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The recent advancement of the asymmetric addition of organozinc reagent s to ketones and α-ketoesters is reviewed according to the type of the chiral ligands, with an emphasis on the introduction of the ligands with high efficiency and high selectivity.

按照手性配体的结构类型分类,综述了近年来有机锌试剂对酮、α-酮酯等化合物的不对称加成反应的研究进展,对高效、高选择性的手性配体在该类反应中的应用进行了重点评述。

After highly fractionating, this Crrich magma formed massive chromite (i.e., Saertuohai chromite deposit), and the melt moved into the mantle rock, and formed the wormlike intergrowth texture consisting of Crspinel and orthopyroxene.

这种富铬岩浆高度分异形成铬铁矿块体后,熔体进入地幔岩中结晶形成铬尖晶石和斜方辉石的蠕虫状共生连晶结构。

After highly fractionating, this Cr-rich magma formed massive chromite (i.e., Sa' ertuohai chromite deposit), and the melt moved into the mantle rock, and formed the worm-like intergrowth texture consisting of Cr-spinel and orthopyroxene.

这种富铬岩浆高度分异形成铬铁矿块体后,熔体进入地幔岩中结晶形成铬尖晶石和斜方辉石的蠕虫状共生连晶结构。

To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Topics include: properties, preparation, and processing of compound semiconductors; theory and practice of heterojunctions, quantum structures, and pseudomorphic strained layers; metal-semiconductor field effect transistors; heterojunction field effect transistors and bipolar transistors; photodiodes, vertical-and in-plane-cavity laser diodes, and other optoelectronic devices.

主要内容包括:化合物半导体的特性、制备与制程;异质接面、量子结构和假晶应变层的理论与实际应用;金属半导体接面场效电晶体;异质接面场效电晶体以及异质接面双极电晶体;检光二极体、垂直和平面共振腔镭射二极体、以及其他光电元件。

Topics include: properties, preparation, and processing of compound semiconductors; theory and practice of heterojunctions, quantum structures, and pseudomorphic strained layers; metal-semiconductor field effect transistors; heterojunction field effect transistors and bipolar transistors; photodiodes, vertical-and in-plane-cavity laser diodes, and other optoelectronic devices.

主要内容包括:化合物半导体的特性、制备与制程;异质接面、量子结构和假晶应变层的理论与实际应用;金属半导体接面场效电晶体;异质接面场效电晶体以及异质接面双极电晶体;检光二极体、垂直和平面共振腔雷射二极体、以及其他光电元件。

The results from ultraviolet spectroscopy and photo -luminescence spectroscopy revealed that:(1) Europium complexes based on neutral ligands, such as azaphenanthroline 2-aryl-5-(α-pyridyl)-1,3,4-ozadiazole had a strong UV absorbance at the wavelength of 290-350 nm and the characteristic PL spectrum of europium ion at 613 nm respectively;(2) The structures of ligands had a critical role influence on PL intensity of europium complexes.

紫外光谱和光致发光光谱研究表明:(1)以氮杂邻菲罗啉、2-芳基-5--1,3,4-噁二唑为中性配体的铕配合物在290~350nm左右都有强烈的紫外吸收,且在紫外光的激发下都能产生铕离子的特征光谱(613nm);(2)配体的结构是影响铕配合物发光强度的关键因素之一。

A lot of organelles such as mitochondria, rough endoplasmic reticula and Golgi bodies were observed in fiber cell. Then, double karyotheca disappeared, and the organelles disintegrated. Multivesicular bodies appeared in fiber cytoplasm. With the further development of fiber, fiber wall underwent continual thickening with aging, and polylaminate structure gradually appeared. While the agglutinated nucleus, transfer vesicles, plasma membrane and plasmodesmata still presented.

研究发现,次生壁形成早期,细胞核具有双层核膜,染色质凝聚,可见大量的线粒体、粗面内质网和高尔基体等细胞器存在于纤维细胞中;随后,双层核膜消失,细胞器将逐渐解体,多泡体开始出现在纤维细胞的细胞质;随着年龄的增加,纤维细胞壁逐渐增厚,并出现多层结构现象,而运输小泡、细胞膜、胞间连丝和凝聚的染色质将持续存在。

In the previous study, we have found that ischemia/reperfusion could cause structural and functional damages to sinoatrial node cells in vivoand in vitro, leading to electrophysiological disturbance by affecting the regular rhythm and frequency.

本实验室在前期的研究中发现,缺血/再灌注可引起在体及离体窦房结细胞结构和功能的改变,影响其电信号发放的节律和频率,导致电生理活动的紊乱。

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It was Napoleon, the immense somnambulist of this dream which had crumbled, essaying once more to advance.

那人便是拿破仑,梦游中的巨人,他还想往前走,去追寻那崩塌了的幻境。

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使用这种设计方法减小了对领域知识专家的严重依赖,提高了知识系统开发的质量和效率。

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