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The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ′(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ′(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ′(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ′(Al3Li) and so strengthen the alloy.

计算结果表明:不包含空位的偏聚晶胞的键络最强键为Al—Al键,其中Al原子的共价半径较Li原子的共价半径要大;而含空位的偏聚晶胞的最强键为Al—Li键, Al原子的共价半径要比Li原子的共价半径要小;在空位存在的情况下,由于Al原子与Li原子的电负性相差明显,促使Al和Li原子结合,倾向形成Al-Li短程序结构偏聚区,这种含空位的短程序结构很可能就是δ′(Al3Li)亚稳相的前兆结构和生长胚胎;由于Al-Li-空位有序偏聚晶胞的Al—Li键络比基体键络要强许多,因此,淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用;后续析出的δ′(Al3Li)亚稳相键络各项异性显著,键络强度明显提高;由于Al3Li与基体共格,其大量均匀弥散析出起到提升基体整体键络强度,同样对合金产生强化作用。

The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ'(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ'(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ'(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ'(Al3Li) and so strengthen the alloy.

计算结果表明:不包含空位的偏聚晶胞的键络最强键为Al-Al键,其中Al原子的共价半径较Li原子的共价半径要大;而含空位的偏聚晶胞的最强键为Al-Li键,Al原子的共价半径要比Li原子的共价半径要小;在空位存在的情况下,由於Al原子与Li原子的电负性相差明显,促使Al和Li原子结合,倾向形成Al-Li短程序结构偏聚区,这种含空位的短程序结构很可能就是δ'(Al3Li)亚稳相的前兆结构和生长胚胎;由於Al-Li-空位有序偏聚晶胞的Al-Li键络比基体键络要强许多,因此,淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用;后续析出的δ'(Al3Li)亚稳相键络各项异性显著,键络强度明显提高;由於Al3Li与基体共格,其大量均匀弥散析出起到提升基体整体键络强度,同样对合金产生强化作用。

ZL03 2 354312.The innovations include: automatic self-closing and reliably sealed valve structure: the design of duplex valve clack with pilot valve to tackle the problem of reverse seal structured valve being difficult to be opened; an automatic drain control device to automatically drain the remaining water from the hydrant; protective plate provided between the hydrant body and the valve block to serve as a connection between the hydrant body and the valve block, which is the first one to be damaged when the ground hydrant is clashed, and prevent pulling-off of the whole above-ground part of the fire hydrant, so as to properly protect the main parts from any damage. The self-closing and reliably sealed valve now prevents drain of water, and only the damaged protective plate is needed to be replaced before immediate re-operation. Thus the repair work after clashing is very easy and simple.

其创新点为:具有能自动关闭并可靠密封的阀门结构:采用有先导阀复式结构阀瓣设计,解决反向密封结构阀门开启沉重费力的难题;设计自控排水装置,能自动排除栓体内余水;在栓体和阀体之间设计撞裂板,它既起到连接栓体和阀体的中介作用,又可在地上消火栓被撞击时率先破裂毁坏,并使露出地面的栓体不见整体脱落,有效保护各主体部件的完好无损,而此时阀门的自闭式结构可靠密封阀门阻止水源外泄,修复时只需更换损坏的撞裂板即可立即复位投入使用,使被撞后的修复工作变得十分轻松简便。

From the equilibra configures obtained during simulating, it was suggested that there is mainly chaintype structure in the LiBO〓 melt, and the dominative variations during the process of being fused may be the decomposition of the long chains, then large member of nonbridge oxygen was come into being in the shorter chains resulting from the decommission.

模拟得到的二硼酸锂熔体中,三配位和四配位的硼氧结构共存,其间相互结合成环状结构;而在偏硼酸锂熔体中没有发现四配位构型,由平衡构像分析,该熔体中可能以链式结构为主,熔化过程中主要的结构变化是长链的分解,分解产生的短链结构产生了大量非桥氧。

In resting cysts, the microtubules under the pellicle, cortical ciliatures, conjunctions between cilia basal bodies, supporting structure of basal bodies and other microtubule structures are absorbed in different extent; microtubule-like assemble bodies appear at the center of the remained cilia basal bodies; the granules of chromatin and nucleolus in macronucleus become smaller whereas nucleus pores of the micronucleus become bigger; the inner membrane of some nucleus pores are attached with chromatin.

结果表明:纤毛虫形成包囊过程中,皮层细胞质中产生具有自噬泡消化特征的细胞器,将部分纤毛结构等逐步消化;休眠包囊中,表膜下微管、皮层纤毛器和纤毛基体间连接、基体托架及其他微管结构不同程度地被吸收、在残剩纤毛基体的中央形成微管形结构聚合体,大核染色质和核仁颗粒变小,核孔增大,并发生染色质附着于核孔内膜的现象;细胞脱包囊期间,皮层细胞骨架、线粒体等经历了在残剩结构基础上的再分化。

By using the calculated results of EET theory, the local valence electron structure elements of residual chemical bonds of Al-Si and Mg-Al alloy melts, that is, the residual bond structure models, were established. From the viewpoint of effect of pressure on melt structure, the essential reason of deviation phenomenon for maximum solution point and eutectic point in thermodynamics equilibrium phase diagram was analysed. Moreover, under pressure condition, the change of thermodynamics equilibrium phase diagram was macroscopic reflection of microstructure change of alloy melt.

运用固体与分子经验电子理论的计算结果分别建立Al-Si、Mg-Al两种合金熔体的剩余化学键的局域价电子结构基本单元即残余键结构模型,从压力对熔体结构作用的层面,分析热力学平衡相图中最大固溶点和共晶点发生偏移的本质原因,并指出压力作用下热力学平衡相图的变化是合金熔体微观结构信息变化的宏观反映。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构;得到了一个在空间上存在位阻作用的配体与金属离子2:1结构的晶体;解析了具有特色的一个配体(LA4)和三个配合物(4、7和10)的晶体结构,其中的配体与金属离子的配位作用显示出细微的差异,表明在同一金属配合物的晶胞中,可以同时存在着多个稳定的构象。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions(0-D chain); complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物,并用X-射线单晶结构分析方法确定了晶体结构,分别为: [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构;配合物2借助水分子形成一维链状结构;配合物3、4、5、6是以H4btc为第一配体、phen为第二配体,通过水热法合成的配合物,其中,Co2+、Ni2+、Cu2+为中心离子;配合物3中的二价钴离子具有相同的配位环境,不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境,在配合物4中,一维链通过H4btc上的羧基形成一个二维层结构;配合物5、6是借助H4btc上的羧基形成的一维链状结构;配合物7、8属于异质同晶结构,它们的分子通过分子间氢键形成三维网状结构,H4btc上的羧基失去2个质子,作为一个二价负离子起到电荷平衡作用。

The main contents are as follows:(1) Configuration design and Experiment research The projectile configuration of penetration weapon is designed according to the technical and tactics target, including the structure design of the projectile , the structure design of the empennage and the structure design of the concrete target. The simulation experiments studying the relation between velocity and concrete intensity and penetration depth have been carried out.

主要内容如下:(1)结构设计和试验研究根据技术指标完成了子母弹侵彻战斗部模拟弹体的尺寸和结构设计,尾翼的尺寸和设计结构、靶体尺寸和结构设计,完成了模拟弹丸混凝土的模拟试验,研究靶体强度和初速度对侵彻深度的影响;通过对结构设计的研究和弹丸侵彻混凝土的试验研究,完善钻地弹设计方案。

The progresive regressing and regressing were made on the fruit production to the parameter of tree framework of gold delicion / M9 / Shandingzi in 6 years old based on the date of yeild investigations and measurment. By the marginal analysis and fuzzy clasification.These parameter were defined that trunk circumafename= 24.93cm, highth of tree=2.5m,average width ot tree=2.5m,size of tree=5.05~5.6m~3, number of length branch / per tree = 101-161.number of middle branch / pe...

本文以金冠/M9/山定子6年生树体为试材,对树体结构参数进行田间测定,用多元回归、逐步回归的方法分析出十种树体结构指标对产量的效益,用边际分析的方法和聚类的方法研究出金冠/M9/山定子产量最高时树体结构参数为:干周=24.93cm,树高=2.5cm,平均冠径=3.01m,冠高=2.5m,树冠体积=5.0~5.6m~3,单株长枝数=101~161个,单株中枝数=122—142个,单株短枝数=601~616个,单株枝量=847~903个,单株叶面积=13.5m~2。

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