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But, because of the complexity of the dye molecule, there has been short of detailed comprehension in its photocatalytic degradation process. The key problem is difficult to detect the intermediates clearly. In this paper, the photocatalytic degradation of azo dye Congo red in water solution was investigated on UV irradiating TiO2 in the homemade reactor. The optimization conditions were determined and then the rate of decolorization, COD decrease, yield of CO2 and varies pH of aqueous solution during illumination were detected; The varies of the possible intermediates during degradation process were monitored with UV-VIS spectrum and HPLC. The possible mechanism of Congo red photocatalytic degradation is discussed combined with the data of MS.

本文选择有代表性的常见偶氮染料—刚果红作为研究对象,以自制TiO2为催化剂和小功率紫外灯为光源,在自制光反应器上确定了光催化降解的优化条件,并在这个优化条件下测定了降解过程中的脱色率、COD去除率和CO2生成量;利用数显酸度计、紫外可见分光光度计和高效液相色谱仪跟踪测定了降解过程中的可能产物,并结合质谱的数据初步探讨了刚果红的可能降解机制。

Silicalites, predominated by pelitic silicalite, occur in collisional zones and back-arc basins. In the collisional zones, they occur as rock sheet as an important part ofophiolitic mé lange, belonging to ophiolitic mélange type silicalite. In the back-arc or interarc basin, they occur as pelitic silicalite intercalation varying in thickness, characteristic of "silica merl",and belonging to abyssal back-arc basin type or carbonate type silicalite. In the magmatic arc, they occur as intercalation related to volcanic hydrotherm or volcalic exhalation, belonging to volcanic arc type silicalite.

在硅质岩方面:冈底斯构造带侏罗系硅质岩主要属泥质硅质岩,在各个碰撞结合带和弧后盆地中均有产出,主要的产出状态有:①在碰撞结合带中呈岩块产出,构成蛇绿混杂岩的重要组成部分,属蛇绿混杂岩型硅质岩;②在弧后或弧间盆地中呈厚度不等的泥质硅质岩夹层产出,常具"硅灰泥"特征,属弧后深水盆地型硅质岩;③呈夹层状产于弧火山岩系中,属火山热液或火山喷气型硅质岩。

The molecular response in the amoeboid and trophozoite stages of T .vaginalis was elucidated by using a systemic comparative transcriptomics and proteomics approach. We identified 49 differentially expressed proteins by 2-DGE and MALDI-TOF MS.

我们首先建立了阴道鞭毛虫滋养体的标准二维电泳蛋白图谱,再利用比较二维电泳结合质谱的方法找出了49个表现量有差异的蛋白。

The blocking mechanism takes advantage of the fact that a small sequence of this CRISPR locus matches staphylococcal conjugative plasmids, including those that confer antibiotic resistance in MRSA strains.

这一位点的阻断机理是利用了以下事实:CRISPR位点上的一小段序列与金黄葡菌中包括引起抗生素抗性质粒在内的结合质粒中的序列互补。

Two-dimensional electrophoresis (2-DE) was used to study the variation expression of proteins of cucumber cotyledonary nodes induced with PP333. The characteristics and functions of differentially expressed proteins were analyzed with MALDI-TOF-TOF/MS and Protein Data Bank.

应用双向凝胶电泳技术研究PP333处理后黄瓜离体子叶节培养物差异蛋白的表达,结合质谱分析和蛋白质数据库检索,确定所检出差异蛋白质的性质和功能。

Silicalites, predominated by pelitic silicalite, occur in collisional zones and back-arc basins. In the collisional zones, they occur as rock sheet as an important part ofophiolitic mé lange, belonging to ophiolitic mélange type silicalite. In the back-arc or interarc basin, they occur as pelitic silicalite intercalation varying in thickness, characteristic of "silica merl",and belonging to abyssal back-arc basin type or carbonate type silicalite. In the magmatic arc, they occur as intercalation related to volcanic hydrotherm or volcalic exhalation, belonging to volcanic arc type silicalite.

在硅质岩方面:冈底斯构造带侏罗系硅质岩主要属泥质硅质岩,在各个碰撞结合带和弧后盆地中均有产出,主要的产出状态有:①在碰撞结合带中呈岩块产出,构成蛇绿混杂岩的重要组成部分,属蛇绿混杂岩型硅质岩;②在弧后或弧间盆地中呈厚度不等的泥质硅质岩夹层产出,常具&硅灰泥&特征,属弧后深水盆地型硅质岩;③呈夹层状产于弧火山岩系中,属火山热液或火山喷气型硅质岩。

The ESR data of 3f suggest that Cu〓 is in a distorted tetrahedral field, that is to say, Cu〓 is coordinated to three tertiaty nitrogen atoms and one chloride anion.

为了探测模型化合物中Cu〓的配位情况和几何构型,采用相同的方法合成和表征了杂双核化合物3f,ESR信号结合质谱信息表明杂双核化合物3f中,Cu〓是四配位的,即它与一个C1〓和三个叔铵氮原子配位而处于变形的四面体场中。

The ESR parameters of 4g strongly indicate that Cu〓 in complex 4g has a trigonal-bipyramidal environment, that is to say, Cu〓 is coordinated to four tertiaty nitrogen atoms and one chloride anion.

为了探测模型化合物中Cu〓的配位情况和几何构型,采用相同的方法合成和表征了杂双核化合物4g,ESR研究结合质谱信息表明在杂双核化合物4g中,Cu〓是五配位的,即它与一个Cl〓和四个叔铵氮原子配位而处于三角双锥场中。

Moreover, by coupling with the MS,α and β subunits with respective relative molecular masses of 18977 and 20330 can be identified.

结合质谱信息,可鉴别出α和β亚基,它们的相对分子质量分别为18977和20330。

The gene-expressionprofile might help to further understand the molecular basis of tube worm physiology.It will also lay a good foundation for functional studies on the adaptation to extremeenvironments and help to make use of them. MicroRNAsare a class of small noncoding RNA that are 20-22nucleotidesand function as regulators of gene expression.

其中,几丁质结合蛋白最具多样性,不仅几丁质酶水解区和几丁质结合区相互独立,而且几丁质结合区也显示丰富的多样性,由不同的几丁质结合区共组成了23种不同的几丁质结合蛋白;EST测序分析中还发现两个溶菌酶基因带有双功能区,可能具有双重功能;此外,肌红蛋白基因也显示了序列的多样性。

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