结构体

The structure of ArsA ATPase with its ligand, arsenite, either on membranes or in solution, was revealed. The current trimeric ring-like structure of this protein doubts the previous dimeric model and gives deeper insight on this protein's physiological roles.

对亚砷酸根复合体ArsA蛋白质分子结构的揭示显示了该蛋白在亚砷酸根存在情况下，在膜上和水溶液中都是环形三聚体，对前人的二聚体模型假说提出了置疑，并为解释它的生理功能提供了重要的结构信息。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮，1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2，2-联吡啶，邻菲啰啉，三苯基氧膦)合成了16个稀土红外配合物(Ln=Er，Nd，Yb)，获得了其中三个配合物的单晶结构，研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

In this thesis, on the one hand, two new tripodal ligands and twenty-three of their lanthanide complexes were synthesized, and their fluorescence properties were investigated, on the other hand, nine new copper and silver complexes with six kinds of tripodal ligands were synthesized and their crystal and molecular structures were determined by X-ray diffraction analysis.

本论文一方面合成了两个新三脚架配体的23个稀土配合物，并对它们的发光性能进行了探讨；另一方面得到了涉及六种三脚架配体的9个铜、银配合物，并测定了它们的晶体结构。

The results indicated that: Tripyrazolone, tripodal and crptands ligand L〓, L〓 and L〓 have good coordination ability with rare earth ions Rare earth ions were coordinated with their oxygen and nitrogen atoms.

结果表明，三脚架结构吡唑啉酮、三酸和穴醚配体与稀土离子有较好的配位作用，它是通过氮原子、氧原子与稀土离子配位的。而穴醚配体与稀土离子配位效果却不好。

As the twinborn shear department of {112}m is obstructed, slipping department {111}P of parent phase begin to work, rely on dislocation"s slipping, coordinate flaky martensite"s twinborn shearing and form dislocation inferior structure at M phase corresponding plane(contain the interface between parent phase and martensite phase).

在本实验电镜照片上可以观察到在片状马氏体亚结构同时存在相变孪晶和形变孪晶，当{112}_m孪生切变系受阻时，母相中滑移系{111}_p启动，依靠母相中的位错滑移协调片状马氏体的孪生切变。

Due to their high strength and overall performance, the panels can be used as division and partion wall even the wall is very high and wide. Only steel structure should be used for fixing which is unstalled inside the wall and it is unnecessary to add wall posts. The anti-blast performance is 1.5 higher than that of brick wall.

由于强度高，整体性能好，因此可用作层高高、跨度大的墙体间隔，只要简单地采用钢结构锚固，型钢埋设于墙体内，大跨度，层高高的墙体就无需增加墙面的柱体，其抗冲击性能是一般砌体的1.5倍。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

Is it print micro-structure etch micro-structure height their that happen layout 3.5μm in 150-240nm to transfer to in a large amount, utilize and etch two times to transfer wetly to technology of printing, but a large amount of models the small and complicated three-dimensional structure.

在研制高发光的二极体，可由鳞片内类似光子晶体的微小结构PCS，所形成高亮度发光二极体。

By mineralogical analysis of Jidong magnetite concentrates what can be found is that: It is mainly composed of magnetite, concentrate grain is medium-coarse granular crystal texture, the most is subidiomorphic or xenomorphic, is chevron and granulated, surface of the concentrate is smooth, minority of concentrate has inclusion or intergrowth, grain inch normally is 0.05~0.16mm, there is incompletely cleavage in concentrate grain.

矿相分析表明：冀东磁铁精矿粉以磁铁矿为主，矿粉颗粒为中粗粒变晶结构，多为半自形或他形，呈尖棱碎粒状，其表面光洁平滑，少数有包裹体或连生体，粒径一般为0.05～0.16mm，矿粒存在不完全解理。

It is concluded that the infrared photodissociation spectroscopy of protonated serine clusters H+n, n = 2 8, provides evidence for a size-dependent transition from neutral to zwitterionic network structures.

第四章的结论中提到由此一系列由二至八的丝胺酸团簇红外吸收光谱结果，我们观察到从二聚体的中性丝胺酸单位到八聚体的两性离子单位，中间经历了结构转换的过程。

It was Napoleon, the immense somnambulist of this dream which had crumbled, essaying once more to advance.

那人便是拿破仑，梦游中的巨人，他还想往前走，去追寻那崩塌了的幻境。

This method alleviates the highly dependent on domain knowledge experts. The quality and efficiency of the KBS were improved.

使用这种设计方法减小了对领域知识专家的严重依赖，提高了知识系统开发的质量和效率。