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1,6-Dimethyl adipate with selectivity of 100% was synthesized by batch and continuous esterification process using adipic acid and methanol as raw materials,DNW-I strong-acid cation exchange resin as catalyst.

摘 要:以DNW-I型强酸型正离子交换树脂为催化剂,己二酸和甲醇为原料,经间歇酯化和连续酯化反应后通过精馏可制备选择性为100%的1,6-己二酸二甲酯。

The axial profile of temperature and concentration in the column is calculated.

得到了催化精馏塔内的温度及液相组成分布。

But the mixture of these two components can not be separated by conventional distillation, because they form azeotrope at atmospheric pressure.

但两者在常压下形成共沸物,应用普通精馏方法难以对其进行有效的分离。

1 M packed with Mellapak SM-250 under vacuum in batch process to obtain fractions rich in such components as pinenes, camphene, limonene as well as p-cymene, terpenol s, respectively.

松轻油先用碱液进行预处理,再用工业SM-250型孔板波纹填料塔(300mm、高10.1m),以真空间歇操作方式进行一次性精馏分离,分别得到富含蒎烯、莰烯、苧烯及对-伞花烃、萜烯醇等的馏分。

The non-equilibrium stage model is used to simulate catalyticdistillation process for cumene synthesis using low concentration propylene and benzene.

对苯与低浓度丙烯合成异丙苯的催化精馏过程建立非平衡级模型。

It is especially suitable for rectification towers under vacuum to treat thermosensitive, decomposable, polymerizable or cokable systems.

特别适用于真空精馏塔,处理热敏性,易分解,易聚合,易结碳的物料。

More interestingly, the phase transfer is found to be size-dependent which might help us distil polydisperse nanoparticles.

更有趣的是,相转移具有尺寸效应,利用尺寸效应可能会实现对某些多分散金纳米粒子进行尺寸精馏。

The results show that the distillation effenciency is effective.

试验结果表明精馏效果是很有效的。

A side stream is recycled to the external feed stream of the column through an equilibrator as an internal feed stream.

塔的一侧线流股经过一个平衡反应器完成平衡反应后,作为内部进料流股与原外部进料混合后重新进入精馏塔内进行分离操作。

Based on these, an improving μ-synthesis is presented, with which the high-purity distillation is designed well. 2. The robust performance problem of MIMO plant is explained with the plant direction angle, which shows that the robust performance varies with different input uncertainties and the μ-synthesis should be applied correctly according to the uncertainty structure. 3. Condition number and bandwidth are the important items for robust performance design in MIMO system. The H〓 two-block problems can not deal with the robust performance design of MIMO system because of the condition number cancellation. A general μ-synthesis procedure for MIMO system with uncertainties is presented. 4. For the SISO system, the object function in robust performance is amplified by at most 〓 than that of H〓 two-block problems in value: So the robust performance of SISO system can be done with the H〓 two-block problems to avoid the complicated μ-synthesis procedure. 5. All the conclusions and methods presented in this paper are demonstrated by some typical design examples.

从而形成一种改进的μ综合方去,并对精馏塔病态对象进行了鲁棒性能设计,得到令人满意的结果;(2)利用对象的方向角解释了MIMO对象鲁棒性能设计出现问题的原因,并提出不同输入摄动形式下系统的鲁棒性能问题也并不相同,因此利用μ综合处理鲁棒性能设计时,应根据不同的摄动情况采用不同的结构进行设计:(3)条件数问题和带宽问题是MIMO系统鲁棒性能设计的两个主要问题,指出由于条件数对消的存在使得一般H〓两块问题无法处理MIMO系统的鲁棒性能设计,而μ综合方法则是处理MIMO系统鲁棒性能设计的有效方法,并给出了其处理MIMO系统鲁棒性能设计的一般性方法;(4)提出对于SISO系统H〓两块问题(S/T问题、S/KS问题)的设计指标函数与鲁棒性能设计的μ指标函数在数值上最大差〓倍,因此对于一般SISO系统的鲁棒性能设计可以简单地用一般的H〓的两块问题处理,而避免μ综合设计的复杂过程;(5)本文中提出的结论和算法都利用H〓/μ发展中的典型例子:Doyle-Stein问题,Safonov的战斗机模型,精馏塔对象等进行了设计验证。

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