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However, partial red clay has swell-shrink characteristics that do harm to engineering, some partial has soft characteristic as low strength, high compressibility, and some partial has size fraction like mixed soil.

但是,红粘土的工程性质及其指标变化范围很大,还有一部分红粘土具有对工程产生危害的胀缩性,部分红粘土具有低强度,高压缩性的软弱特性,还有一部分具有混合土的特点。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Then studied on several clays affect on the stability of ferrate solution. The results show the addition of clays retarded the decomposition of ferrate in alkaline solution. Through analysed the results of test, we found this due to the silicium or polysilicium of clays and its increasing stabilizing effect on ferrate when the concentration of silicium or polysilicium increases.

接着作了粘土对高铁酸盐溶液的稳定作用的研究,结果表明粘土对高铁酸盐溶液有良好的稳定作用,通过实验分析得到其稳定作用是由于粘土中溶出的硅酸根或多聚硅酸根所致,且随着其浓度的增加对高铁酸盐的稳定作用增强。

At the heavy metal concentration of 3-4ppm, our study on adsorption capacity, adsorption selectivity of montmorillonite, illite and kaolinite to Cu〓、 Pb〓、 Zn〓、 Cd〓、 Cr〓 shows that the adsorption capacity is mainly determined by the capacity of exchangeable cations and the adsorption capacity of the three clay minerals decreases in this sequence: montmorillonite >> illite>kaolinite. It is found that clay minerals have obvious adsorption selectivity to various heavy metals. Montmorillonite exhibits a stronger affinity to Cr〓 and Cu〓 while kaolinite and illite sorb Cr〓 and Pb〓 more effectively. At the same heavy metal concentration, adsorption amount of clay minerals to heavy metals increase with increasing pH value of the solution.

在痕量浓度下,研究了蒙脱石、伊利石、高岭石三种粘土矿物对Cu〓、Pb〓、Zn〓、Cd〓、Cr〓五种重金属离子的吸附容量、吸附选择性及其介质条件对吸附量的影响,结果表明,粘土矿物的阳离子交换容量越大,对重金属离子的吸附容量也越大,其大小顺序为蒙脱石>>伊利石>高岭石;同时,不同粘土矿物对重金属离子具有明显的吸附选择性,蒙脱石对Cr〓和Cu〓有较好的选择性,伊利石和高岭石则对Cr〓和Pb〓有较好的选择性;随着吸附溶液pH值的增大,其吸附量有增加的趋势。

Brecciated clay rock and hydromica clay rock at tunnel exit section have been almost argillized clay and the clay is easy swelling when encountering water.

其角砾状粘土岩和水云母粘土岩多已泥化成粘土,遇水易膨胀。

In order to improve the soil in Hobq desert, this paper has dealt with such characteristics of palygorskite clays as gelatination, water absorbency and water conservation.

以改良库布齐沙漠为目的,结合坡缕石粘土特有的成胶性、吸附性和保水性能,用巴拉贡矿区的低品位坡缕石粘土进行了粘土成胶性能的研究。

The test results showed that: Young Modulus of undisturbed Kitan clay is much bigger than that of reconstituted one under the same stress level; Young Modulus of the same clay under high strain rate is bigger than that of small strain rate; Undisturbed Kitan clay showed perfect linear elastic property within small strain smaller than 0.01

试验结果显示:在相同应力水平条件下,未扰动Kitan粘土的杨氏模量大于重塑土;对于同一种粘土,在应变率大的情况下,它的杨氏模量同样大;在应变小于0.01%时,未扰动Kitan粘土呈线弹性。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

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