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Spirodilactone s are a series of compounds with the structures of spiro carbon and lactone which result in the special physical and chemical characters of Spirodilactone s.

螺双内酯是一类含双内酯环和螺碳原子这一特定结构的化合物。这种特定螺双内酯结构决定了这类化合物具有特殊的物理和化学性质。本文主要综述了螺双内酯及衍生物的合成方法、衍生化反应、手性拆分以及在合成高分子领域的研究现状和进

To further testify the high efficiency of these new reagents in the synthesis of sterically hindered peptides, we successfully synthesized the extensively -N-methylated peptide moiety of the antineoplastic and lipophilic depsipeptide Dolastatin 15 using reagent BEP and FEP. We also synthesized the highly hindered tetrapeptide segment of Cyclosporin A using reagent BEMT and BEP, respectively.

为进一步检验这类吡啶正离子型缩合剂在有空间位阻的多肽合成中的性能,我们以BEP和FEP为缩合剂,成功地合成了具有抗肿瘤活性的亲脂性酯肽Dolastatin 15分子中高N-烷基化的肽链部分;分别以BEMT和BEP为缩合剂合成了生物活性肽Cyclosporin A中空间位阻最大的四肽片断。

Tachistoscopic visual half-field test was used to investigate functional hemispheric laterality for three kinds of cognitive processing task (reading,simple addition and conceptual decision)on Arabic numerals and numerals in capital of Chinese characters.

用半视野速示术检查阿拉伯数字和汉字大写数字在三种任务加工条件(认读、简单相加、奇偶概念异同判断)下进行认知的大脑两半球机能活动一侧化效应。结果表明:以被试正确反应的百分数为指标,两类数字的三种任务加工均没有表现出明显的视野优势。

A photosensitive resin for UV curing acrylic powder coating has been synthesized by esterification of methacrylic acid and GMA-type acrylic resin at the presence of ethyl acetate as solvent, tetramethylammonium chloride as catalyst, YK as inhibitor.

以醋酸丁酯为溶剂,四甲基氯化铵为催化剂,氮氧自由基为阻聚剂,由甲基丙烯酸缩水甘油酯类丙烯酸树脂与甲基丙烯酸酯化反应制得了UV固化粉末涂料用感光性丙烯酸树脂。

A series of copper halides in one, two, or three dimensions have been successfully synthesized such as rhomboid dimers of stoichiometry [Cu2X2L2]n, the tetranuclear species on cubane or stepped cubane tetramers of stoichiometry [Cu4X4L4]n and hexagonal[Cu6X6] grid chains.2 The main strategy in crystal engineering is a secondary building block approach.3 For a given building block, there are two routes to construct frameworks.

在一维、二维或三维的一系列卤化铜已经成功地得到了合成,比如化学计量法[Cu2X2L2]n的长菱形二聚物、化学计量法[Cu4X4L4]n和六边形[Cu6X6]网格链的在立方烷上的四核类或阶梯式立方烷四聚物。[2] 在晶体工程上的主要策略是一种次级构件途径。[3] 对于一给定的构件来说,有两条构件骨架的路线。

A series of urea,thiourea and thiodiazole derivatives bearing mercaptotetrazole were synthesized using NaN_3 as a nitrogen source.

以叠氮化钠为氮源,合成了一系列含四唑环的芳基脲及噻二唑类化合物,其结构经1H NMR,IR和元素分析表征。

The removal of organic sulfur such as thiofuran , thioether and mercaptan is the main objective of dry desulfurization , and hydroconversion of organic sulfur and preventing the methanation side reaction are the technological difficulties of hydroconversion desulfurization. The combination of two-level conversion and two.1evel absorption is the preferential scheme for refined removal of high-concentration organic sulfur.

脱除噻吩、硫醚、硫醇类有机硫是干法脱硫的主要目标,加氢转化有机硫并防止发生甲烷化副反应是加氢转化脱硫的技术难点,组合式两级转化、两级吸收是精脱高浓度有机硫的优选方案。

Biogenic amines are basic nitrogenous compounds formed mainly by decarboxylation of amino acids or by amination and transamination of aldehydes and ketones.

生物胺是一类含氮的脂肪族、芳香族或杂环类低分子化合物,主要是通过氨基酸的脱羧或醛和酮的胺化和转氨基作用形成的。

The phosphorus oxychloride or phosphorus tribromide N, N-dimethylformamide mix and react to form the Vilsmeier reagent used in the reaction. The newly prepared Vilsmeier reagent is added into the reaction bottle provided with the return condenser and the blender; a reaction raw material N, N-dimethylformamide solution expressed in the reaction formula is added into the system; the temperature is risen; the corresponding multi substituting pyridine-2 (1 H)-ketone compound can be made after the column chromatography of the silica gel; the production rate is between 60 and 95 percent according to different reactions.

由三氯氧磷或三溴化磷N,N-二甲基甲酰胺混合获得反应中所用Vilsmeier试剂;将新配制的Vilsmeier试剂加入装有回流冷凝管、搅拌器的反应瓶中,向体系中加入反应通式中表示的一种反应原料的N,N-二甲基甲酰胺溶液,升温,经硅胶柱层析分离得相应的多取代吡啶-2(1H)-酮类化合物,产率视不同反应在60~95%之间。

Triphenylamine and their derivatives are excellent optical materials,and TPA is chosen as the basic framework for the design and synthesis of a series of TPA-based dyes.

三苯胺(Triphenylamine,TPA)及其衍生物是一类性能优良的光电材料,本论文即是选用三苯胺为基本骨架,通过简单的有机反应,设计和合成一系列三苯胺类有机敏化剂。

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What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢?

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我,一个心中布满虚荣的女孩子真实的想法。

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