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The results show that the different amount of water addition could alter the structure of condensation polymer and the calcination temperature had great effect on phase structure and grain size.

结果表明:加水量影响醇盐水解缩聚物的结构,煅烧温度对粉体的形貌和晶粒大小有较大的影响。

It was found that the solvent type affected the gel point, the different amount of water addition could alter the structure of condensation polymer, the varying of ageing time influenced the growth of grains and the calcination temperature had great effect on phase structure and grain size.

发现不同的溶剂类型能够改变胶凝时间,加水量的多少会影响醇盐水解缩聚物的结构,陈化时间的长短直接改变晶粒的生长状态,煅烧温度的变化对粉体的相结构和晶粒大小有重要的作用。

EDTA-diaminodibenzo-18-crown-6 (cis- and trans-) condensation polymer is a new compound of crown ether derivatives of EDTA.

本文报道了一种新的EDTA-二氨基二苯并-18-冠-6缩聚物顺、反异构体对铀和铀在盐酸介质中的吸附行为。

High molecular weight polymer Ⅰ and Ⅱ with decomposition temperature of 560℃ were prepared from condensation of two diamine and terephthaloyl chloride respectively.

两种二胺分别与对苯二甲酰氯进行直接缩聚反应,得到的聚合物分别为缩聚物Ⅰ和Ⅱ,两种缩聚物的热分解温度均超过560℃。

In the early seventies, Whiteway et al. have criticized Flory for deriving, the MWD function of A_a type polycondensate and proposed a new MWD function themselves.

七十年代初Whiteway等人批评了Flory导出的A_a型缩聚物的分子量分布函数并建议了一个由他们导出的新分布函数。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物,通过&Click chemistry&,合成了具有1,2,3-三唑环结构单元的全氟环丁基类聚芳醚;利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应,制备了具有苯基氧膦结构单元的含氟聚芳醚;通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应,得到了具有PPO结构单元的含氟聚醚酰亚胺。

It has been successfully applied in the fields of high-performance carbon fiber, needle coke used for ultrahigh power electrode, anode of rechargeable lithium-ion batteries, activated carbon with super-high surface area, catalyst supports and carbon foams、 In this paper, the effects of raw materials and pyrolysis conditions including heat-treatment temperature, pressure and time on the formation and development of carbonaceous mesophase were discussed in detail Since complex constitutes of raw material, various reactions and phases are involved in the process of mesophase evolution, we suggest that a given carbonaceous mesophase product should be manufactured by selecting raw materials and setting pyrocondensation conditions according to the specific requirement of the product, so that products with the best structure and performance could be obtained.

它在高性能炭纤维、超高功率电极用针状焦、锉离子二次电池负极、超高比表面积活性炭及催化剂载体、泡沫炭等领域得到了较好的应用。综述了原料和热缩聚条件对炭质中间相形成和发展的影响,这些影响因素包括原料的种类、热缩聚温度、反应压力和保温时间等。通过讨论指出,由于炭质中间相涉及的原料种类多样,热缩聚制备过程中涉及的反应、物相复杂,因此,在制备特定性能的产品时,应针对产品的特定性能要求来选择原料、设定热缩聚条件,以制得具有最佳结构和性能的产品。

A silicon carbide slurry as a casting abrasive material was prepared by sulphonated acetone-formaldehyde polymer as a dispersant.

由自制的磺化丙酮-甲醛缩聚物(sulphonated acetone-formaldehyde plymer,SAF)作为分散剂制备了浇注碳化硅砂轮水基浆料。

The adsorption behaviour of chemically different superplasticizers, such as melamine formaldehyde sulphite polycondensate,β-naphthalene sulfonate formaldehyde polycondensate and polycarboxylate, on early hydrating cement phases was studied. For this purpose, pure ettringite AF(subscript t, monosulfate AF(subscript m and syngenite were prepared. The adsorbed amount and zeta potential of early hydration products were measured.

制备了钙矾石AF(下标 t、单硫型硫铝酸钙AF(下标 m和钾长石类单矿物,并研究了三聚氰胺磺酸盐甲醛缩聚物、β-萘磺酸盐甲醛缩合物及聚发酸盐等几种化学成分不同的超塑化剂在其早期水化颗粒表面上的吸附行为。

Adopting condensation copolymerization between alkylphenol polyoxyethylene ether and methyl aldehyde and using concentrated sulfuric acid sulfonation, which it with sodium hydroxide neutralization, finally acquired sulphonate anionic surfactant, utilize as temperature resistance 、mineral salt tolerance for heavy oil viscosity reducer , research on the performance evaluation, the result indicate, the amount of sulphonate anionic surfactant to be used at 0.2wt%, viscosity reducer rate reached 92.1%; added with 0.5wt%, the calcium and magnesium ions resistance in mineral water up to 800mg/L.

采用辛基酚聚氧乙烯醚和甲醛的共缩聚物与浓硫酸磺化后,再用氢氧化钠中和后得到磺酸盐阴离子表面活性剂作耐温抗矿盐稠油降粘剂,并对其进行性能评价,结果表明,辛基酚聚氧乙烯醚甲醛共缩聚物磺酸盐阴离子表面活性剂加量为0.2wt%时,降粘率高达92.1%,抗钙、镁离子能力达800mg/L。

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