缩二脲

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

Through analysis on the technology characteristic and the main operating point in the different parts of process, such as granulation system temperature control, biuret concentration control, aminated triple superphosphate, dedusting and washing system, raw material distribution system and so on, the advantage of high-nitrogen compound fertilizer produced by K-T process is remarkable.

介绍尿基复合肥K-T技术工艺流程；通过造粒，系统温度控制，缩二脲含量控制，重钙的氨化，除尘洗涤系统，配料系统等方面的技术特点，操作控制要点的分析，指出K-T工艺生产高氮复合肥的突出优势。

Key words: compound fertilizer; determination; biuret; spectrophotometry; interference matter

濮阳市氯碱厂，河南濮阳 457000 复合肥；测定；缩二脲；分光光度法；干扰物质

The characters and applications of vacuum film evaporation and molecular evaporation are outlined, and an XZN inner-cooling vacuum agitated film evaporator was used to reduce free monomer from HDI biuret , which is for improving the quality of polyurethane paints and coatings, decreasing pollution and danger to worker.

本文介绍了真空薄膜蒸发和分子蒸发的原理、特点和应用，并介绍了真空薄膜蒸发-冷凝工艺在分离HDI 缩二脲中游离单体中的应用。

The electrochemical property of PDT and PDT metal complexes were characterized by CV, from the result of CV, it can be found that PDT and PDT metal complexes possesses electrochemical activity, which arised from the heteroatom of molecules.

我们用循环伏安表征了对二苯甲醛缩氨基硫脲及其金属络合物的电化学性质，从循环伏安的结果来看，对二苯甲醛缩氨基硫脲及其金属络合物具有一定的电化学活性，并且这些电化学活性主要来自于分子中的杂原子。

Dioxide quinoxaline formaldehyde semicarbazones and imines were synthesized by the reactions of 1,4-dioxide quinoxaline formaldehyde with aminourea or substituted anilines.

用1，4-二氧喹喔啉甲醛与氨基脲、苯胺、取代苯胺等反应，合成了11种1，4-二氧喹喔啉甲醛－缩氨脲和醛亚胺。

The recent advances in the main clean processes to synthesize diphenylmethane diisocyanates are reviewed, such as BTC method, condensation of aniline, reductive carbonylation of nitrobenzene, oxidative carbonylation of aniline, methoxycarbonylation of aniline, alcoholysis of N,N'-diphenyl urea and the coupling process.

回顾了清洁合成二苯甲烷二异氰酸酯的几种主要方法，如BTC法、苯胺缩和法、硝基苯还原羰基化法、苯胺氧化羰基化法、碳酸酯法、二苯基脲法和反应耦合法等合成路线。

Additionally LC-MS was also used in qualitative analysis of the reactionsystem for the synthesis of dipropyl toluene-2,4-dicarbamate TDC(Pr. The main side-reactions were condensation reactions between 3-amino-4-methyl N-propylphenylcarbamate with TU or toluene 2,4-bisurea.

同样，运用液质联用技术对甲苯-2，4-二氨基甲酸丙酯TDC合成反应进行了定性分析，确定了副产物并推测其主要副反应是中间产物3-氨基-4甲基苯氨基甲酸丙酯与TU和甲苯-2，4-二脲之间的缩合反应。

The experimental results showed that when AcO-or other anion s were added to a solution consisting of 1,5-(di-benzaldehyde) dithiocarbohydrazone and Hg2+(at a ratio of 1∶2),a hypsochromic shift took place on the maximum ultraviolet absorption peak of the ligand.

设计合成了配体1，5-二双缩二氨基硫脲及其金属配合物，探讨了不同金属阳离子对1，5-二双缩二氨基硫脲紫外吸收光谱的影响，并将标题化合物应用于阴离子识别。

Firstly, phenyliodine diacetate was immobilized to the 2% cross-linked polystyrene or the liner polystyrene resin. The more iodine the resin had, the lower conversion to phenyliodine diacetate. We made our endeavor to extend the range of useful application of polystyrene supported phenyliodine diacetate in organic synthesis:(1) the reagent was used as an effective reagent of carbonyl regeneration from oximes and semicarbazones of ketones.(2) the reagent was also applied to the synthesis of 1, 3, 4-oxadiazoles, 1, 3-disubstituted-2-pyrazoline, 2-arylbenzoxazole from aldehyde N-acylhydrazones, aldehyde hydoazones and phenolic Schiff's bases respectively.

首先，我们以2％交联的聚苯乙烯和线性的聚苯乙烯树脂为载体，制备了聚合物负载的二醋酸碘苯，通过研究发现：(1)聚苯乙烯二醋酸碘苯是酮肟、缩氨脲有效的去保护试剂，不仅芳香酮，脂肪酮和α，β不饱和酮的肟、缩氨脲也能顺利转化为相应的酮，实现酮基的再生；(2)我们还利用此试剂，分别与醛的N-酰基苯、N-酰基苯腙及邻羟基芳亚胺反应，在温和的条件下发生成环反应，以良好的产率生成1，3，4-噁二唑、吡唑啉和二取代苯并噁唑等杂环化合物；(3)聚苯乙烯二醋酸碘苯还可有效地将邻羟基芳酮的酰腙经氧化、重排成1，2-二酰基苯。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。