated poly copolymers with different degree of sulfonation were synthesized by aromatic nucleophilic polycondensation of 3,3′-disulfonate 4,4′-dichlorodiphenylsulfone,4,4′-dichlorodiphenylsulfone and 4,4′-biphenol.

将磺化二氯二苯砜、二氯二苯砜与4，4′-联苯酚通过亲核缩聚反应得到一系列具有不同磺化度的磺化聚芳醚砜共聚物。

The invention uses the method of the fusion and direct polymerization to prepare the carboxyl-terminated lactic acid prepolymer and then copolymerize with the aliphatic polycarbonate; then the reaction is done in the twin-screw extruder to screw out the extension chain and the good polylactic acid copolymer is made.

本发明采用熔融直接缩聚的方法制备出羧基封端的乳酸预聚物，接着再与脂肪族聚碳酸酯二元醇进行共聚，然后再在双螺杆挤出机中进行反应挤出扩链，制备性能良好的聚乳酸共聚物。

Since complex constitutes of raw material, various reactions and phases are involved in the process of mesophase evolution, we suggest that a given carbonaceous mesophase product should be manufactured by selecting raw materials and setting pyrocondensation conditions according to the specific requirement of the product, so that products with the best structure and performance could be obtained.

通过讨论指出，由于炭质中间相涉及的原料种类多样，热缩聚制备过程中涉及的反应、物相复杂，因此，在制备特定性能的产品时，应针对产品的特定性能要求来选择原料、设定热缩聚条件，以制得具有最佳结构和性能的产品。

The present invention provides an improved method of producing polyester by the polycondensation of polyester forming reactants wherein the improvement comprises utilizing, as the polycondensation catalyst, lithium titanyl oxalate.

本发明提供了一种由制备聚酯用反应物的缩聚反应制备聚酯的改进方法，其中的改进包括使用钛氧基乙二酸锂作为缩聚反应催化剂。

The concrete steps are: the lactic acid and small-molecule dicarboxylic acid react under the condition with the presence of the catalyst to directly polymerize the carboxyl-terminated lactic acid prepolymer; then the aliphatic polycarbonate diol and the catalyst are added; with the presence of the N2, the reaction is kept for 1 to 10 hours at the temperature of 150 to 200 Celsius system to get the poly lactic acid and polycarbonate copolymer of the low molecular weight; then the reaction is done in the twin-screw extruder at the temperature of 150 to 190 Celsius system to screw out the extension chain; finally the polylactic copolymer of the high molecular weight, toughness and heat resistance is made.

具体步骤是：乳酸和小分子二元酸在催化剂条件下反应直接缩聚合成羧基封端的乳酸预聚物，然后加入脂肪族的聚碳酸酯二元醇和催化剂，在N 2 气氛下，抽真空，在150～200℃温度下，反应1～10小时，得到低分子量聚乳酸/聚碳酸酯共聚物，然后在双螺杆挤出机中在140～190℃下，进行反应挤出扩链，最终得到高分子量的、韧性与耐热性较好的聚乳酸共聚物。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。