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In coalfield exploration in Runan County of Henan Province,thickness of tertiary and quaternary formation is up to 700 m,water sensitive clay,sandy clay,sandy argillite,aleurolite and gravel strata are often encountered.These easily cause hole diameter's shortage or enlargement,wall of hole collapsing and breaking.

在河南省驻马店汝南县林楼一正阳县张楼一带的煤田勘探中,第三、第四系地层厚达700m,经常遇到水敏性粘土、砂质粘土、砂质泥岩、粉砂岩和卵砾石等地层,易造成缩径、超径、坍塌和掉块等孔内复杂情况。

Clay is important, because it is used around the world to make containers of all kinds.

粘土是非常重要的,因为在世界各地都有使用粘土来制作各种器皿。

The main reason for slicing the clay is to homogenize the distribution of soft and dry clay.

主要原因切片粘土是同质化的分布和干软粘土。

Poly(N-isopropylacrylamide-co-2-hydroxyethyl methacrylate)/clay hydrogel was copolymerized with NIPA and HEMA cross-linked by clay to form a new kind of nanocomposite hydrogel P(NIPA-co-HEMA)/clay was obtained.

以无机粘土为交联剂制备了具有温度、pH双重敏感性的聚(N-异丙基丙烯酰胺-co-甲基丙烯酸-β-羟乙酯)/粘土纳米复合水凝胶P(NIPA-co-HEMA/clay,并用红外和X衍射对其结构和形态进行了表征。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Moreover drilling measures in different strata are pointed out,which are firstly drilling without slurry in part of silty clay layer,secondly adopting double-bottom bailing bit and bore directly and abandoning slurry with impact drilling rig in muddy clay layer,thirdly selecting short screw auger at low speed in gravel layer,finally choosing rock-socketed drilling tube in shaly sand layer.

指出旋挖钻机在不同地层中的钻进措施:部分粉质粘土层中可用清水或干孔钻进,淤泥质粘土层中采用双底捞砂钻头、直接用冲击钻机钻孔弃浆,圆砾层中采用短螺旋钻头低速钻进,泥质砂岩层中采用嵌岩钻筒钻进等措施,保证施工工期满足架梁节点要求。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Recent developments in the research on the geology and geochemistry of the newly-discovered clayey breccias at the lop of the Xiaochaka Formation in the Juhuashan, Xiaochaka and Shishuihe areas, Qiangtang Basin, northern Tibet have disclosed that mineral compositions, textures and structures, occurrences and sectional architectures of the clayey breccias agree well with those of the paleo-weathering crust in these areas. Compared with the bedrocks, the paleo-weathering crust is characterized by the leaching out of CaO and CO2, and relative enrichment of SiO2, Al2 O3, Fe2O3, K2O, Na2O, MnO and P2O5. The clayey weathered residues in the paleo-weathering crust are characterized by marked enrichment of REEs, much higher contents of LREEs than those of HREEs, markedly positive Ce anomalies and negative Eu anomalies, and a noticeable increase in other element contents besides Mo, Sn and U from the clayey weathered residues.

对最近在藏北羌塘盆地菊花山、肖茶卡、石水河等地区新发现的肖茶卡组顶部的粘土质角砾岩的地质、地球化学特征研究表明:其岩石矿物成分、结构构造、角砾层产状及剖面演化序列等与古风化壳的形成及其特征较为一致;相对于基岩,古风化壳的主量元素表现为CaO、CO2的淋失和SiO2、Al2O3、Fe2O3、K2O、Na2O、MnO、P2O5等不同程度的相对富集;古风化壳中的粘土质风化残积层的稀土元素具有明显的富集,表现为LREE含量远大于HREE的特征,存在明显的Ce的正异常以及Eu的负异常;微量元素除Mo、Sn和U外,粘土质风化残积层的其余元素含量均有明显的增加。

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