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The determination demonstrated that the anionic polymerization of ε-caprolactam under 230℃ leaded to a mesomorphous form of PA6; the EPDM had heterogeneous nucleation effect on the crystallization of dispersed PA6 phase; in situ polymerization could further reduce crystallization enthalpy of PA6 component on the level of reactive compatibilization.

研究表明,230℃下进行阴离子聚合得到的PA6为β-介晶型;EPDM对这种分散在橡胶相中的PA6的结晶具有异相成核作用;原位聚合可在反应增容的基础上使得共混物中PA6的结晶焓进一步降低。

The results show that nuclei make the microcrystalline structure and crystalline rate of PA1010 changed.

通过引入成核剂(Nd2O3)研究PA1010微晶结构的变化,以及对PA1010结晶行为的影响,也讨论了成核剂对结晶-非晶中间相的作用。

Studies on the crystallizing kinetics and micromeasurement explained that it speeded up the nucleation and avoided the aggregation of the crystals thus making the crystal product to be minimized.

结晶动力学的研究和微观检测显示,控制一定的结晶工艺参数可减小二维晶核临界半径,加快晶核生成速度并避免了晶体的团聚作用,从而使产品趋于微晶化。

An coupling apparatus with a chlorination reactor and a melt crystallizer was built,which was used in chlorination of acetic acid and separation of monochloroacetic acidby crystalliza- tion at the same time.

用氯化反应与熔融结晶耦合装置,进行乙酸氯化与产物氯乙酸的结晶分离,避免了 MCA 的深度氯化,从而提高了 MCA 的收率。

To obtain large single crystal of ΔnifE Av1 suitable for X-ray diffraction, a body of studies were performed on the crystallization conditions such as kinds and concentrations of precipitants, pH value of buffer, diffusion method and protein batch.

为获得可供X-射线衍射的ΔnifE Av1的大单晶,对组成蛋白质沉淀剂的各种化合物的种类和浓度、缓冲液的pH值、结晶方法及蛋白样品的批次、浓度等结晶条件进行了大量优化研究。

To obtain large single crystal of △nifE Avl suitable for X-ray diffraction, a body of studies were performed on the crystallization conditions such as kinds and concentrations of precipitants, pH value of buffer, diffusion method and protein batch.

为获得可供X-射线衍射的△nifE Avl的大单晶,对组成蛋白质沉淀剂的各种化合物的种类和浓度、缓冲液的pH值、结晶方法及蛋白样品的批次、浓度等结晶条件进行了大量优化研究。

Synchronous fluorescence showed that the addition of POM could enhance the fluorescence intensity of CV, which was explained in terms of the hindrance of the formation of the nonfluorescent twisted intramolecular charge transfer states of CV by the assembled POM-CV system, and the surfactant CTAB could enhance the luminescence by coordinated assembly.

具有同样Keggin结构的4种稀土杂多阴离子与结晶紫的作用总体一致,稀土元素不同体系的光活性会表现出一定的差异。实验证实,阳离子表面活性剂CTAB的存在会进一步增强体系的发光活性。三者协同作用,形成了更稳定的杂多阴离子-CV-CTAB三元超分子体系,而β-CD的存在对稀土杂多酸盐与结晶紫的超分子体系稳定不利。

In the initial crystallization stage which the growing speed of supersaturation was more than the relaxing speed,the crystallization was situated in kinetic region of phase transformation reaction control.In this region, and the oversaturation of solution was going from up to down.

过饱和生成速度大于消除速度的结晶初期,结晶过程处于相变反应控制的动力学区域,该区域和溶液过饱和度由上升到下降。

The non-isothermal crystallization kinetics of polyoxymethyleneand poly- oxymethylene/co-polyamideat different cooling rates were investigated uisng differential scanning calorimetry.

采用差示扫描量热法研究了聚甲醛和聚甲醛/盐聚酰胺二元共混体系在不同降温速率下的非等温结晶行为,并用 Jeziorny 法、Ozawa 法和莫志深法计算了聚甲醛及其共混物的非等温结晶动力学参数。

The results show that the products morphologies are amorphous, granular, needle-like when the kinetics advances linearly and the products of tetrapod and multipod-like ZnO appear as the kinetics proceeds parabolically.

结果表明:氧化动力学遵守直线规律时,产物的结晶形貌是无定形、颗粒状和单针状;氧化动力学曲线为抛物线规律时,产物的结晶形貌是四针状和多针状。

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