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The Automotive Finishes was composed of Cardura E 10-based acrylic resin with high-solids and excellent weather resistance as main resin, and Cardura E10-based polyester resin with high-solids as additional resin to be used to improve decorative properties, such as chubbiness, gloss, PGD,and so on, of the only acrylic amido automotive finishes.

该面漆以叔碳酸缩水甘油酯(商品名E10)改性高固体份丙烯酸树脂作为主体树脂,该树脂是具有高耐候性的丙烯酸树脂,以叔碳酸缩水甘油酯改性高固体份聚酯树脂作为添加树脂,弥补单纯丙烯酸氨基漆在丰满度、光泽、鲜映性等外观装饰性等方面的不足,从而形成高耐候性、高装饰性的高品质、高固体份汽车面漆。

The cardanol glycidyl ether and nonyl phenyl glycidyl ether were synthesized by using cardanol and nonyl phenol as raw material respectively. The products structure and the structure of CGE/E51 and NGE/E51 cured system were characterized by FT-IR.

以腰果酚、壬基酚为原料制备了环氧树脂活性稀释剂腰果酚基缩水甘油醚和壬基苯基缩水甘油醚,对其结构及其与E51共混体系的固化物结构进行了红外光谱表征。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷,包括:γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3,4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3,4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

A photosensitive prepolymer was prepared by the reaction of tetrahydrocannabinol phthalate glycidyl and acrylic acid, and optimized the reaction conditions. The structure of the resin was characterized by FT-IR.

以四氢邻苯二甲酸二缩水甘油酯与丙烯酸反应制备缩水甘油丙烯酸酯,优化了合成反应的条件,并用红外光谱对产物结构进行了表征。

The intermediate decyl-glycidol ether of Gemini phosphate surfactant was synthesized with decanol and epichlorohydrin in the presence of phase-transfer catalyst; the intermediate decyl digomeric glycol of Gemini phosphate surfactant was prepared by opening ring reaction of decyl glycide ether and glycol in the presence of potassium as catalyst; and the influence of type and dosage of phase-transfer catalysts was studied.

以正癸醇与环氧氯丙烷为原料在相转移催化剂存在的条件下合成Gemini磷酸酯表面活性剂的中间体I-正癸基缩水甘油醚,讨论催化剂种类及用量对反应的影响;以乙二醇和正癸基缩水甘油醚为原料,金属钾为催化剂合成Gemini磷酸酯表面活性剂的中间体Ⅱ-正癸基低聚二醇,讨论催化剂种类与用量对反应的影响;以P2O5与正癸基低聚二醇为原料合成Gemini磷酸酯表面活性剂,讨论投料比、反应温度和反应时间等因素对反应的影响。

In the presence of DMAc/LiCl solvent, disproportionated rosin glycide-cassava starch ester was synthesized from cassava starch and modified disproportionated glycide ester under microwave irradiation. The effect of reaction conditions on the degree of substitution has been discussed.

在微波辐照下,以DMAc/L iC l为溶剂体系,歧化松香缩水甘油酯和木薯淀粉亲核开环反应得到歧化松香缩水甘油木薯淀粉酯,探讨了各反应因素对产物取代度的影响。

Stability of electrodeposition liquid, the physical and chemical resistance properties of the film depend on amine value, kinds of glycidic ester used, GA content and the amount of blocked polyisocyanate used.

结果表明,环氧基在固化过程中会参与交联反应,电泳液的稳定性、涂膜的物理性能和耐化学品性能由胺值、缩水甘油酯单体种类、丙烯酸缩水甘油酯含量和封闭型多异氰酸酯用量等因素决定。

The synthetic route of glycidyl nitrate was improved. Glycidol was synthesized by the cyclization process from allyl alcohol and m-CPBA, then glycidyl nitrate was synthesized with glycidol as raw materials and HNO3/ 2O as nitrating agent.

为了改进缩水甘油醚硝酸酯的合成路线,以丙烯醇为原料,经间氯过苯甲酸环氧化后得到缩水甘油醇,然后GA经硝酸/醋酐硝化后得到了GN,硝化产物GN的收率为70.2%,经过减压精馏后GN的纯度达到了98.9%。

The result showed that the thermal decomposition temperature of chlorinated paraffin reached 133℃ by adding 0.3% composite stabilizer in which the weight percentages of ethylene glycol diglycidyl ether, methyl stannic, triphenyl phosphate, exoxidized soybean oil were 72%, 3%, 10%, 15%, respectively. It is 15℃ more than that of using pure ethylene glycol diglycidyl ether.

结果表明:当复合稳定剂中乙二醇二缩水甘油醚、甲基锡、亚磷酸三苯酯、环氧大豆油的质量分数分别为72%,3%,10%,15%,复合稳定剂的添加量为氯化石蜡的0.3%时,氯化石蜡的热分解温度为133℃,比单独使用乙二醇二缩水甘油醚提高了15℃,热稳定效果较好。

Glycidyl benzoate,glycidyl propionate,glycidyl acetate were obtained respectly through a phase-transfer catalytic methodology using sodium benzoate, sodium propionate, sodium acetate and epichlorohydrin as raw materials, and pure products were obtained though vaccum distillation.β-cyclodextrin and glycidyl benzoate, glycidyl propionate, glycidyl acetate, reacted in organic solvent and goal product were

先以苯甲酸钠、乙酸钠、丙酸钠和环氧氯丙烷为原料在相转移催化剂的作用下分别合成了苯甲酸缩水甘油酯、乙酸缩水甘油酯和丙酸缩水酯,经过减压蒸馏,得到相应的纯品;β-环糊精和苯甲酸缩水甘油酯、乙酸缩水甘油酯、丙酸缩水甘油酯在有机溶剂中反应,经过硅胶色谱柱分离,得到了相应的产品,产品经过TLC、IR、1H NMR、MS表征,并研究了温度、反应时间、催化剂等几个因素对反应工艺的影响,结果表明温度和催化剂对反应的快慢有较大影响。

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