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TEM, FTIR, spectrophotometry characterized the morphology, structure and dispersion stability of nanoparticles respectively. The results show that the inorganic nanoparticles in the aqueous solution can redisperse more effectively through ultrasonic irradiation than by conventional stirring, which was the basis for monomers to polymerize on the surface of nanoparticles. By selecting proper nanoparticles and monomers, the long-stable latexes were successfully prepared.

研究了超声辐照下多种纳米粒子(SiO〓、Al〓O〓、TiO〓)在水体系中的分散、粉碎及活化等各种行为,采用TEM、FTIR、分光光度法等对纳米粒子的形态、结构、分散稳定性进行了表征,证明超声辐照比常规搅拌更有效地实现无机纳米粒子在液相中的分散,为单体在纳米粒子表面的聚合创造了条件。

Recently, Shelnutt and co-workers obtained discrete porphyrin nanosheets reprecipitated from their solutions;[3] Sathish and co-workers constructed hexagonal C60 nanosheets using a liquid–liquid interfacial precipitation method;[4] the groups of Yao[5] and Hu[6] prepared singlecrystalline nanosheets of polycyclic aromatics using a surfactant- assisted reprecipitation and a physical vapor transporting method, respectively; and Zhang and co-workers suggested that molecules with intramolecular charge-transfer dipole moments could be grown into quasi-2D nanostructures.

近年来,Shelnutt及其同事由他们的溶液再沉淀获得了离散的卟啉纳米片[3]; Sathish和他的同事用液-液界面沉淀法构建了六边形的C60纳米片[4]; Yao[5]和Hu[6]分别用表面活性剂辅助的再沉淀和物理气相输运法制备了多环芳烃的单晶纳米片;而Zhang和他的同事提出,具有分子内电荷转移偶极矩的分子可以生长成准二维的纳米结构[7]。

Many nanotwins were formed in this triangular region. HREM observations showed that nanotwinning dislocations were nucleated at noncoherent twin boundaries with the local stress concentration, and the nucleation is related to the dislocation dissociations at the boundary ledges. The proceeding of these nanotwins is the homogenous shears of 1/6 [11〓] twinning dislocations, which is that the trailing 1/6 [112] twinning dislocations repel the leading twinning dislocations to proceed in the (111) planes. Therefore, twinning dislocations at the twin tip appear to be on one side of twin, forming a noncoherent twin boundary with a semilenticular shape.

在此三角区域内发现许多纳米孪晶的存在,通过高分辨电镜手段观察到纳米孪晶中的孪生位错是在具有原位应力集中的非共格入射孪晶界上形核的,纳米孪晶的形核与界面的台阶位错及其位错分解反应有关,纳米孪晶的行进是1/6[11〓]孪生位错均匀切变机制,即每一个(111)孪生面上对应一个孪生位错,其中拖尾的1/6[11〓]孪生位错将会推动领先的孪生位错行进,于是在形变孪晶头部位置的孪生位错排列常常出现在形变孪晶的一侧界面,形成一个半透镜状的非共格孪晶界。

CuS thin film composed of nano/micro tubes with diameters in the range of 150 to 200 nm and lengths up to several microns and CuO thin film composed of nano/micro crystals with sizes ranging from 150 to 250 nm have been successfully prepared through a gas-solid sulfurization and oxidation reaction using well-aligned CuCl nanorod films as precursor.

在本文中,以由氯化亚铜纳米棒组成的薄膜为前驱体,分别通过气-固相的硫化和氧化反应获得了由直径150到200纳米,长度达数微米的硫化铜管组成的薄膜和粒径为150到200纳米的氧化铜纳米/微米晶所组成的薄膜。

Polyaniline/Sulphosalicylic Acid nanotubes and nanofibers which are formed by doping 5-sulphosalicylic acid into aniline, neodymium oxide( Nd_2O_3) and Polyaniline/ Nd_2O_3 composite nanomaterial are successfully synthesized by a method of template.

利用模板法合成了5-磺基水杨酸与苯胺掺杂形成的聚苯胺/磺基水杨酸纳米纤维及纳米管,以及氧化钕(Nd_2O_3)纳米棒和PAN/Nd_2O_3复合纳米材料。

Contact configuration under unlubricated condition were investigated, with the effect of the nano-La_2O_3 content on the friction and wear behaviors of the composite coatings to be emphasized. The worn surfaces of the composite coatings were analyzed using a scanning electron microscope and compared with t...

结果表明,在干摩擦条件下,随着La2O3纳米颗粒含量的增加,纳米复合镀层的摩擦系数降低,耐磨性能提高;La2O3质量分数为3.1%的纳米复合镀层的摩擦系数最低,耐磨性能最佳;纯Ni镀层呈现严重的粘着磨损特征,而纳米复合镀层主要呈现轻微磨粒磨损特征。

Especially, the difference of the nearest-neighbor hopping integral is due to the effect of the curvature of the carbon nanotubes. So, in fact there is a very narrow energy gap near the Fermi energy of unsquashed metallic zigzag carbon nanotubes, and, a slighter deformation is required to open a considerable energy gap in metallic zigzag carbon nanotubes than that in armchair nanotubes.

特别是,最近邻格点之间的跃迁积分的变化与碳纳米管的曲率紧密相关,因此实际上,理想金属型 zigzag 碳纳米管本身具有微小能隙,而施加比 armchair 碳纳米管小的多的压缩量,就可以使金属型 zigzag 碳纳米管在费米能处打开相当的能隙。

The particular preparation procedure is as follows: preparing a carbon nanotube with carboxyl by acidulating the carbon nanotube; Preparing the carboxylic carbon nanotube/nylon 66 composite material by polymerizing the carboxylic carbon nanotube and the raw material (such as polybasic acid and polybasic amine) which is used for preparing the nylon 66 through in situ polymerization.

具体步骤为:通过对碳纳米管进行酸化,制备携带羧基的碳纳米管。通过原位聚合法将羧基化碳纳米管与制备尼龙66的原料进行聚合,制备羧基化碳纳米管/尼龙66复合材料。

Nano-powder (nano-Ag 35%, nano-TiO2 40%, kaolin 25%) 30%, polyethylene 56% and cross-link reagents 14% were immingled in uniformity for 1 h, then extruded to nano-granule after cooling by 1-2 minutes.

纳米包装材料是以纳米粉体(纳米Ag 35%、高岭土 25%、纳米TiO2 40%)、塑料、腊、聚乙烯等制备而成用于水果蔬菜的包装,可显著提高水果在贮藏过程中的品质。

In particular, nanowires would play an important role as both interconnects and active components in fabricating nanoscale device.

特别是纳米线,它即可以连接纳米器件又可以充当纳米器件中的活性部件,所以在纳米器件制造领域占据着极其重要的位置。

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