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The spatiotemporal spectral line intensities of the first three atomic lines in Hydrogen Balmer series (λ=656. 28, 486. 13, 434. 05nm) of RF ion source plasma, are measured with calibrated Optical Multichannel Analyzer . Some plasma parameters, including electron temperature, hydrogen atom density and hydrogen ion density, are calculated and analyzed Using Partial Local Thermodynamic Equilibrium theory and Abel transform.

实验采用绝对定标后的光学多道分析系统测定了离子源等离子体不同时间和空间位置的氢原子巴耳末谱线系中前三条谱线(λ=656.28,486.13,434.05nm)的强度,并采用PLTE的理论和Abel变换方法,计算出了高频离子源等离子体的电子温度、氢原子浓度、氢离子浓度等参数在放电的不同阶段和径向分布情况,并进行了简要分析。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题,系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性,通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析,全文主要内容如下: 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明:红磷在空气中发生缓慢氧化、歧化反应,微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度,其中铜离子的作用最为明显,而铝、锌等离子减慢了红磷的氧化速度,银离子对减少红磷的吸湿性效果最好。

This essay will give the further explanation about the shape of hydronium and iron and aluminum, and the dry methods between them by the approximate cafculation of hydronium in the liquid of polymeric iron and polymeric aluminum.

通过对聚合铁和聚合铝溶液中氢离子的有关近似计算,进一步说明了氢离子与铁铝形态、干燥方式等之间的关系,指出了进行聚合铁理论研究时应注意其制备方法、浓度和氢离子的重要性。

The results show that the calculated cell parameters are in agreement with the experimental ones. The interactions between Li—N and Al—N are strong ionic bonds in Li3AlN2. The interaction between N and H is strong covalent bond and the interaction between Li and N is strong ionic bond in LiNH2. The calculated reaction enthalpies are 23.7 and 55.3 kJ/mol, respectively, which are in agreement with the experimental ones.

结果表明:Li3AlN2的Li—N、Al—N键主要为离子键,LiNH2的N—H键主要为共价键,Li—N键主要为离子键;298 K时贮氢反应的反应焓计算值分别为23.7和55.3 kJ/mol,与实验值均符合得较好;反应中各固态、气态物质的晶胞的结构优化后的晶格常数、键长与键角等与相应的实验值均符合较好。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。

The effects of ,, and temperature on the distribution ratio have been investigated. The composition of the extracted species is determined by the methods of slope ratio, continuous variation,extraction isotherm curves and their chemical analyses. The extraction is found to proceed according to the reaction:AuCl_4 ~-+DEOTA_(0)TAuCl3 .DEOTA_...

着重研究了盐酸浓度、氯离子浓度、氢离子浓度和温度诸因素对萃取的影响;对有机相中金的反萃行为也进行了初探;通过斜率法、等摩尔系列法、萃取等温线法确定了配合物的组成;推定了DEOTA在盐酸体系中萃取金的机理为配位取代反应;计算了萃取反应的表观平衡常数和配合物的稳定常数。

Occurrence of RE hydride was identified in the Al-Si alloy containing RE andenrichment of hydrogen in polynary RE intermetallic compound was determined by means ofEPMA, secondary ion mass spectrography, Hg-free vacuum drivepipe hydrogen-meter to-gether with metallography and porosity measurement.

采用电子探针、二次离子质谱、无汞真空套管测氢仪等检测手段,并配合金相分析及试样孔隙度的测定,鉴定出含稀土的Al-Si合金中有稀土氢化物的存在,确认在多元稀土金属间化合物中氢的富集,提出稀土具有较强固氢作用的观点。

Compared of the efficiency of treating heavy metals in FGD wastewater with NaOH, Ca_2 and Mg_2. It indicated that NaOH was much efficient for precipitated waste water; Ca_2 was much efficient for unprecipitated waste water, the removal efficiency reached 98.4%. With the increasing of the main ion of Ca~2+, Cl~- in FGD wastewater, the efficiency decreased. It decreased 60% for the removing of Mn and 10% for Zn, Cd and Ni. The rectification coefficient token the Ksp of practical wastewater because it quite different with theoretic Ksp at different pH; the theoretic and practice addition were proportioned and it commonly reached 1:300.The precipitation efficiency of Na2S at different pH and the effect of Ca2+ was determined.

比较了NaOH、Ca_2和Mg_2处理脱硫废水时重金属的去除效果,分析了Ca~(2+)、SO_4~(2-)和Cl~-等主要离子的影响,结果表明:NaOH和Ca_2能有效处理脱硫废水中的重金属;对澄清废水而言,NaOH效果较好,对于未澄清废水而言,Ca_2效果更好,但去除废水中重金属的效率都能达到98.4%;随着Ca~(2+)、Cl~-等主要离子浓度的增大,中和作用去除重金属的效率降低,Mn最大降低60%,Zn,Cd,Ni降低10%左右;实际重金属浓度和用理论Ksp计算所得值差别很大,通过校正系数能有效计算实际重金属浓度;实现相同pH时氢氧化物的理论和实际投加量成一定比例,最大可达1:500。

The oil shale ash is disintegrated into fine powder less than 150 eye to be calcined at a certain temperature, then sulfuric acid solution is added for performing acid dipping, after solid-liquid separation and solid residue removal, aluminum sulfate solution is obtained and is then filtered after sodium hydroxide solution is added in, further metallic ions as Ca2 , Mg2 , Fe3 , Fe2 and the like are filtered from the solution, thereby sodium aluminate solution is obtained, gas of carbon dioxide is communicated into the sodium aluminate solution to obtain aluminum hydroxide sediment, and after drying and calcining aluminum hydroxide powder is obtained.

将油页岩灰渣粉碎至<150目的细粉,在一定温度下煅烧,加入硫酸溶液进行酸浸,固液分离,去除固体残渣,得硫酸铝滤液,加氢氧化钠溶液后过滤,滤除溶液中的Ca 2 、Mg 2 、Fe 3 、Fe 2 等金属离子,得偏铝酸钠溶液,向偏铝酸钠溶液通入二氧化碳气体,得到氢氧化铝沉淀,经烘干、煅烧得到氢氧化铝粉末。

Using the time-match semiempirical models for two flares (one is classified as a SB flare and the other a 2B flare), which were deduced from the spectral data obtained with the solar tower telescope of Nanjing University, we calculate the radiative loss at different phase of the flares.

针对我们已经建立的二个定态色球耀斑半经验模型,计算了耀斑不同时刻下的色球辐射损失速率,包括氢在四个能级假设下的所有跃迁、CaⅡ在五个能级下的所有跃迁、MgⅡ在三个能级下的所有跃迁、以及负氢离子的自由——自由和束缚——自由跃迁等。

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