精馏的

Batch extractive distillation is used to separate azeotrope or the mixture of which the relative volatility is close to 1.0. For it has both advantages of batch distillation and extractive distillation, batch extractive distillation is becoming increasingly important to the production of small scale and high value products like fine chemicals and pharmaceuticals.

间歇萃取精馏是分离共沸物或近沸物的一种方法，由于它结合了间歇和萃取的优点，特别适用于化工、制药、溶剂回收、天然产物提取等产量小，品种多的行业，因此间歇萃取精馏近年来已成为非常活跃的研究和开发领域。

Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍，也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤，并将这些参数用于萃取精馏萃取剂的选择与优化；也通过线性溶剂化能关系式建立无限稀释活度系数预测模型，取得了一定的预测精度；将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究，通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂，测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据，并进行关联计算；以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究，取得大量塔内数据；通过选用合适的热力学模型，采用ASPEN中RadFrac模块对分离过程进行模拟研究，通过实验与模拟相结合，建立了C5分离的新工艺，为将来的工业化打下了坚实的基础。

The experimental setup is designed to measure the change of dynamic holdup during the course of non-reflux period and the calculation value is consistent with the experimental results, which indicates that the downflow velocity of dynamic holdup becomes smaller with the decrease of dynamic holdup in the column during the course of non-reflux period.

本文设计了测定无回流过程中动持液量变化的实验装置，在与动态液相交换的全回流间歇精馏串联实验相同的条件下测定了无回流阶段的动持液量变化，模型计算值与实验值比较吻合，结果表明在无回流过程中随着精馏塔中动持液量越来越少，动持液向下流动速度也越来越小。

The solvent selection and batch extractive distillation with a middle vessel were studied by theoretical analysis and experiment.

本文通过理论分析和实验相结合的方法，主要研究了萃取精馏溶剂的选择以及带有中间储罐塔的间歇萃取精馏过程的操作性能和设计计算问题。

Automatic differentiation and implicit function differentiation rule were used to calculate the precise absolute and relative sensitivity coefficients, with no truncation error introduced.

提出一种基于自动微分和隐函数求导法则的精馏塔优化计算灵敏度分析方法，可以求出精确的、无截断误差的灵敏度系数，以反映精馏塔模型中各种不确定因素变化所引起的改变和影响。

So the process is offered using isomerization with separation. 1,2,4-trimethylbenzen is converted to 1,3,5-trimethylbenzen by isomerization. By means of precise distillation mesitylene is separated from products of isomerization as much as possible with high purity. 1,2,4-trimethylbenzen is recycled, at last , more mesitylene is produced and the productive cost is much lower .

为此，本文将催化异构化技术和精密精馏技术结合起来，通过异构化将偏三甲苯转化为均三甲苯，通过精密精馏技术将产物中均三甲苯最大限度的分离出来，得到很高的产品纯度，同时偏三甲苯循环使用，提高了均三甲苯的产量，降低了均三甲苯的生产成本。

In allusion to the complexity in developing a strict dynamic mechanism model of distillation column and the trouble in applying the mechanism model, an optimal BP algorithm combined with conjugate gradient and self adaptive variable step is proposed, and a predicting model of distillation column is built.

针对建立精馏塔严格动态机理模型的复杂性以及机理模型应用的诸多不便，提出了一种综合共轭梯度和自适应变步长的优化BP算法，并利用该优化BP算法建立了精馏塔的预测模型。

ZG rotating bed consists of mono-or multi-rotors.Gas and liquid flow zigzag through the rotors countercurrently and carry out mass transfer.In ZG rotating bed,gas and liquid contact intensively,and the mass transfer rate can be increased greatly.It is a breakthrough for traditional plate and packed columns.ZGrotating bed of 1.5 meter high can achieve the separation ability which traditional plate of packed columns of 15 meters high can achieve.

该设备由一个或多个高速旋转的转子组成，气液以逆向折流方式流经转子，进行接触传质，1.5米高的ZG系列超重力精馏机相当于15米高的常用精馏塔，是对传统的板式塔、填料塔的重大突破，由国家级专家组鉴定，产品达到国际先进水平（专利号：ZL011343214）。

To solve the practical problem where the temperature field distribution is low at the lower part of furnace chamber and high at the upper part and the temperature difference is untolerable , which is reflected by the thermocouples at site, the authors take the methods of multipoint test and computer hologram simulation to research into the fields in the furnace chamber of the zinc fractionating tower at Shaoguan Smelter CNNC.

针对锌精馏炉炉膛各检测点反映出的其上部温度偏高，下部温度偏低，上下温度偏差过大的实际问题，采用现场多点温度测试，结合炉膛内流场、浓度场、释热场和温度场数值仿真的方法对韶关冶炼厂二精馏系统进行研究；利用仿真结果中的流场扣浓度场数据，统计出实测中无法得到的各次空气和煤气在南1号至南4号各喷口的流量。

In the present dissertation, the principles and application of the reaction rectification techology in the syntheses of benzyl chloride, chloroacetic acid, monochloroacetone were approached.

本论文采用反应精馏技术氯化苄的合成、氯乙酸的合成进行了认真的研究，并且对一氯丙酮、氯苄系列产品进行了反应精馏研究，都得到了理想的结果。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。