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绿泥石

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The lithologies of the Al rich rocks under ultra high pressure metamorphism in central China are characterized by kyanite topaz quartzite which has special mineral associations of kyanite, rich topaz,Mg rich chloritoid,coesite and diaspore.

我国中部在超高压条件下形成的高铝质变质岩石,以蓝晶黄玉石英岩为特征,具有以蓝晶石、富水黄玉、富镁硬绿泥石、柯石英、硬水铝石等为代表的高压-超高压变质矿物,矿物组合主要为蓝晶石+黄玉+石英、蓝晶石+蓝刚玉±富镁硬绿泥石等。

Confirmation of high-pressure pelitic rocks in the north. The mineral assemblage of the early stage is gamet-Mg-rich chloritoid +phegite +quartz ±kyanite ±aragonite or gamet+Mg-rich chloritoid+phengite+paragonite+quartz, P-T conditions are 550±30℃ and 1.4~2.0GPa; the mineral assemblage of the late stage is muscovite +chlorite+quartz±albite, which undergone retrograde metamorphism of greenschist facies, P-T conditions are <550℃ and <0.6GPa.

确定北部高压变泥质岩石,早期矿物组合为石榴子石+富镁硬绿泥石+多硅白云母+石英±蓝晶石±文石或石榴子石+富镁硬绿泥石+多硅白云母+钠云母+石英,对应的温压条件为550±30℃和1.4~2.0GPa;晚期矿物组合为白云母+绿泥石+石英±钠长石,经受了绿片岩相的退变质作用,其温度小于550℃,压力低于0.6GPa。

In the experiment,ζ-potential of the two minerals were measured, and the effects of pH, concentration of oleic acid and flotation time on the purity and recovery of SiO2 were tested. Furthermore, the crystal structure, surface characters of quartz and clinochlore, and the solution chemistry of oleic acid as the anionic collector were analyzed.

实验中测定粉石英和斜绿泥石的ζ电位、pH值、油酸浓度、浮选时间对SiO2回收率和纯度的影响;分析粉石英、斜绿泥石的晶体结构和表面性质以及油酸作阴离子捕收剂时的溶液化学。

The results show that quartz cannot react with oleic irons at pH=8-10, because it is difficult to combine with metallic irons. On the contrary, clinochlore can adsorb with oleic ions because there are enough active metallic positive ions between the minerals layers which can combine with clinochlore. The clinochlore can be hydrophobic, and so the separation can be realized finally. At pH=9, the clinochlore removal rate is the maximum, the purity of SiO2 is 99.86%, and the recovery of SiO2 is 35%.

结果表明:在pH为8~10的碱性溶液中,粉石英难与金属阳离子缔合,所以,不与油酸根离子结合;而斜绿泥石解离后层间存在活性金属阳离子,可与油酸根离子发生化学吸附产生疏水作用,因而使用反浮选的方法能有效地实现二者的分离:当pH为9时,斜绿泥石的去除率最高,粉石英的纯度达99.86%,回收率为35%。

Field obserbation and laboratory study indicate the main type of rock alterationwere K-feldsparization, biotitization, sericitization, silication, epidotization,chloritization and carbonatization. From early to late, these alteration could dividedinto three epochs: early-stage was K-feldsparization-biotitization, middle-stage wasquartzification -sericitization, late-stage was silication, carbonatization, epidotizationand chloritization.

通过野外观察及室内研究表明,围岩蚀变类型主要有钾长石化、黑云母化、绢云母化、硅化、绿帘石化、绿泥石化和碳酸盐化,从早至晚可分为三期:早期为钾长石-黑云母化;中期为石英-绢云母化;晚期为硅化、碳酸盐化和绿泥石、绿帘石化。

With the Jinshan gold deposit in Jiangxi Province as an example, the authors determined the crystallinity, mean crystal size and lattice strain of illite and chlorite and, on such a basis, discussed the difference of crystallinity, mean crystal size and lattice strain between illite and chlorite caused by deformation of mylonite and untramylonite.

本文以江西金山金矿为例,通过对热液蚀变粘土矿物伊利石和绿泥石结晶度、平均结晶大小和晶格应变的测定,讨论了岩石变形对伊利石和绿泥石结晶生长差异的影响。

The study revealed that: 1 chlorite occurred in vein, agglomerate or had the false pattern of biotite type, or the worm or bladed configuration; 2 Fe/Si diagram revealed mast of the chlorite occurred in the ferroamesite and aphrosiderite areas, few in the pycnochlorite area; 3 the formation temperature of chlorite varied from 179-276℃, mainly within the range of 230-260℃ as calculated by the empirical equation presented by Battaglia; 4 chlorite was formed in the reducing condition, the main formation mechanisms were dissolution-precipitation and dissolution-migration-precipitation.

研究表明:①岩石中绿泥石主要呈脉状、黑云母假象或团块状等产出,具有蠕虫状、叶片状等形貌特征;②绿泥石的Fe/Si图解显示201和361铀矿床中绿泥石主要为铁镁绿泥石和蠕绿泥石,少数属密绿泥石;③根据Battaglia提出的经验方程式计算了201和361铀矿床绿泥石的形成温度变化于179~276℃之间,且主要介于230~260℃之间;④绿泥石主要形成于还原环境,其主要的形成机制是溶解-沉淀和溶解-迁移-沉淀。

AndLeptochlorite in Goutouling mine, chamoisite in Bailashui mine and brunsvigite inWuchangping and Shanmenkou mines are concluded by Electron-probe analysis .The content ofFe is richer in this field, which demonstrates forming environment is relatively acid andFe/ of different stages of mineralization is regular.

对其电子探针分析表明,绿泥石的种类分别是狗头岭矿区的鳞绿泥石、白腊水矿区的鲕绿泥石、山门口和白腊水屋场坪矿区的铁镁绿泥石和辉绿泥石,说明芙蓉锡矿田中绿泥石都为富含铁的绿泥石,铁取代镁,铁含量增大,表征其形成于相对酸性环境,且不同成矿期Fe/有一定规律性。

The results show that the chlorite jade is in dark green, semi-translucent to opaque, and lepidoblastic texture, with hardness of 2.5, refractive index 1.58 and density 2.60 g/cm^3. It has homogeneous texture and less fissures, and no fluorescence under ultraviolet fluorescence lamp. XRD analysis shows that the mineral composition of the chlorite jade is mainly chlorite.

结果表明,该绿泥石玉呈深绿色、微透明-不透明集合体,具鳞片变晶结构,裂隙少,质地均匀,在紫外荧光灯下不发荧光,摩氏硬度为2.5,折射率为1.58,密度为2.60g/立方公分。X射线衍射分析结果表明,该绿泥石玉的物相为绿泥石

The author analyses and studies in detail through X-diffraction test of up to date special reserver samples and find that 1:1 regulation mix layers of corrensite and allevardite exists in some piecis of the eroded volcano tuff 's sandstone at the same time, and can appear continuously in a large amount In a certain limit, authors point out characteristic of corrensite and allevardite in this district and it's mining to genesis mineralogy that related to stratum water and trace element geochemistry characteristics.

作者通过最近的海拉尔盆地特殊储层样品的X衍射试验分析和详细研究,发现1:1规则混合层矿物柯绿泥石和钠板石同时存在于海拉尔盆地含火山凝灰质蚀变储层或非储层的某些井段中,而且在一定范围内的岩石孔隙中可以大量持续出现,指出了本区柯绿泥石和钠板石的组合特征,结合该区地层水和微量元素地球化学特征以及重砂特征等研究了柯绿泥石和钠板石的成因矿物学意义和其它石油地质意义。

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