精馏

Simulation and optimization of multicompnent distillation with the nonequilibrium stage model:METSH equations were introduced in this paper.

前 言关于精馏塔模型的研究至今已经有 3 0余年了，经典的平衡级模型和非平衡级模型也都已经有了很多种的计算方法。

The distillation column with a single photochlorination reactor was built in this paper, which is used in the laboratory study. In light initiation, the semi-continuous operation was applied to study the influence of the chlorine flow, the reflux and the height of the packing on photochlorination of acetic acid. Crude MCA with a purity of 90% or more was attained and the feasibility of this technology was proved.

本文建立了适合实验室研究的背包式光氯化反应精馏耦合装置，采用半连续操作的方法，在光引发条件下，考察了氯气流量、回流量和填料高度对乙酸光氯化反应的影响，得到了含量达90％以上的氯乙酸粗品，证实了工艺的可行性。

In the distillation column with a single reactor, the outer loop reactor is designed and applied. The reaction dynamics datas of photochlorination of acetic acid in the reactor were tested. According to parallel-consecutive reaction dynamics model, the parameters were fitted and the model result tallys experiment result well.

在背包式反应精馏装置中，采用了外环流反应器，实验测定了该反应器中乙酸光氯化的反应动力学数据，采用平行-连串反应动力学模型进行了参数拟合，所得模型计算值和和实验值吻合较好。

More interestingly, the phase transfer is found to be size-dependent, which might help us distill polydisperse nanoparticles.

更有趣的是，相转移具有尺寸效应，利用尺寸效应可能会实现对某些多分散金纳米粒子进行尺寸精馏。

The main objective of this research project is to modify the Methyl-Acetylene/propadiene selective hydrogenation reaction system of the No.3 Naphtha Cracker in CPC. The original gas phase reaction system was redesigned to a liquid phase reaction so that higher propylene selectivity was achieved and lower rates of propane and green oil were produced. To recover effectively the higher production of valuable propylene from the reaction system, the following fractionator was also redesigned.

本研究之目的在於修改中油公司三轻工场老旧的甲基乙炔／丙二烯选择性氢化气相反应系统，使成为液相反应系统，藉由液相反应的优异性，提高由MAPD氢化得到丙烯之选择率，同时降低丙烷及绿油产率，以增加丙烯产率，另亦修改丙烯精馏系统，以提升蒸馏塔提纯之效率。

The method comprises heating up the lactic acid solution to gasify at 150-200 degree C, mixing the obtained mixed vapour of lactic acid and water with the carrier gas, entering into gas-solid catalytic reactor to get the reaction product gas by the action of a modified Y zeolite molecular sieve catalytic agent and dewatering after heating up the mixed gas to 200-450 degree C, obtaining the propenoic acid solution through gas-liquid dissociation after cooling the reaction product gas, obtaining coarse propenoic acid products form the propenoic acid solution by gas stripping, azeotropic distillation, extraction and rectification in turns.

其特征在于将乳酸水溶液加热至150～200℃气化得到的乳酸-水混合蒸气与载气混合，将混合后的气体继续加热到200～450℃后进入气-固相催化反应器中经改性Y沸石分子筛催化剂作用脱水得反应产物气体，反应产物气体冷却后经气液分离得到丙烯酸溶液，丙烯酸溶液再依次经过气提、共沸蒸馏或萃取、精馏得到粗丙烯酸产品。

In the process of extractive distillation o f butadiene,thequality of the byproduct butane-butene raffinate are rel ated to many process para meters, which are coupling and with noises.

丁二烯萃取精馏过程中，副产品抽余液的质量和很多工艺参数有关，工艺参数之间又是相互关联、耦合的，并具有噪声。

The raffinate column in the eluxyl unit of an aromatics complex is the key fractionator to separate C8 aromatics from para-diethyl benzene. PDEB is expensive and only if the PDEB content in C8 aromatics side cut is less than 25×10^(-6) mol/mol, the operation cost could be lowered effectively.

对二甲苯装置吸附分离单元的抽余液塔是分离碳八芳烃(C8A)和对二乙苯的关键精馏塔，PDEB价格昂贵，在侧线C8A中的含量要求小于25×10^(-6)mol/mol才能有效降低装置操作成本。

Energy savings can be achieved in this distillation system by running one of the columns at a higher pressure and integrating the condenser of the high-pressure column with the reboiler of the low-pressure column.

它的基本原理是由一个高压塔和一个低压塔来构成一个精馏系统，高压塔的塔顶蒸汽作为低压塔的塔釜供热，以节省能耗。

The system may be operated to keep the top composition constant by increasing the reflux ratio as the composition of the liquid in the reboiler changes.

间歇精馏操作可以通过随着再沸器中液相组成的变化，逐渐增加回流比，以保持塔顶馏出液组成恒定。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。