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The IR result shows that conjugative effect is the reason for the red shift of stretching vibration frequency for carbonyl, meanwhile hydrogen bonds lead to the red shift of stretching vibration frequency for hydroxy groups.

红外振动光谱结果发现,共轭效应导致了羰基伸缩振动频率红移,氢键的存在导致了羟基伸缩振动频率红移

Hexaazatriphenylene derivatives were designed and synthesized by introducing methoxyphenyl or fluorenyl peripheral aryl substituents,and the effect of these aromatic substituents on their optical properties and bandgap were characterized by means of UV-Vis absorption spectroscopy,fluorescence spectroscopy and electrochemical cyclic voltammogram.

结果发现,芴和甲氧基苯芳香基团的引入使三亚吡嗪化合物的接收电子能力显著提高,LUMO能级从化合物1a的-3.50 eV降低到化合物1b的-3.68 eV和化合物1c的-3.66 eV,并伴随着吸收光谱和荧光光谱的显著红移,最大吸收和发射峰从化合物1a的413和432 nm红移到化合物1b的460和543 nm以及化合物1c的479和552 nm。

The absorption bands observed for Pb-pheophytin a at 462nm and 673nm , while for Pb-pheophytin b at 480nm and 662nm . Compared with pheophytin a and pheophytin b, all these bands red shifted more or less. Among the reported metallochlorophylls, the degree of red shift of Pb-pheophytin in Soret band was the largest by 54nm and 44nm for Pb-pheophytin a and Pb-pheophytin b, respectively.

实验表明:对铅叶绿素a和b系列来说,它们在Soret带、Q带的特征吸收峰分别在462nm,673nm和480nm,662nm;与脱镁叶绿素a,b相比,铅叶绿素a,b在Soret带和Q带吸收峰均有不同程度的红移;与现已报道的金属叶绿素相比,铅叶绿素a,b在Soret带的红移程度最大,分别为54和44nm;铅叶绿素不具有荧光活性,并能猝灭脱镁叶绿素的荧光。

Compared with the PL-CDM model, the RSI-CDM model can raise the mass abundance of dark haloes for small mass haloes at lower redshifts, but it is not apparent on scales of massive mass haloes.

与PL-CDM相比,RSI-CDM在低红移处小质量暗晕的质量丰度较大,但在大结构质量晕中两者差别不明显,而且这个差异随著红移降低而增大。

UV spectra of the n -octanol gels formed by the three gelators indicate that the K bands of benzene rings are red shifted. It reveals that the π-π stack is one of the driving forces for the self-assembly of the gelators. The extent of red shifts of K bands depends on the amount of methyl groups in benzene rings which is in accord with the stabilities of the gels formed by such three gelators.

紫外吸收光谱表明,对比其溶液态,三种衍生物聚集体苯环的K带发生红移,表明π-π堆积作用是亚苄基山梨醇衍生物凝胶剂自组装的驱动力之一;红移的幅度随苯环上甲基数量的增加而增加,这与三种衍生物形成的分子凝胶的热稳定性相吻合。

Slipher knew that when an object's light was redshifted, it was moving away from Earth, and that the object's speed was proportional to the redshift.

Slipher 知道当一个物体发出的光表现为红移时,说明物体在远离地球,并且远离速度和红移成正比。

Fluorescence emission spectra and UV absorb spectra analysis have been undertaken to test the influence of solvent polarity on the lowest excited singlet state of the tertiary amines. The absorption maxima were red-shafted slightly, and the emission maxima were red-shafted strongly, which showed all of the three compounds were found to be essentiallyππ* in character, which makes for the formation of triplet-exciplex state and the subsequent reactions,?known as photo-reduction and hydrogen-abstraction.

本文借助光谱检测的手段测试了新合成的增感剂的光物理化学性能,利用荧光发射光谱和紫外吸收光谱测试了溶剂极性对叔胺的最低激发单重态的影响,实验结果表明叔胺的紫外最大吸收波长随溶剂极性的增强产生轻微的红移,荧光最大发射波长随溶剂极性的增强产生明显的红移,表明三种叔胺的最低激发单重态具有ππ*跃迁的特性,这对于激态复合物的生成以及其后的光致还原反应和提氢反应的发生都非常有利。

This means in redshift space there are preferred redshifts where galaxies are more dense due to a slower expansion rate at those epochs...

这意味着,在红移空间中,一些占优红移位置上的较稠密星系应该归因于那些宇宙膨胀速率较缓慢的时期。。。

I also found that broad Balmer emission lines probably have gravtitational redshifts. I tried to explain in the context of binry black hole model the quasi-periodic optical darkening and brightening, the H_βdouble peaked profile, the gravitational redshift of H_βemission line,and the wiggling of jet.

我注意到宽发射线H_β有双峰结构,并对双峰结构尝试给出了合理的解释,我还注意到巴耳末宽发射线可能存在引力红移,并尝试在双黑洞模型下来解释准周期性光学变暗和爆发、H_β双峰结构、引力红移和喷流摆动。

The results show that the as-synthesized chalcone-containing copolymers are a kind of thermosensitive polymer with a lower critic solution temperature and the LCST of the copolymer decreases with the increase of the chalcone content in the copolymer. With the increase of the solvent polarity, both the maximum absorption wavelength and the fluorescence emitting wavelength of the chalcone-containing copolymers redshifts, and the intensity of fluorescence first increases, then decreases, which exhibits solvent polarity sensitive fluorescence properties.

结果表明,侧链查尔酮共聚物是一类具有低临界溶解温度的温敏性聚合物,其LCST温度随着共聚物中查尔酮含量的增加而降低;随着溶剂极性的增加,侧链查尔酮共聚物的紫外-可见最大吸收波长红移,其荧光发光波长红移并且发光强度先增强后降低,具有溶剂极性敏感的荧光特性;同时对比侧链查尔酮共聚物水溶液低温和高温下的荧光,发现低温下几乎无荧光,高温下其荧光得到明显增强,其荧光具有可逆的温度&开/关&特性。

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