纳米

In this paper fulgurite technique was firstly used to synthesize one-dimensional nanostructure such as nanorods, nanowires and nanobelts via the precursors. It is found that nanoparticles can grow by self-organization.

首次将熔盐技术应用于一维纳米材料的合成，以纳米颗粒前驱体为原料制备了一维纳米结构纳米棒、纳米线和纳米带；并发现了一维纳米结构生长的新现象，即纳米颗粒固相自生长。

A device and method for preparing compound nano fiber endless tow, which contains feeding material liquid to pair of electric spinning nozzle on frame, each nozzle respectively applied with high dc voltage with opposite polarity, each pair of nozzle jetting out nano fiber with opposite electric charge, said nano fiber attracting and colliding each other to form compound nano fiber, then forming nano fiber endless tow after drawing and stretching, the first opposite set pair of electric spinning nozzle jetted compound nano fiber endless tow is stretched down and used as acceptor which covered by the nano fiber jetted by second pair of nozzle an d forming two layers of compound nano fiber endless tow after drawing and stretching, in turn to get multilayer compound nano fiber endless tow after drawing and stretching by godet roller.

复合纳米纤维长丝束制备装置及其制备方法是一种简单、高效电纺制备纳米纤维长丝束的方法，其步骤为将料液输送给支架(3)上的电纺喷头对(1)；喷口相向的电纺喷头对(1)的每个喷头分别施加相反极性的直流高电压；每对相向喷口喷出分别带相反电荷的纳米纤维，并在空中相互吸引、碰撞形成复合纳米纤维，经牵引、拉伸后形成复合纳米纤维长丝束；第一对相向放置的电纺喷头纺丝形成的复合纳米纤维长丝束向下拉伸，并作为接受体与第二对电纺喷头喷出的分别带相反电荷并相互吸引的纳米纤维在空中相遇，被第二对电纺喷头喷出的纳米纤维包裹，经牵引、拉伸后形成两层复合纳米纤维长丝束；依次类推，最后经导丝辊对(2)牵引、拉伸后得到多层复合纳米纤维长丝束。

Further oxidation treatment or reduction treatment of molybdenum dioxide nanowire arrays resulted in molybdenum trioxide nanowire arrays and molybdenum nanowire arrays. We fabricated WO3 nanowire arrays successfully by further oxidizing W18O49 nanowire arrays. Based on the vertical aligned zinc oxide nanowire arrays, we prepared the aligned zinc oxide/silicon core-shell nanowire arrays, zinc oxide nanowire-zinc silicate nanotube heterojunction arrays and zinc silicate nanotube arrays by adjusting the size of the templates as well as the annealing temperature.

我们通过氧化和还原处理二氧化钼纳米线阵列，分别合成了三氧化钼纳米线阵列和单质钼纳米线阵列；通过氧化W18O49纳米线阵列合成了三氧化钨纳米线阵列；利用氧化锌纳米线阵列作为模板，通过调节氧化锌纳米线模板的尺寸和退火温度，合成了氧化锌－硅同轴纳米线阵列、氧化锌纳米线－硅酸锌纳米管异质结阵列和硅酸锌纳米管阵列。

Nanomaterials have many new characterizes which different from the normal materials for their small size, big surface area ratio and quanta dimension domino effect, for examples, the metal with good conductor will be turned into nonmetal when the size is reduced tonanometer levels; the resistance of originally nonconductor will be descended greatly when its size is reduced several nanometers or so, and loss the nonconductor property; the general solid is steady under certain conditions, while under nanometer conditions, the capabilities will be effected greatly by the granule sizes, the newness characteristics made nanomaterials have great appliance foreground on catalyze, optics, and industry produce and so on, therefore the nanomaterials have been the hotspot for materials science, chemistry science and so on.

纳米材料由于尺寸小、比表面积大和量子尺寸效应使它具有不同于常规固体材料的新的特征，如原来是良导体的金属，当尺寸减小到纳米量级时就变成非金属型；原来是绝缘体的物质，当尺寸减小到几纳米或几十纳米时电阻大大下降，失去了绝缘体特性；常规固体在一定条件下物理性能是稳定的，在纳米状态下，颗粒尺寸对性能产生强烈的影响等等，这些新奇的特点使得纳米材料在催化、光学、工业生产等各个方面都有着广阔的应用前景，因此，纳米材料目前已经成为材料科学、物理学及化学等学科的前沿热点。1990年7月在美国巴尔基摩召开了国际第一届纳米科学技术会议，正式把纳米材料科学作为材料科学的一个新的分支公布于世。

Nanoparticle of an appropriate proportion were homogeneously dispersed in the PI matrix, and the interfacial adhesion between the matrix and the nanoparticle was hence strong owing to the high specific surface area and reactivity of the nanoparticle. Subsequently, the molecular chains of PI attained unchanged or even increased interaction at a proper mass fraction of the nanometer particle, which contributed to improve the wear-resistance of the nanocomposites.

采用PI的原位聚合填充方法，利用聚酰亚胺与无机纳米表面较强的相互作用（如静电作用、较强的范德华力、氢键甚至化学键的形成），用非水悬浮工艺制备了无机纳米/聚酰亚胺纳米复合材料，率先用大型分析仪器全面地表征了复合材料的结构，采用原位聚合填充法制备的聚酰亚胺复合材料中，无机纳米分散状态良好；无机纳米氧化物/聚酰亚胺复合材料的结构表征显示出PI有机相和SiO〓无机相之间形成了键联型复合体系，两相相互影响；在复合体系中，单相本体的结晶结构并未发生改变；在摩擦过程中纳米氧化物没有发生价态的转变；无机纳米氧化物的加入，提高了聚酰亚胺的耐热等级；适量纳米氧化物并不影响复合材料的机械性能， 2。

In chapter three, various theories and experience on the dispersion of nano-powders proposed by former researchers were generalized and reviewed. Technical standards and experimental process for determining technological parameters were suggested for the dispersion of nano-scaled metal oxides in aqueous medium according to their surface wettability, surface charge, the dependence of surface charge on pH and the compatibility of surfactants with pH and pH adjusting agents. Based on these suggested standards and experimental method, highly stable and dispersive aqueous suspensoid of nm-ZnO, nm-TiO〓, nm-Co〓O〓 and nm-MnO powders were prepared successfully and surface modification on these nano-powders was also achieved.

本文第三章通过大量的文献调研，归纳总结了前人在纳米粒子分散技术方面的理论和经验，并在此基础上根据纳米氧化物粉体的表面润湿性、表面电性及其与分散介质pH值的关系、表面活性剂及其与pH调节剂的配伍关系设计了纳米氧化物水分散体系的工艺规范以及确定工艺参数的通用实验步骤，成功地制备了纳米氧化锌、纳米二氧化钛、纳米氧化钴和纳米氧化锰的高稳定分散悬浮液并实现了干粉体的表面改性，为纳米材料在氧化锌压敏电阻中的应用创造了第二个前提条件。

In this thesis, three major achievements were made in theoretical study: conditions and rules for preparing nano-powders by chemical precipitation are analyzed from the point of view of thermodynamics and kinetics, the principle, standards and experimental method for the aqueous dispersion of nano-scaled metal oxide powders were proposed and verified, mathematical model of nano-filming addition of dopants by chemical coprecipitation was established. In experimental research, nm-ZnO, nm-Bi〓O〓, nm-Co〓O〓 and nm-MnO powder with spherical shape, narrow particle size distribution and small particle size were prepared successfully, highly stable and dispersive aqueous suspensoid of nm-ZnO, nm-TiO〓, nm-Co〓O〓 and nm-MnO powder were prepared successfully and surface modification on these nano-powders was also achieved, 0-3 nanocomposite ZnO varistors with nm-ZnO, nm-TiO〓and nm-MnO respectively were prepared successfully by conventional mechanical attrition, and exhibited much better electrical properties than those of conventional varistors.

综上所述，本文在理论研究方面取得了三项成果：（1）从热力学和动力学角度推导并分析了液相化学沉淀法制备纳米粉体的反应条件和规律，（2）提出了纳米氧化物的水分散体系的设计原理、规范和通用实验步骤，（3）提出了共沉淀的数学模型和计算方法；在实验方面所取得的成果有：（1）成功制备了粒度小、分布窄、形貌对称的纳米氧化锌、纳米氧化铋、纳米氧化钴和纳米氧化亚锰，（2）成功地制备了纳米氧化锌、纳米二氧化钛、纳米氧化钴和纳米氧化锰的高稳定分散悬浮液并实现了干粉体的表面改性，（3）成功地进行了纳米氧化锌、纳米二氧化钛和纳米氧化锰对压敏电阻的0—3复合掺杂实验，试样性能远优于常规压敏电阻，为实现压敏电阻的高能高压化提供了新的方法和思路。

We prepared the ordered porous alumina membrane by a two-step anodization method in oxalic or sulfuric acids, which is a self-ordered hexagonal array of cells with an adjustable pore diameter of 20-150nm and a different pore structures (i.e. Y-branched, dendriform, toothed and torous ones). Furthermore, the template-electrodeposition, vapor-catalytic growth, and controlled chemical etching were developed for well-aligned carbon nanotubes and oxide nanopillars with adjustable diameter, Al2O3-AlN one-dimensional heterojunction, Y-junction and dendriform metal nanowires, as well as Y-junction, and torous carbon nanotubes. The resultant one-dimensional junctions were characterized by XRD, SEM, TEM,HRTEM, and STM, and the field emission of the well-aligned carbon nanotubes and the luminescence of ZnO nanopillar array have also been mearsured.

完善和发展了阳极腐蚀法制备多孔氧化铝膜的方法，制备出了孔径在20-150nm之间可调和具有不同孔结构（如Y形、树枝状、锯齿状）的系列多孔氧化铝模板，在此基础上，利用电化学沉积、气相催化生长和化学控制腐蚀等方法，成功地生长出具有可调直径的碳纳米管和氧化物纳米柱有序阵列、Al2O3-AlN异质结纳米线、Y形和树枝状的金属纳米线以及Y形、藕节形和锯齿形的碳纳米管等多种一维结纳米材料及其阵列体系，探索了基于模板孔壁内沿生长一维结纳米材料的机制，较系统的研究了碳纳米管阵列的场发射性能和氧化锌纳米柱的发光性能，为低维纳米材料器件化提供了实验基础。

The mian works are as follows:(1)By coprecipitation technique and coprecipitation- gel technique the nano zirconia powder was produced, factors affecting the properties of nano zirconia powder such as pH and the content of stabilizator are analyzed;(2)By the new pressless sintering process, the nano zirconia ceramic was produced, factors which can affecting the properties of nano zirconia sinter body such as moulding press and the sinter temperature are analyzed;(3)By the microtherm pressless sintering process, the nano copper added functional zirconia ceramic composite was produced, microscopic dimensionality and electric properties of such sinter body and the factors affecting such sinter body are analyzed;(4)By the self-invented "external albumen coating" technique the zirconia powder was successfully coated by carbon in the corresponding sinter body, which can help solve the traditional aggregation problem to some degree;(5)Based on analyze the characteristics in the nano powder sinter process, the "three-ball sinter model" was proposed, for the relationship between the relative density and porosity of sinter body, by mathematical fitting, such model was successfully verified.

本研究比较系统地研究了纳米氧化锆陶瓷的合成与成型机理，特别是讨论了纳米氧化锆陶瓷的稳定性，为防止纳米颗粒在外场作用下的团聚和长大提供了理论基础和实验数据，具体工作有以下几方面：(1)采用共沉淀法和共沉淀-凝胶法制备了纳米氧化锆粉体，并分析了pH值和稳定剂含量对粉体性能的影响；(2)采用新型无压烧结工艺制备了纳米氧化锆陶瓷，并分析了成型压力和烧结温度对烧结体性能的影响；(3)采用低温无压烧结工艺制备出添加纳米铜的功能性纳米氧化锆复合陶瓷，并分析了烧结体的微观尺度和电学性能的变化以及影响因素；(4)通过自创的&鸡蛋清外敷法&在真空镀膜台上对纳米氧化锆粉体进行包敷碳颗粒的表面处理，并采用真空烧结工艺制得相应烧结体，初步开始解决陶瓷烧结过程中团聚长大这一传统难题；(5)通过分析纳米颗粒在制备烧结体过程中的实际特点，提出了&三球烧结数学模型&，通过引入坯体相对密度和孔隙率的相对关系分析并通过自行编写的数学拟合软件，验证了这一数学模型。

The method is as follows that the two ends of a nanometer are fixed on two pivots and an axial micro-pulling force T is applied on the nanometer; an electrode is arranged on the middle part of the side of the nanometer and an alternate voltage is applied on the electrode to motivate the nanometer to generate resonance, and therefore, the natural frequency f of the nanometer is measured and acquired; according to the material characteristics and the geometry characteristics of the nanometer as well as the boundary condition of the nanometer material, the relation between the natural frequency and the axial pulling force of the nanometer, namely the f-t curves of the nanometer, can be calculated by a vibration equation; according to the measured natural frequency f, the size of the micro-pulling force T can be acquired.

该方法将一根纳米材料的两端固定在两个支点上，给纳米材料施加一个轴向的微小拉力T；在纳米材料的侧面，位于该纳米材料的中部放置一个电极，在电极上施加一个交变的电压激励纳米材料使其发生共振，测得纳米材料的固有频率f；根据纳米材料的材料特性和几何特征以及纳米材料的边界条件，由振动方程计算出该纳米材料的固有频率与所受的轴向拉力的关系，即纳米材料的f-T曲线；根据上述测得的固有频率f，得到微小拉力T的大小。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。