立方的

The crystal structure of pure Pd is of face centered cubic and it is a hydrogen absorbing metal.

钯是一种面心立方结构的吸氢金属，氢原子溶解在晶格中，占据八面体间隙位，形成fcc的子晶格，吸氢时晶格发生等方性膨胀；氢在钯中的扩散路径为O T O跃迁，存在反同位素效应；钯氢化物的氢同位素分离因子较大，并受到温度、氢浓度等因数的影响；钯氢体系的p c等温线表现出良好的坪台性，Pd H和Pd D均存在临界点，尚未确定Pd T有无临界点；单晶钯氢反应动力学与不同的晶面有关；钯氚体系存在氚老化效应

The Pd-Cu/C catalysts were shown to have the face centered cubic crystal structure. This could indicate that the addition of Cu shortened the Pd-Pd distances in the crystal lattice, and therefore –HO(subscript 2ads) and O-O could be better adsorbed on the surface of the catalyst. When NaBH4 was used as the reducing agent, and the atomic ratio of Pd to Cu was 3:1, the resulting catalysts had an average particle size of 3. 4nm and showed the best catalytic performance. The electrochemical active surface are a of Pd3Cu/C was 38.9m^2/gPd and the oxidation reduction reaction activity of the Pd3Cu/C catalyst was much higher than that of the Pd/C catalyst. The electrochemical activity of the Pd3Cu/C catalyst was comparable to that of a commercial Pt/C catalyst.

结果表明：催化剂中Pd与Cu的物质的量之比与预设值相近，Pd和Cu基本被全部还原；Pd-Cu/C催化剂为面心立方结构，元素铜的加入使催化剂的Pd-Pd间距缩小，从而HO(下标 2 ads)和OO键能更好地吸附在催化剂金属表面；当采用NaBH4为还原剂，Pd与Cu物质的量比为3：1时，催化剂(Pd3Cu/C)的平均粒径为3.4 nm，催化剂的催化性能最好，电化学活性表面积EAS达到38.9平方公尺/gPd，电化学性能较Pd/C催化剂有很大提高，接近Pt/C商用催化剂。

The results show that the microscopical pore structure of the three dimensional orthogonal woven carbon fabric structure perform is composed of body-centered cubes which arranged periodically at spaces. The net structure and shape of the pores of perform are determined by the size and proration of the fasciculus diameter, which are key factors influencing the gaseous permeability and final density of composites. Once the proration of the fasciculus diameters of different directions is determined, the trend of diversification of the permeability followed by pore rate during CVI process and the density of composites are stated, and the permeability increases with the increase of the fasciculus diameter.

研究结果表明：三维正交结构炭纤维预制体的宏观孔隙结构在空间上可以看成是由呈周期性排列的体心立方"晶胞"构成； X ， Y 和 Z 3个方向纤维束直径大小及比例关系决定三维正交结构炭纤维预制体宏观孔隙网络的结构和形状，也是决定反应气体在孔隙中的比渗透率和复合材料最终致密度的重要因素；当 X ， Y 和 Z 3个方向纤维束直径的比例关系一定时，不同预制体在CVI增密过程中比渗透率随孔隙率变化的趋势相同；复合材料的最终致密度一定；比渗透率随纤维束直径增大而略有增大。

CCDI's portfolio shows a history of working for the progress of the public. Our projects have been recognized by both the public and the consultancy industry, most recently with the design of the "Watercube", the National Swimming Center and other six sport facilities for the Beijing 2008 Olympic Games. Incus the past, we have provided project management services for the Shanghai International Exhibition Center, using our experience to achieve an optimized control of time, cost and quality of the project. At present, our work in the Healthcare industry is helping to raise the quality of Chinese medical facilities to international standards and our Environment and Energy division has begun an ecological preservation effort at Dongli Lake in Tianjin….. At CCDI, we care about the environment we are living in and we are here to help resolve challenges presented in the progress of China urbanization.

CCDI为2008年北京奥运会主持设计了国家游泳中心"水立方"、网球中心、沙滩排球馆、射箭场、曲棍球场、小轮车场等六个场馆；意识到城市可持续发展的迫切性，我们正在推进天津东丽湖全生态城镇方案以及河南、安徽、山东等地区新能源项目的实施；在医疗领域，我们关注人们的医疗和健康，将国际标准应用于医院设计，引领国内医疗行业设施建设的发展方向；通过国际经验的运用，为上海国际会展中心提供全程项目管理服务，实现了时间、成本、质量的更优控制……在CCDI，我们珍爱我们生活的城市环境，为此我们将一如既往地担负起企业的社会责任，为中国城市建设提供高标准的专业服务。

This paper studies the invariant, which is the linear preserving problem based on generalized inverse of matrices. The generalized inverse of matrices and the research status of preserving problems of generalized inverse are outlined. In the basis of deeply understanding the basic knowledge of linear maps, the definition, characteristics of generalized inverse and decomposition of matrix, the author analyzes the decomposition form of preserving idempotence and preserving tripotence in the PID, then studies on the linear maps form of preserving group inverses of symmetric matrices.

本文研究的不变量是矩阵广义逆线性算子的保持问题，概述了广义逆矩阵，广义逆保持问题的研究现状，在对线性映射的基础知识，广义逆矩阵的定义、性质和矩阵的分解深入理解的基础上，深入分析了保幂等、保立方幂等矩阵在主理想整环上的分解形式，继而研究了保对称矩阵群逆的线性算子形式。

4The electrical double layer model, joining with the microstructure of CFRC,fractal electrical emission, electrothermal effect, thermoelectrical effect and electrical osmosis are used to analyze the mechanism of mechanoelectric effect and electromechanical effect of CFRC.

采用正交试验方法研究了不同配比分散剂对碳纤维在水泥基体中分散性的影响，得到了较佳分散剂配比，探讨了分散剂的作用机理和碳纤维长度分布规律；（2）研究了碳纤维水泥基复合材料中纤维掺量、水灰比、电极形式、载荷形式等对力电效应的影响，考察了CFRC力电效应的两种表现形式及在机敏混凝土结构上的应用；（3）研究了CFRC立方试块、CFRC梁和不含导电填料梁的电力效应，分析了电流大小、电流方向等与电致变形的关系；（4）根据界面电偶层模型，结合CFRC的微观结构，以及断裂电发射、电热效应、热电效应和电渗效应等分析了CFRC力电、电力效应的机理，阐明碳纤维的作用机制。

Using the one-atom theory, the electronic structures of Pt-electrocatalyst with fcc structure was determined as follows:(5dn)6.48 (5dc)2.02 (6sc)1.48(6sf)0.02. Compared to the result obtained by the first-principle method such as FP-LMTO, CASTEP, their results are in good agreement with each other. Comparing the calculations of physical properties such as lattice constants, cohesive energy and bulk modulus by OA method and first-principle method, the result obtained by OA method is in excellent agreement with experimental value, but the result obtained by first-principle method is not accordable. The relationship between the electronic structures and catalytic performance was explained qualitatively by OA method and first principle method according to its electronic structures. Because the d-orbital vacancies increases and static density is high around Fermi energy band, Pt has good catalytic performance.

摘 要：依据纯金属单原子理论确定面心立方结构电催化剂Pt的电子结构为(5dn)6.48(5dc)2.02-(6sc)1.48(6sf)0.02，与采用第一原理的FP-LMTO和CASTEP等方法所计算的电子结构相比较，其结果非常相近；由OA理论和第一原理方法计算的晶格常数、结合能、体弹性模量等物理参数进行比较，OA理论计算的结果与实验值较符合，而第一原理方法计算的结果与实验值相差较大；在此基础上用OA理论和第一原理方法研究了Pt的电子结构与催化性能的关系，由于d带空穴增多和费米能级附近态密度较高，导致金属Pt的催化性能很好。

The batch seeded isothermal desupersaturation experiments of SPM in aqueous solution were carried out and the overall crystal growth kinetics parameters were determined by the nonlinear optimization techniques. Assuming that the volume diffusion rate at growth is equal to the mass transfer rate at dissolution under the same conditions, the two-step crystal growth rate parameters can be determined. At the fow supersaturation, the surface integration rate is proportional to relative surface supersaturation.

通过测量螺旋霉素均相成核动力学，获得了表面能的值，估算出表面熵因子的值在1.41～1.56之间，从而可以推断出螺旋霉素晶体生长的表面反应速率同表面相对过饱和度成线性关系，这种生长机理同第四章得到的结果是相吻合的；利用估算的表面熵因子的值，把螺旋霉素晶体看作为简单的立方科瑟尔晶体，根据能量最低原理，对螺旋霉素的晶体生长进行了模拟。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

The results show that the microscopical pore structure of the three dimensional orthogonal woven carbon fabric structure perform is composed of body-centered cubes which arranged periodically at spaces. The net structure and shape of the pores of perform are determined by the size and proration of the fasciculus diameter, which are key factors influencing the gaseous permeability and final density of composites. Once the proration of the fasciculus diameters of different directions is determined, the trend of diversification of the permeability followed by pore rate during CVI process and the density of composites are stated, and the permeability increases with the increase of the fasciculus diameter.

研究结果表明：三维正交结构炭纤维预制体的宏观孔隙结构在空间上可以看成是由呈周期性排列的体心立方&晶胞&构成； X ， Y 和 Z 3个方向纤维束直径大小及比例关系决定三维正交结构炭纤维预制体宏观孔隙网络的结构和形状，也是决定反应气体在孔隙中的比渗透率和复合材料最终致密度的重要因素；当 X ， Y 和 Z 3个方向纤维束直径的比例关系一定时，不同预制体在CVI增密过程中比渗透率随孔隙率变化的趋势相同；复合材料的最终致密度一定；比渗透率随纤维束直径增大而略有增大。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。